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Title: Facet-Dependent Deposition of Highly Strained Alloyed Shells on Intermetallic Nanoparticles for Enhanced Electrocatalysis

Compressive surface strains can enhance the performance of platinum-based core@shell electrocatalysts for the oxygen reduction reaction (ORR). Bimetallic core@shell nanoparticles (NPs) are widely studied nanocatalysts but often have limited lattice mismatch and surface compositions; investigations of core@shell NPs with greater compositional complexity and lattice misfit are in their infancy. Here, a new class of multimetallic NPs composed of intermetallic cores and random alloy shells is reported. Specifically, face-centered cubic (fcc) Pt- Cu random alloy shells were deposited non-epitaxially on PdCu B2 intermetallic seeds, giving rise to faceted core@shell NPs with highly strained surfaces. In fact, high resolution transmission electron microscopy (HRTEM) revealed orientation-dependent surface strains, where the compressive strains were minimal on Pt-Cu {111} facets but greater on {200} facets. These core@shell NPs provide higher specific and mass activities for the ORR when compared to conventional Pt-Cu NPs. Moreover, these intermetallic@random alloy NPs displayed high endurance, undergoing 10,000 cycles with only a slight decay in activity and no apparent structural changes.
Authors:
 [1] ;  [2] ;  [1] ;  [1] ;  [2] ;  [1]
  1. Indiana Univ., Bloomington, IN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Grant/Contract Number:
AC05-00OR22725; SC0010489
Type:
Published Article
Journal Name:
Nano Letters
Additional Journal Information:
Journal Volume: 17; Journal Issue: 9; Journal ID: ISSN 1530-6984
Publisher:
American Chemical Society
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Indiana Univ., Bloomington, IN (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; core−shell; lattice misfit; oxygen reduction reaction; Pt-M nanoparticles; seeded growth; surface strains
OSTI Identifier:
1378291
Alternate Identifier(s):
OSTI ID: 1394467; OSTI ID: 1421601; OSTI ID: 1482342

Wang, Chenyu, Sang, Xiahan, Gamler, Jocelyn T. L., Chen, Dennis P., Unocic, Raymond R., and Skrabalak, Sara E.. Facet-Dependent Deposition of Highly Strained Alloyed Shells on Intermetallic Nanoparticles for Enhanced Electrocatalysis. United States: N. p., Web. doi:10.1021/acs.nanolett.7b02239.
Wang, Chenyu, Sang, Xiahan, Gamler, Jocelyn T. L., Chen, Dennis P., Unocic, Raymond R., & Skrabalak, Sara E.. Facet-Dependent Deposition of Highly Strained Alloyed Shells on Intermetallic Nanoparticles for Enhanced Electrocatalysis. United States. doi:10.1021/acs.nanolett.7b02239.
Wang, Chenyu, Sang, Xiahan, Gamler, Jocelyn T. L., Chen, Dennis P., Unocic, Raymond R., and Skrabalak, Sara E.. 2017. "Facet-Dependent Deposition of Highly Strained Alloyed Shells on Intermetallic Nanoparticles for Enhanced Electrocatalysis". United States. doi:10.1021/acs.nanolett.7b02239.
@article{osti_1378291,
title = {Facet-Dependent Deposition of Highly Strained Alloyed Shells on Intermetallic Nanoparticles for Enhanced Electrocatalysis},
author = {Wang, Chenyu and Sang, Xiahan and Gamler, Jocelyn T. L. and Chen, Dennis P. and Unocic, Raymond R. and Skrabalak, Sara E.},
abstractNote = {Compressive surface strains can enhance the performance of platinum-based core@shell electrocatalysts for the oxygen reduction reaction (ORR). Bimetallic core@shell nanoparticles (NPs) are widely studied nanocatalysts but often have limited lattice mismatch and surface compositions; investigations of core@shell NPs with greater compositional complexity and lattice misfit are in their infancy. Here, a new class of multimetallic NPs composed of intermetallic cores and random alloy shells is reported. Specifically, face-centered cubic (fcc) Pt- Cu random alloy shells were deposited non-epitaxially on PdCu B2 intermetallic seeds, giving rise to faceted core@shell NPs with highly strained surfaces. In fact, high resolution transmission electron microscopy (HRTEM) revealed orientation-dependent surface strains, where the compressive strains were minimal on Pt-Cu {111} facets but greater on {200} facets. These core@shell NPs provide higher specific and mass activities for the ORR when compared to conventional Pt-Cu NPs. Moreover, these intermetallic@random alloy NPs displayed high endurance, undergoing 10,000 cycles with only a slight decay in activity and no apparent structural changes.},
doi = {10.1021/acs.nanolett.7b02239},
journal = {Nano Letters},
number = 9,
volume = 17,
place = {United States},
year = {2017},
month = {8}
}