skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation with a Ni(PS)2 Complex

Authors:
 [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry, University of Louisville, 2320 South Brook Street 40292 Louisville KY USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1377932
Grant/Contract Number:  
FG02-08CH11538
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
European Journal of Inorganic Chemistry
Additional Journal Information:
Journal Name: European Journal of Inorganic Chemistry Journal Volume: 2017 Journal Issue: 31; Journal ID: ISSN 1434-1948
Publisher:
ChemPubSoc Europe
Country of Publication:
Germany
Language:
English

Citation Formats

Jain, Rahul, Mashuta, Mark S., Buchanan, Robert M., and Grapperhaus, Craig A. Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation with a Ni(PS)2 Complex. Germany: N. p., 2017. Web. doi:10.1002/ejic.201700590.
Jain, Rahul, Mashuta, Mark S., Buchanan, Robert M., & Grapperhaus, Craig A. Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation with a Ni(PS)2 Complex. Germany. doi:10.1002/ejic.201700590.
Jain, Rahul, Mashuta, Mark S., Buchanan, Robert M., and Grapperhaus, Craig A. Fri . "Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation with a Ni(PS)2 Complex". Germany. doi:10.1002/ejic.201700590.
@article{osti_1377932,
title = {Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation with a Ni(PS)2 Complex},
author = {Jain, Rahul and Mashuta, Mark S. and Buchanan, Robert M. and Grapperhaus, Craig A.},
abstractNote = {},
doi = {10.1002/ejic.201700590},
journal = {European Journal of Inorganic Chemistry},
number = 31,
volume = 2017,
place = {Germany},
year = {2017},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/ejic.201700590

Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Proposed Ligand-Centered Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation at a Noninnocent Mononuclear Metal–Thiolate
journal, July 2015

  • Haddad, Andrew Z.; Kumar, Davinder; Ouch Sampson, Kagna
  • Journal of the American Chemical Society, Vol. 137, Issue 29
  • DOI: 10.1021/jacs.5b05561

Synthesis and electrocatalytic function for hydrogen generation of cobalt and nickel complexes supported by phenylenediamine ligand
journal, October 2016


Metal-Stabilized Thiyl Radicals as Scaffolds for Reversible Alkene Addition via C–S Bond Formation/Cleavage
journal, October 2011

  • Ouch, Kagna; Mashuta, Mark S.; Grapperhaus, Craig A.
  • Inorganic Chemistry, Vol. 50, Issue 20
  • DOI: 10.1021/ic200416y

A short history of SHELX
journal, December 2007

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
  • DOI: 10.1107/S0108767307043930

Determining the Overpotential for a Molecular Electrocatalyst
journal, December 2013

  • Appel, Aaron M.; Helm, Monte L.
  • ACS Catalysis, Vol. 4, Issue 2
  • DOI: 10.1021/cs401013v

Molecular mechanisms of cobalt-catalyzed hydrogen evolution
journal, September 2012

  • Marinescu, S. C.; Winkler, J. R.; Gray, H. B.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 38
  • DOI: 10.1073/pnas.1213442109

Rapid and Reversible Reactions of [NiFe]-Hydrogenases with Sulfide
journal, June 2006

  • Vincent, Kylie A.; Belsey, Natalie A.; Lubitz, Wolfgang
  • Journal of the American Chemical Society, Vol. 128, Issue 23
  • DOI: 10.1021/ja061732f

o-Lithiothiophenol equivalents. Generation, reactions and applications in synthesis of hindered thiolate ligands
journal, January 1989

  • Block, Eric; Eswarakrishnan, Venkatachalam; Gernon, Michael
  • Journal of the American Chemical Society, Vol. 111, Issue 2
  • DOI: 10.1021/ja00184a039

2-Phosphino- and 2-phosphinylbenzenethiols: new ligand types
journal, March 1989

  • Block, Eric; Ofori-Okai, Gabriel; Zubieta, Jon
  • Journal of the American Chemical Society, Vol. 111, Issue 6
  • DOI: 10.1021/ja00188a071

Beyond Metal-Hydrides: Non-Transition-Metal and Metal-Free Ligand-Centered Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation
journal, June 2016

  • Haddad, Andrew Z.; Garabato, Brady D.; Kozlowski, Pawel M.
  • Journal of the American Chemical Society, Vol. 138, Issue 25
  • DOI: 10.1021/jacs.6b04441

