Magnesium-ion battery-relevant electrochemistry of MgMn2O4: crystallite size effects and the notable role of electrolyte water content
Abstract
MgMn2O4 nanoparticles with crystallite sizes of 11 (MMO-1) and 31 nm (MMO-2) were synthesized and their magnesium-ion battery-relevant electrochemistry was investigated. Here, MMO-1 delivered an initial capacity of 220 mA h g–1 (678 mW h g–1). Electrolyte water content had a profound effect on cycle retention.
- Authors:
-
[1];
- Stony Brook Univ., Stony Brook, NY (United States)
- Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Electricity (OE); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1376671
- Report Number(s):
- BNL-114103-2017-JA
Journal ID: ISSN 1359-7345; CHCOFS
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 53; Journal Issue: 26; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Yin, Jiefu, Brady, Alexander B., Takeuchi, Esther S., Marschilok, Amy C., and Takeuchi, Kenneth J. Magnesium-ion battery-relevant electrochemistry of MgMn2O4: crystallite size effects and the notable role of electrolyte water content. United States: N. p., 2017.
Web. doi:10.1039/c7cc00265c.
Yin, Jiefu, Brady, Alexander B., Takeuchi, Esther S., Marschilok, Amy C., & Takeuchi, Kenneth J. Magnesium-ion battery-relevant electrochemistry of MgMn2O4: crystallite size effects and the notable role of electrolyte water content. United States. https://doi.org/10.1039/c7cc00265c
Yin, Jiefu, Brady, Alexander B., Takeuchi, Esther S., Marschilok, Amy C., and Takeuchi, Kenneth J. Mon .
"Magnesium-ion battery-relevant electrochemistry of MgMn2O4: crystallite size effects and the notable role of electrolyte water content". United States. https://doi.org/10.1039/c7cc00265c. https://www.osti.gov/servlets/purl/1376671.
@article{osti_1376671,
title = {Magnesium-ion battery-relevant electrochemistry of MgMn2O4: crystallite size effects and the notable role of electrolyte water content},
author = {Yin, Jiefu and Brady, Alexander B. and Takeuchi, Esther S. and Marschilok, Amy C. and Takeuchi, Kenneth J.},
abstractNote = {MgMn2O4 nanoparticles with crystallite sizes of 11 (MMO-1) and 31 nm (MMO-2) were synthesized and their magnesium-ion battery-relevant electrochemistry was investigated. Here, MMO-1 delivered an initial capacity of 220 mA h g–1 (678 mW h g–1). Electrolyte water content had a profound effect on cycle retention.},
doi = {10.1039/c7cc00265c},
journal = {ChemComm},
number = 26,
volume = 53,
place = {United States},
year = {Mon Mar 06 00:00:00 EST 2017},
month = {Mon Mar 06 00:00:00 EST 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 65 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Effective ionic radii in oxides and fluorides
journal, May 1969
- Shannon, R. D.; Prewitt, C. T.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 25, Issue 5
How General is the Conversion Reaction in Mg Battery Cathode: A Case Study of the Magnesiation of α-MnO 2
journal, August 2015
- Ling, Chen; Zhang, Ruigang; Arthur, Timothy S.
- Chemistry of Materials, Vol. 27, Issue 16
Role of Structural H 2 O in Intercalation Electrodes: The Case of Mg in Nanocrystalline Xerogel-V 2 O 5
journal, March 2016
- Sai Gautam, Gopalakrishnan; Canepa, Pieremanuele; Richards, William Davidson
- Nano Letters, Vol. 16, Issue 4
Express and low-cost microwave synthesis of the ternary Chevrel phase Cu2Mo6S8 for application in rechargeable magnesium batteries
journal, October 2016
- Murgia, Fabrizio; Antitomaso, Philippe; Stievano, Lorenzo
- Journal of Solid State Chemistry, Vol. 242
RF sputtering deposition of MgMn 2 O 4 spinel thin films
journal, March 2004
- Malavasi, L.; Mozzati, M. C.; Chiodelli, G.
- Journal of Materials Science, Vol. 39, Issue 5
Communication—Sol-Gel Synthesized Magnesium Vanadium Oxide, Mg x V 2 O 5 · nH 2 O: The Role of Structural Mg 2+ on Battery Performance
journal, January 2016
- Yin, Jiefu; Pelliccione, Christopher J.; Lee, Shu Han
- Journal of The Electrochemical Society, Vol. 163, Issue 9
Advanced hybrid battery with a magnesium metal anode and a spinel LiMn 2 O 4 cathode
journal, January 2016
- Pan, Baofei; Feng, Zhenxing; Sa, Niya
- Chemical Communications, Vol. 52, Issue 64
Hydrothermal synthesis of LiMn2O4/C composite as a cathode for rechargeable lithium-ion battery with excellent rate capability
journal, September 2009
- Yue, HongJun; Huang, XingKang; Lv, DongPing
- Electrochimica Acta, Vol. 54, Issue 23
Phase Diagram of Mg Insertion into Chevrel Phases, Mg x Mo 6 T 8 (T = S, Se). 1. Crystal Structure of the Sulfides
journal, November 2006
- Levi, E.; Lancry, E.; Mitelman, A.
- Chemistry of Materials, Vol. 18, Issue 23
Comparison of Metal Ion Dissolutions from Lithium Ion Battery Cathodes
journal, January 2006
- Choi, W.; Manthiram, A.
