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Title: Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in nitric acid

Abstract

Eichrom’s Pb resin, a crown-ether-based extraction chromatography resin, was characterized for separation of the flerovium (Fl) homologs, Pb and Sn. Batch uptake of Pb(II) and Sn(IV) radionuclides was determined from an HNO3 matrix. Pb(II) was strongly retained on the resin at all HNO3 concentrations, while Sn(IV) showed no uptake. Extraction kinetics for Pb(II) were examined and show suitable uptake on the second time scale. Here, separation methods for the isolation of individual homologs, Pb(II) and Sn(IV), have been established using 2 mL pre-packed vacuum flow Pb resin columns.

Authors:
 [1];  [2];  [3];  [3];  [3];  [3];  [4]
+ Show Author Affiliations
  1. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Univ. of Nevada, Las Vegas, NV (United States)
  2. Univ. of California, Berkeley, CA (United States)
  3. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
  4. Univ. of Nevada, Las Vegas, NV (United States)
Publication Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1377776
Report Number(s):
LLNL-JRNL-696830
Journal ID: ISSN 0236-5731
Grant/Contract Number:  
AC52-07NA27344
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Radioanalytical and Nuclear Chemistry
Additional Journal Information:
Journal Volume: 311; Journal Issue: 1; Journal ID: ISSN 0236-5731
Publisher:
Springer
Country of Publication:
United States
Language:
English
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

Citation Formats

Despotopulos, John D., Kmak, Kelly N., Gharibyan, Narek, Henderson, Roger A., Moody, Kenton J., Shaughnessy, Dawn A., and Sudowe, Ralf. Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in nitric acid. United States: N. p., 2016. Web. doi:10.1007/s10967-016-5038-4.
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Despotopulos, John D., Kmak, Kelly N., Gharibyan, Narek, Henderson, Roger A., Moody, Kenton J., Shaughnessy, Dawn A., & Sudowe, Ralf. Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in nitric acid. United States. https://doi.org/10.1007/s10967-016-5038-4
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Despotopulos, John D., Kmak, Kelly N., Gharibyan, Narek, Henderson, Roger A., Moody, Kenton J., Shaughnessy, Dawn A., and Sudowe, Ralf. Sat . "Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in nitric acid". United States. https://doi.org/10.1007/s10967-016-5038-4. https://www.osti.gov/servlets/purl/1377776.
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@article{osti_1377776,
title = {Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in nitric acid},
author = {Despotopulos, John D. and Kmak, Kelly N. and Gharibyan, Narek and Henderson, Roger A. and Moody, Kenton J. and Shaughnessy, Dawn A. and Sudowe, Ralf},
abstractNote = {Eichrom’s Pb resin, a crown-ether-based extraction chromatography resin, was characterized for separation of the flerovium (Fl) homologs, Pb and Sn. Batch uptake of Pb(II) and Sn(IV) radionuclides was determined from an HNO3 matrix. Pb(II) was strongly retained on the resin at all HNO3 concentrations, while Sn(IV) showed no uptake. Extraction kinetics for Pb(II) were examined and show suitable uptake on the second time scale. Here, separation methods for the isolation of individual homologs, Pb(II) and Sn(IV), have been established using 2 mL pre-packed vacuum flow Pb resin columns.},
doi = {10.1007/s10967-016-5038-4},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
number = 1,
volume = 311,
place = {United States},
year = {Sat Sep 17 00:00:00 EDT 2016},
month = {Sat Sep 17 00:00:00 EDT 2016}
}
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Journal Article:
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Publisher's Version of Record
https://doi.org/10.1007/s10967-016-5038-4
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Works referenced in this record:

Production and isolation of homologs of flerovium and element 115 at the Lawrence Livermore National Laboratory Center for Accelerator Mass Spectrometry
journal, October 2015

  • Despotopulos, John D.; Kmak, Kelly N.; Gharibyan, Narek
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 308, Issue 2
  • DOI: 10.1007/s10967-015-4500-z

A lead-selective extraction chromatographic resin and its application to the isolation of lead from geological samples
journal, July 1994

Superheavy nuclei from 48Ca-induced reactions
journal, December 2015

The preparation, performance and factors affecting band spreading of high efficiency extraction chromatographic columns for actinide separations
journal, December 1972

The Stability of the Oxidation State +4 in Group 14 Compounds from Carbon to Element 114
journal, October 1998

Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in hydrochloric acid
journal, June 2016

  • Despotopulos, John D.; Kmak, Kelly N.; Gharibyan, Narek
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 310, Issue 3
  • DOI: 10.1007/s10967-016-4917-z
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