skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Cu and Zn Substituted Silicon Clathrates with the Cubic Type-II Structure: Synthesis and Characterization of Cs 8Na 16Cu 3.8Si 132.2 and Cs 8Na 16Zn 6.9Si 129.1

Authors:
 [1];  [1]
  1. Department of Chemistry and Biochemistry, University of Delaware, 19716 Newark DE USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1378150
Grant/Contract Number:  
SC0008885
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Zeitschrift fuer Anorganische und Allgemeine Chemie
Additional Journal Information:
Journal Name: Zeitschrift fuer Anorganische und Allgemeine Chemie; Journal ID: ISSN 0044-2313
Publisher:
Wiley
Country of Publication:
Germany
Language:
English

Citation Formats

Schäfer, Marion C., and Bobev, Svilen. Cu and Zn Substituted Silicon Clathrates with the Cubic Type-II Structure: Synthesis and Characterization of Cs8Na 16Cu3.8Si132.2 and Cs8Na16Zn6.9Si129.1. Germany: N. p., 2017. Web. doi:10.1002/zaac.201700236.
Schäfer, Marion C., & Bobev, Svilen. Cu and Zn Substituted Silicon Clathrates with the Cubic Type-II Structure: Synthesis and Characterization of Cs8Na 16Cu3.8Si132.2 and Cs8Na16Zn6.9Si129.1. Germany. doi:10.1002/zaac.201700236.
Schäfer, Marion C., and Bobev, Svilen. Fri . "Cu and Zn Substituted Silicon Clathrates with the Cubic Type-II Structure: Synthesis and Characterization of Cs8Na 16Cu3.8Si132.2 and Cs8Na16Zn6.9Si129.1". Germany. doi:10.1002/zaac.201700236.
@article{osti_1378150,
title = {Cu and Zn Substituted Silicon Clathrates with the Cubic Type-II Structure: Synthesis and Characterization of Cs8Na 16Cu3.8Si132.2 and Cs8Na16Zn6.9Si129.1},
author = {Schäfer, Marion C. and Bobev, Svilen},
abstractNote = {},
doi = {10.1002/zaac.201700236},
journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie},
number = ,
volume = ,
place = {Germany},
year = {2017},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/zaac.201700236

Save / Share:

Works referenced in this record:

Atomic Displacement Parameters and the Lattice Thermal Conductivity of Clathrate-like Thermoelectric Compounds
journal, September 1999

  • Sales, B. C.; Chakoumakos, B. C.; Mandrus, D.
  • Journal of Solid State Chemistry, Vol. 146, Issue 2
  • DOI: 10.1006/jssc.1999.8354

Synthesis and characterization of framework-substituted Cs8Na16Cu5Ge131
journal, February 2009


Clathrates Ba 8 {Zn,Cd} x Si 46− x , x ∼7: synthesis, crystal structure and thermoelectric properties
journal, August 2009


New type-I clathrates with ordered Eu distribution
journal, August 2006


Inorganic clathrate-II materials of group 14: synthetic routes and physical properties
journal, January 2008

  • Beekman, M.; Nolas, G. S.
  • J. Mater. Chem., Vol. 18, Issue 8
  • DOI: 10.1039/B706808E

Structural, Chemical, and Transport Properties of a New Clathrate Compound:  Cs 8 Zn 4 Sn 42
journal, September 1999

  • Nolas, G. S.; Weakley, T. J. R.; Cohn, J. L.
  • Chemistry of Materials, Vol. 11, Issue 9
  • DOI: 10.1021/cm990164i

Clathrates of Group 14 with Alkali Metals: An Exploration
journal, August 2000

  • Bobev, Svilen; Sevov, Slavi C.
  • Journal of Solid State Chemistry, Vol. 153, Issue 1
  • DOI: 10.1006/jssc.2000.8755

On the possibility for Rb- and Eu-cation ordering in type-I clathrates: synthesis and homogeneity range of the novel compounds Rb 8– x Eu x (In,Ge) 46 (0.6 ≤ x ≤ 1.8)
journal, November 2013

  • Schäfer, Marion C.; Bobev, Svilen
  • Acta Crystallographica Section C Crystal Structure Communications, Vol. 69, Issue 12
  • DOI: 10.1107/S0108270113030011

Synthesis and single-crystal X-ray diffraction studies of new framework substituted type II clathrates, Cs8Na16AgxGe136−x (x<7)
journal, March 2007


Precursor routes to quaternary intermetallics: Synthesis, crystal structure, and physical properties of clathrate-II Cs8Na16Al24Si112
journal, May 2016


A Combined Metal-Halide/Metal Flux Synthetic Route towards Type-I Clathrates: Crystal Structures and Thermoelectric Properties of A 8 Al 8 Si 38 (A=K, Rb, and Cs)
journal, September 2014

  • Baran, Volodymyr; Senyshyn, Anatoliy; Karttunen, Antti J.
  • Chemistry - A European Journal, Vol. 20, Issue 46
  • DOI: 10.1002/chem.201403416

New Type-I and Type-II Clathrates in the Systems Cs–Na–Ga–Si, Rb–Na–Ga–Si, and Rb–Na–Zn–Si
journal, March 2014


Synthesis, Structural Characterization, and Physical Properties of the Type-I Clathrates A 8 Zn 18 As 28 ( A = K, Rb, Cs) and Cs 8 Cd 18 As 28
journal, September 2012

  • He, Hua; Zevalkink, Alex; Gibbs, Zachary M.
  • Chemistry of Materials, Vol. 24, Issue 18
  • DOI: 10.1021/cm3020226

Thermoelectric clathrates of type I
journal, January 2010

  • Christensen, Mogens; Johnsen, Simon; Iversen, Bo Brummerstedt
  • Dalton Trans., Vol. 39, Issue 4
  • DOI: 10.1039/B916400F

Significance tests on the crystallographic R factor
journal, May 1965


Synthesis and Characterization of Stable Stoichiometric Clathrates of Silicon and Germanium:  Cs 8 Na 16 Si 136 and Cs 8 Na 16 Ge 136
journal, April 1999

  • Bobev, Svilen; Sevov, Slavi C.
  • Journal of the American Chemical Society, Vol. 121, Issue 15
  • DOI: 10.1021/ja9844175

Tin Clathrates with the Type II Structure
journal, January 2013

  • Schäfer, Marion C.; Bobev, Svilen
  • Journal of the American Chemical Society, Vol. 135, Issue 5
  • DOI: 10.1021/ja3112934