Title: All-Iron Redox Flow Battery Tailored for Off-Grid Portable Applications

Journal Article · · ChemSusChem
 [1];  [1];  [1]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Energy Storage and Distributed Resources Division

We proposed and developed an all-iron redox flow battery for end users without access to an electricity grid. The concept is a low-cost battery which the user assembles, discharges, and then disposes of the active materials. Our design goals are: (1) minimize upfront cost, (2) maximize discharge energy, and (3) utilize non-toxic and environmentally benign materials. These are different goals than typically considered for electrochemical battery technology, which provides the opportunity for a novel solution. The selected materials are: low-carbon-steel negative electrode, paper separator, porous-carbon-paper positive electrode, and electrolyte solution containing 0.5 m Fe 2 (SO 4 ) 3 active material and 1.2 m NaCl supporting electrolyte. Furthermore, with these materials, an average power density around 20 mW cm -2 and a maximum energy density of 11.5 Wh L -1 are achieved. A simple cost model indicates the consumable materials cost US$6.45 per kWh -1 , or only US$0.034 per mobile phone charge.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Fuel Cell Technologies Office (EE-3F)
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1378687
Journal Information:
ChemSusChem, Journal Name: ChemSusChem Journal Issue: 23 Vol. 8; ISSN 1864-5631
Publisher:
ChemPubSoc EuropeCopyright Statement
Country of Publication:
United States
Language:
English

References (9)

Optimization and Analysis of High-Power Hydrogen/Bromine-Flow Batteries for Grid-Scale Energy Storage journal October 2013
Performance and cycling of the iron-ion/hydrogen redox flow cell with various catholyte salts journal May 2013
Maximizing plating density and efficiency for a negative deposition reaction in a flow battery journal December 2014
Impact of membrane characteristics on the performance and cycling of the Br2–H2 redox flow cell journal June 2015
Self-Assembled Monolayers of n -Alkanethiols Suppress Hydrogen Evolution and Increase the Efficiency of Rechargeable Iron Battery Electrodes journal December 2012
Investigation of Factors Affecting Performance of the Iron-Redox Battery journal January 1981
A High-Performance Rechargeable Iron Electrode for Large-Scale Battery-Based Energy Storage journal January 2012
An Investigation into Factors Affecting the Iron Plating Reaction for an All-Iron Flow Battery journal November 2014
Studies of Iron-Ligand Complexes for an All-Iron Flow Battery Application journal January 2014

Cited By (6)

High Voltage, Transition Metal Complex Enables Efficient Electrochemical Energy Storage in a Li-Ion Battery Full Cell journal December 2016
Iron-based flow batteries to store renewable energies journal February 2018
Material design and engineering of next-generation flow-battery technologies journal November 2016
Rechargeable redox flow batteries: flow fields, stacks and design considerations journal January 2018
Water-soluble pH-switchable cobalt complexes for aqueous symmetric redox flow batteries journal January 2020
All-Iron Hybrid Flow Batteries with In-Tank Rebalancing journal January 2019