Structural diversity in binary superlattices self-assembled from polymer-grafted nanocrystals
Abstract
Multicomponent nanocrystal superlattices represent an interesting class of material that derives emergent properties from mesoscale structure, yet their programmability can be limited by the alkyl-chain-based ligands decorating the surfaces of the constituent nanocrystals. Polymeric ligands offer distinct advantages, as they allow for more precise tuning of the effective size and 'interaction softness' through changes to the polymer' s molecular weight, chemical nature, architecture, persistence length and surrounding solvent. Here we show the formation of 10 different binary nanocrystal superlattices (BNSLs) with both two- and three-dimensional order through independent adjustment of the core size of spherical nanocrystals and the molecular weight of densely grafted polystyrene ligands. These polymer-brush-based ligands introduce new energetic contributions to the interparticle potential that stabilizes various BNSL phases across a range of length scales and interparticle spacings. Our study opens the door for nanocrystals to become modular elements in the design of functional particle brush solids with controlled nanoscale interfaces and mesostructures.
- Authors:
-
- Univ. of California, Berkeley, CA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoScience Institute, Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1255541
- Alternate Identifier(s):
- OSTI ID: 1378674
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 6; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Ye, Xingchen, Zhu, Chenhui, Ercius, Peter, Raja, Shilpa N., He, Bo, Jones, Matthew R., Hauwiller, Matthew R., Liu, Yi, Xu, Ting, and Alivisatos, A. Paul. Structural diversity in binary superlattices self-assembled from polymer-grafted nanocrystals. United States: N. p., 2015.
Web. doi:10.1038/ncomms10052.
Ye, Xingchen, Zhu, Chenhui, Ercius, Peter, Raja, Shilpa N., He, Bo, Jones, Matthew R., Hauwiller, Matthew R., Liu, Yi, Xu, Ting, & Alivisatos, A. Paul. Structural diversity in binary superlattices self-assembled from polymer-grafted nanocrystals. United States. https://doi.org/10.1038/ncomms10052
Ye, Xingchen, Zhu, Chenhui, Ercius, Peter, Raja, Shilpa N., He, Bo, Jones, Matthew R., Hauwiller, Matthew R., Liu, Yi, Xu, Ting, and Alivisatos, A. Paul. Wed .
"Structural diversity in binary superlattices self-assembled from polymer-grafted nanocrystals". United States. https://doi.org/10.1038/ncomms10052. https://www.osti.gov/servlets/purl/1255541.
@article{osti_1255541,
title = {Structural diversity in binary superlattices self-assembled from polymer-grafted nanocrystals},
author = {Ye, Xingchen and Zhu, Chenhui and Ercius, Peter and Raja, Shilpa N. and He, Bo and Jones, Matthew R. and Hauwiller, Matthew R. and Liu, Yi and Xu, Ting and Alivisatos, A. Paul},
abstractNote = {Multicomponent nanocrystal superlattices represent an interesting class of material that derives emergent properties from mesoscale structure, yet their programmability can be limited by the alkyl-chain-based ligands decorating the surfaces of the constituent nanocrystals. Polymeric ligands offer distinct advantages, as they allow for more precise tuning of the effective size and 'interaction softness' through changes to the polymer' s molecular weight, chemical nature, architecture, persistence length and surrounding solvent. Here we show the formation of 10 different binary nanocrystal superlattices (BNSLs) with both two- and three-dimensional order through independent adjustment of the core size of spherical nanocrystals and the molecular weight of densely grafted polystyrene ligands. These polymer-brush-based ligands introduce new energetic contributions to the interparticle potential that stabilizes various BNSL phases across a range of length scales and interparticle spacings. Our study opens the door for nanocrystals to become modular elements in the design of functional particle brush solids with controlled nanoscale interfaces and mesostructures.},
doi = {10.1038/ncomms10052},
journal = {Nature Communications},
number = ,
volume = 6,
place = {United States},
year = {Wed Dec 02 00:00:00 EST 2015},
month = {Wed Dec 02 00:00:00 EST 2015}
}
Web of Science
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Recent advances in amphiphilic block copolymer templated mesoporous metal-based materials: assembly engineering and applications
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Inverse design of multicomponent assemblies
journal, March 2018
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Potential of mean force for two nanocrystals: Core geometry and size, hydrocarbon unsaturation, and universality with respect to the force field
journal, July 2018
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Self-assembly of active core corona particles into highly ordered and self-healing structures
journal, October 2019
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Hierarchical complex self-assembly in binary nanoparticle mixtures
journal, August 2019
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Soft nanostructured films for directing the assembly of functional materials
journal, March 2017
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DNA-Based Assembly of Quantum Dots into Dimers and Helices
journal, March 2019
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Shape-Tunable Colloids from Structured Liquid Droplet Templates
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Inverse Design of Multicomponent Assemblies
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Luminescent Gold Nanocluster-Decorated Polymeric Hybrid Particles with Assembly-Induced Emission
journal, May 2018
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Assembling Ordered Crystals with Disperse Building Blocks
journal, July 2019
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Hierarchically self-assembled hexagonal honeycomb and kagome superlattices of binary 1D colloids
journal, August 2017
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Microscopic mechanisms of deformation transfer in high dynamic range branched nanoparticle deformation sensors
journal, March 2018
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Understanding and tailoring ligand interactions in the self-assembly of branched colloidal nanocrystals into planar superlattices
journal, March 2018
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Creating two self-assembly micro-environments to achieve supercrystals with dual structures using polyhedral nanoparticles
journal, July 2018
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Space- and time-resolved small angle X-ray scattering to probe assembly of silver nanocrystal superlattices
journal, October 2018
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Nanocomposite Metamaterials Based on Self-assembled Titanium Dioxide Rolls with Embedded Gold Nanoparticles
journal, May 2019
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- Scientific Reports, Vol. 9, Issue 1
Colloidal Self-Assembly of Inorganic Nanocrystals into Superlattice Thin-Films and Multiscale Nanostructures
journal, September 2019
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