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Title: Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution

Abstract

A “bare” V5+ complex with glutaroimide-dioxime (H3L), a ligand for uranium recovery from seawater, was synthesized from aqueous solution as Na[V(L)2]2H2O and the structure determined by x-ray diffraction. It is the first non-oxo V(v) complex that has been directly synthesized in and crystallized from aqueous solution.

Authors:
 [1];  [2];  [3];  [1];  [1];  [1];  [4];  [5];  [4];  [1];  [2];  [1]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division; Univ. of California, Berkeley, CA (United States). Dept. of Chemistry
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  4. Pacific Northwest National Lab. (PNNL), Richland, WA (United States). National Security Directorate
  5. Fundamental and Computational Sciences Directorate; Pacific Northwest National Laboratory; Richland, USA
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Nuclear Energy (NE)
OSTI Identifier:
1377416
Alternate Identifier(s):
OSTI ID: 1337242
Report Number(s):
PNNL-SA-112588
Journal ID: ISSN 2041-6520; CSHCBM; ark:/13030/qt2p03j1ms
Grant/Contract Number:  
AC02-05CH11231; AC05-76RL01830
Resource Type:
Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 7; Journal Issue: 4; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; vanadium; uranium; seawater; amidoxime; XRD

Citation Formats

Leggett, C. J., Parker, B. F., Teat, S. J., Zhang, Z., Dau, P. D., Lukens, W. W., Peterson, S. M., Cardenas, A. J. P., Warner, M. G., Gibson, J. K., Arnold, J., and Rao, L. Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution. United States: N. p., 2016. Web. doi:10.1039/c5sc03958d.
Leggett, C. J., Parker, B. F., Teat, S. J., Zhang, Z., Dau, P. D., Lukens, W. W., Peterson, S. M., Cardenas, A. J. P., Warner, M. G., Gibson, J. K., Arnold, J., & Rao, L. Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution. United States. https://doi.org/10.1039/c5sc03958d
Leggett, C. J., Parker, B. F., Teat, S. J., Zhang, Z., Dau, P. D., Lukens, W. W., Peterson, S. M., Cardenas, A. J. P., Warner, M. G., Gibson, J. K., Arnold, J., and Rao, L. Thu . "Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution". United States. https://doi.org/10.1039/c5sc03958d. https://www.osti.gov/servlets/purl/1377416.
@article{osti_1377416,
title = {Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution},
author = {Leggett, C. J. and Parker, B. F. and Teat, S. J. and Zhang, Z. and Dau, P. D. and Lukens, W. W. and Peterson, S. M. and Cardenas, A. J. P. and Warner, M. G. and Gibson, J. K. and Arnold, J. and Rao, L.},
abstractNote = {A “bare” V5+ complex with glutaroimide-dioxime (H3L), a ligand for uranium recovery from seawater, was synthesized from aqueous solution as Na[V(L)2]2H2O and the structure determined by x-ray diffraction. It is the first non-oxo V(v) complex that has been directly synthesized in and crystallized from aqueous solution.},
doi = {10.1039/c5sc03958d},
journal = {Chemical Science},
number = 4,
volume = 7,
place = {United States},
year = {2016},
month = {1}
}

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