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Title: Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in nitric acid

Eichrom’s Pb resin, a crown-ether-based extraction chromatography resin, was characterized for separation of the flerovium (Fl) homologs, Pb and Sn. Batch uptake of Pb(II) and Sn(IV) radionuclides was determined from an HNO 3 matrix. Pb(II) was strongly retained on the resin at all HNO 3 concentrations, while Sn(IV) showed no uptake. Extraction kinetics for Pb(II) were examined and show suitable uptake on the second time scale. Here, separation methods for the isolation of individual homologs, Pb(II) and Sn(IV), have been established using 2 mL pre-packed vacuum flow Pb resin columns.
Authors:
 [1] ;  [2] ;  [3] ;  [3] ;  [3] ;  [3] ;  [4]
  1. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Univ. of Nevada, Las Vegas, NV (United States)
  2. Univ. of California, Berkeley, CA (United States)
  3. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
  4. Univ. of Nevada, Las Vegas, NV (United States)
Publication Date:
Report Number(s):
LLNL-JRNL-696830
Journal ID: ISSN 0236-5731
Grant/Contract Number:
AC52-07NA27344
Type:
Accepted Manuscript
Journal Name:
Journal of Radioanalytical and Nuclear Chemistry
Additional Journal Information:
Journal Volume: 311; Journal Issue: 1; Journal ID: ISSN 0236-5731
Publisher:
Springer
Research Org:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1377776

Despotopulos, John D., Kmak, Kelly N., Gharibyan, Narek, Henderson, Roger A., Moody, Kenton J., Shaughnessy, Dawn A., and Sudowe, Ralf. Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in nitric acid. United States: N. p., Web. doi:10.1007/s10967-016-5038-4.
Despotopulos, John D., Kmak, Kelly N., Gharibyan, Narek, Henderson, Roger A., Moody, Kenton J., Shaughnessy, Dawn A., & Sudowe, Ralf. Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in nitric acid. United States. doi:10.1007/s10967-016-5038-4.
Despotopulos, John D., Kmak, Kelly N., Gharibyan, Narek, Henderson, Roger A., Moody, Kenton J., Shaughnessy, Dawn A., and Sudowe, Ralf. 2016. "Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in nitric acid". United States. doi:10.1007/s10967-016-5038-4. https://www.osti.gov/servlets/purl/1377776.
@article{osti_1377776,
title = {Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in nitric acid},
author = {Despotopulos, John D. and Kmak, Kelly N. and Gharibyan, Narek and Henderson, Roger A. and Moody, Kenton J. and Shaughnessy, Dawn A. and Sudowe, Ralf},
abstractNote = {Eichrom’s Pb resin, a crown-ether-based extraction chromatography resin, was characterized for separation of the flerovium (Fl) homologs, Pb and Sn. Batch uptake of Pb(II) and Sn(IV) radionuclides was determined from an HNO3 matrix. Pb(II) was strongly retained on the resin at all HNO3 concentrations, while Sn(IV) showed no uptake. Extraction kinetics for Pb(II) were examined and show suitable uptake on the second time scale. Here, separation methods for the isolation of individual homologs, Pb(II) and Sn(IV), have been established using 2 mL pre-packed vacuum flow Pb resin columns.},
doi = {10.1007/s10967-016-5038-4},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
number = 1,
volume = 311,
place = {United States},
year = {2016},
month = {9}
}