Characterizing the electronic states of the second-row transition metal cations using high-resolution ion mobility mass spectrometry

Manard, Manuel J.; Kemper, Paul R.

doi:10.1016/j.ijms.2016.07.006

Title: Characterizing the electronic states of the second-row transition metal cations using high-resolution ion mobility mass spectrometry

Abstract

Reduced mobilities for ground-state and electronic excited-state configurations of the second-row transition metal cations, excluding Tc+, have been measured. These values were obtained using an ion mobility mass spectrometer that uses a 2 m drift tube to generate high-resolution ion mobility data. Several of these atomic cations have been previously studied and the results obtained here are compared to reduced mobilities reported in the literature. In all cases, ions were generated using pulsed-laser vaporization of either a metal rod or foil target. Presented here for the first time are the reduced mobilities of Y+, Ru+, and Rh+. A discussion of the observed trends in the mobilities of the second-row transition metal series, relative to those measured for the first-row series, is also provided.

Authors:: Manard, Manuel J.; Kemper, Paul R.

Publication Date:: Mon Aug 01 00:00:00 EDT 2016

Research Org.:: National Security Technologies, LLC. (NSTec), Las Vegas, NV (United States)

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA)

OSTI Identifier:: 1378286

Alternate Identifier(s):: OSTI ID: 1576490

Report Number(s):: DOE/NV/25946-2873
Journal ID: ISSN 1387-3806; S1387380616301154; PII: S1387380616301154

Grant/Contract Number:: AC52-06NA25946

Resource Type:: Published Article

Journal Name:: International Journal of Mass Spectrometry

Additional Journal Information:: Journal Name: International Journal of Mass Spectrometry Journal Volume: 407 Journal Issue: C; Journal ID: ISSN 1387-3806

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Subject:: 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; high-resolution ion mobility; collision cross section; electronic excited states; transition metal cations

Citation Formats


                    Manard, Manuel J., and Kemper, Paul R. Characterizing the electronic states of the second-row transition metal cations using high-resolution ion mobility mass spectrometry.  Netherlands: N. p., 2016. 
Web.  doi:10.1016/j.ijms.2016.07.006.

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                    Manard, Manuel J., & Kemper, Paul R. Characterizing the electronic states of the second-row transition metal cations using high-resolution ion mobility mass spectrometry.  Netherlands.  https://doi.org/10.1016/j.ijms.2016.07.006

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                    Manard, Manuel J., and Kemper, Paul R. Mon .  
"Characterizing the electronic states of the second-row transition metal cations using high-resolution ion mobility mass spectrometry".  Netherlands.  https://doi.org/10.1016/j.ijms.2016.07.006.

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@article{osti_1378286,

  title        = {Characterizing the electronic states of the second-row transition metal cations using high-resolution ion mobility mass spectrometry},

  author       = {Manard, Manuel J. and Kemper, Paul R.},

  abstractNote = {Reduced mobilities for ground-state and electronic excited-state configurations of the second-row transition metal cations, excluding Tc+, have been measured. These values were obtained using an ion mobility mass spectrometer that uses a 2 m drift tube to generate high-resolution ion mobility data. Several of these atomic cations have been previously studied and the results obtained here are compared to reduced mobilities reported in the literature. In all cases, ions were generated using pulsed-laser vaporization of either a metal rod or foil target. Presented here for the first time are the reduced mobilities of Y+, Ru+, and Rh+. A discussion of the observed trends in the mobilities of the second-row transition metal series, relative to those measured for the first-row series, is also provided.},

  doi          = {10.1016/j.ijms.2016.07.006},

  journal      = {International Journal of Mass Spectrometry},

  number       = C,

  volume       = 407,

  place        = {Netherlands},

  year         = {Mon Aug 01 00:00:00 EDT 2016},

  month        = {Mon Aug 01 00:00:00 EDT 2016}

}

Copy to clipboard

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Abstract

Citation Formats

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Rate coefficients for oxidation of Ti + and Th + by O 2 and NO at low energies journal, December 1974

Interactions between Amyloid-β and Tau Fragments Promote Aberrant Aggregates: Implications for Amyloid Toxicity journal, September 2014

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Reactions of Fe+, Co+, and Ni+ with Silane. Electronic State Effects, Comparison to Reactions with Methane, and M+-SiHx (x = 0-3) Bond Energies journal, January 1995

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journal, July 1990

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journal, December 1992

Mobility of gaseous lons in weak electric fields
journal, July 1958

Binding interactions of mono- and diatomic silver cations with small alkenes: experiment and theory
journal, March 2005

Size- and support-dependency in the catalysis of gold
journal, April 1997

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journal, July 2007

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journal, May 2016

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journal, March 2006

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journal, June 1997

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journal, March 1997

Ion mobility spectrometry: A personal view of its development at UCSB
journal, September 2014

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journal, March 2014

Electronic-state chromatography: application to first-row transition-metal ions
journal, June 1991

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journal, December 1974

Interactions between Amyloid-β and Tau Fragments Promote Aberrant Aggregates: Implications for Amyloid Toxicity
journal, September 2014

Structures of carbon cluster ions from 3 to 60 atoms: Linears to rings to fullerenes
journal, September 1991

Metastable Metal Ion Production in Sputtering dc Glow Discharge Plasmas: Characterization by Electronic State Chromatography
journal, February 1999

Relating ion/neutral reaction rate coefficients and cross-sections by accessing a database for ion transport properties
journal, November 1995

A new, higher resolution, ion mobility mass spectrometer
journal, October 2009

Ion Mobility of Ground and Excited States of Laser-Generated Transition Metal Cations
journal, February 2008

Organometallic chemistry in the gas phase
journal, September 1991

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journal, January 1995

Remote functionalization of C-H and C-C bonds by "naked" transition-metal ions (Cosi Fan Tutte)
journal, August 1989

Biomolecule Analysis by Ion Mobility Spectrometry
journal, July 2008

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Guided Ion Beam Studies of the Reactions of Group 3 Metal Ions (Sc+, Y+, La+, and Lu+) with Silane. Electronic State Effects, Comparison to Reactions with Methane, and M+-SiHx (x = 0-3) Bond Energies
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