Nickel Complexes for Robust Light-Driven and Electrocatalytic Hydrogen Production from Water
journal, January 2015


Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides
journal, June 2016


From The Cover: Electrocatalytic hydrogen oxidation by an enzyme at high carbon monoxide or oxygen levels
journal, October 2005

  • Vincent, K. A.; Cracknell, J. A.; Lenz, O.
  • Proceedings of the National Academy of Sciences, Vol. 102, Issue 47, p. 16951-16954
  • DOI: 10.1073/pnas.0504499102

Characteristics of Nickel(0), Nickel(I), and Nickel(II) in Phosphino Thioether Complexes:  Molecular Structure and S -Dealkylation of (Ph 2 P( o -C 6 H 4 )SCH 3 ) 2 Ni 0
journal, January 1996

  • Kim, Jang Sub; Reibenspies, Joseph H.; Darensbourg, Marcetta Y.
  • Journal of the American Chemical Society, Vol. 118, Issue 17
  • DOI: 10.1021/ja953686h

Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N -Heterocyclic Carbene–Isoquinoline Complex
journal, September 2013

  • Thoi, V. Sara; Kornienko, Nikolay; Margarit, Charles G.
  • Journal of the American Chemical Society, Vol. 135, Issue 38
  • DOI: 10.1021/ja4074003

Size- and Shape-Dependent Activity of Metal Nanoparticles as Hydrogen-Evolution Catalysts: Mechanistic Insights into Photocatalytic Hydrogen Evolution
journal, January 2011

  • Kotani, Hiroaki; Hanazaki, Ryo; Ohkubo, Kei
  • Chemistry - A European Journal, Vol. 17, Issue 9
  • DOI: 10.1002/chem.201002399

Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species
journal, January 2015

  • Martin, Daniel J.; McCarthy, Brian D.; Donley, Carrie L.
  • Chemical Communications, Vol. 51, Issue 25
  • DOI: 10.1039/C4CC08662G

Synthesis and electrochemical properties of a water soluble nickel(II) complex supported by N-phenylpyridin-2-ylmethanimine ligand
journal, August 2017


Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds
journal, November 2010

  • Cook, Timothy R.; Dogutan, Dilek K.; Reece, Steven Y.
  • Chemical Reviews, Vol. 110, Issue 11
  • DOI: 10.1021/cr100246c

Earth-abundant hydrogen evolution electrocatalysts
journal, January 2014

  • McKone, James R.; Marinescu, Smaranda C.; Brunschwig, Bruce S.
  • Chem. Sci., Vol. 5, Issue 3
  • DOI: 10.1039/C3SC51711J

Metal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids
journal, January 2016

  • Lawrence, Elliot J.; Clark, Ewan R.; Curless, Liam D.
  • Chemical Science, Vol. 7, Issue 4
  • DOI: 10.1039/C5SC04564A

Sacrificial electron donor reagents for solar fuel production
journal, March 2017


Metal Complexes (M = Zn, Sn, and Pb) of 2-Phosphinobenzenethiolates: Insights into Ligand Folding and Hemilability
journal, August 2013

  • Barry, Brian M.; Stein, Benjamin W.; Larsen, Christopher A.
  • Inorganic Chemistry, Vol. 52, Issue 17
  • DOI: 10.1021/ic400990n

ORTEP -3 for Windows - a version of ORTEP -III with a Graphical User Interface (GUI)
journal, October 1997


Electrochemical Oxidation of Aliphatic Amines and Their Attachment to Carbon and Metal Surfaces
journal, September 2004

  • Adenier, Alain; Chehimi, Mohamed M.; Gallardo, Iluminada
  • Langmuir, Vol. 20, Issue 19
  • DOI: 10.1021/la049194c

Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels
journal, December 2009

  • Morris, Amanda J.; Meyer, Gerald J.; Fujita, Etsuko
  • Accounts of Chemical Research, Vol. 42, Issue 12
  • DOI: 10.1021/ar9001679

Hydrogen Production under Aerobic Conditions by Membrane-Bound Hydrogenases from Ralstonia Species
journal, August 2008

  • Goldet, Gabrielle; Wait, Annemarie F.; Cracknell, James A.
  • Journal of the American Chemical Society, Vol. 130, Issue 33
  • DOI: 10.1021/ja8027668

Development of Molecular Electrocatalysts for Energy Storage
journal, February 2014