- Journal of The Electrochemical Society, Vol. 153, Issue 9
Critical Evaluation and Thermodynamic Modeling of the Mg-Mn-O (MgO-MnO-MnO 2 ) System
journal, July 2014
- Panda, Sourav Kumar; Jung, In-Ho
- Journal of the American Ceramic Society, Vol. 97, Issue 10
Solvation of Mg2+ ions in methanol–water mixtures: Molecular dynamics simulation
journal, May 2012
- Rybicki, Marcin; Hawlicka, Ewa
- Chemical Physics, Vol. 400
The Coupling between Stability and Ion Pair Formation in Magnesium Electrolytes from First-Principles Quantum Mechanics and Classical Molecular Dynamics
journal, February 2015
- Rajput, Nav Nidhi; Qu, Xiaohui; Sa, Niya
- Journal of the American Chemical Society, Vol. 137, Issue 9, p. 3411-3420
Electrochemical Conversion of LiMn[sub 2]O[sub 4] to MgMn[sub 2]O[sub 4] in Aqueous Electrolytes
journal, January 2008
- Sinha, Nupur Nikkan; Munichandraiah, N.
- Electrochemical and Solid-State Letters, Vol. 11, Issue 11
Prototype systems for rechargeable magnesium batteries
journal, October 2000
- Aurbach, D.; Lu, Z.; Schechter, A.
- Nature, Vol. 407, Issue 6805, p. 724-727
Synthetic control of manganese birnessite: Impact of crystallite size on Li, Na, and Mg based electrochemistry
journal, November 2016
- Yin, Jiefu; Takeuchi, Esther S.; Takeuchi, Kenneth J.
- Inorganica Chimica Acta, Vol. 453
Solvation Structures and Dynamics of the Magnesium Chloride (Mg 2+ –Cl – ) Ion Pair in Water–Ethanol Mixtures
journal, July 2013
- Chatterjee, Anupam; Dixit, Mayank Kumar; Tembe, B. L.
- The Journal of Physical Chemistry A, Vol. 117, Issue 36
Sol Gel Based Synthesis and Electrochemistry of Magnesium Vanadium Oxide: A Promising Cathode Material for Secondary Magnesium Ion Batteries
journal, January 2014
- Lee, S. H.; DiLeo, R. A.; Marschilok, A. C.
- ECS Electrochemistry Letters, Vol. 3, Issue 8
Solvothermal synthesis of GO/V 2 O 5 composites as a cathode material for rechargeable magnesium batteries
journal, January 2015
- Du, Xinchuan; Huang, Gang; Qin, Yuling
- RSC Advances, Vol. 5, Issue 93
Investigation of the Mechanism of Mg Insertion in Birnessite in Nonaqueous and Aqueous Rechargeable Mg-Ion Batteries
journal, January 2016
- Sun, Xiaoqi; Duffort, Victor; Mehdi, B. Layla
- Chemistry of Materials, Vol. 28, Issue 2
α-MnO2 as a cathode material for rechargeable Mg batteries
journal, September 2012
- Zhang, Ruigang; Yu, Xiqian; Nam, Kyung-Wan
- Electrochemistry Communications, Vol. 23
Raman spectroscopy of AMn2O4 (A = Mn, Mg and Zn) spinels
journal, June 2002
- Malavasi, Lorenzo; Galinetto, Pietro; Mozzati, Maria C.
- Physical Chemistry Chemical Physics, Vol. 4, Issue 15
High capacity positive electrodes for secondary Mg-ion batteries
journal, November 2012
- Rasul, Shahid; Suzuki, Shinya; Yamaguchi, Shu
- Electrochimica Acta, Vol. 82
Mg Intercalation Properties into V[sub 2]O[sub 5] gel/Carbon Composites under High-Rate Condition
journal, January 2003
- Imamura, Daichi; Miyayama, Masaru; Hibino, Mitsuhiro
- Journal of The Electrochemical Society, Vol. 150, Issue 6
Activation of a MnO 2 cathode by water-stimulated Mg 2+ insertion for a magnesium ion battery
journal, January 2015
- Song, Jaehee; Noked, Malakhi; Gillette, Eleanor
- Physical Chemistry Chemical Physics, Vol. 17, Issue 7
Structural and Transport Properties of Mg1−xMnxMn2O4±δ Spinels
journal, June 2002
- Malavasi, Lorenzo; Ghigna, Paolo; Chiodelli, Gaetano
- Journal of Solid State Chemistry, Vol. 166, Issue 1
Composite Anodes for Secondary Magnesium Ion Batteries Prepared via Electrodeposition of Nanostructured Bismuth on Carbon Nanotube Substrates
journal, October 2014
- DiLeo, R. A.; Zhang, Q.; Marschilok, A. C.
- ECS Electrochemistry Letters, Vol. 4, Issue 1
High-pressure stability of the tetragonal spinel : Role of inversion
journal, May 2005
- Malavasi, Lorenzo; Tealdi, Cristina; Flor, Giorgio
- Physical Review B, Vol. 71, Issue 17
Cathode materials for magnesium and magnesium-ion based batteries
journal, March 2015
- Huie, Matthew M.; Bock, David C.; Takeuchi, Esther S.
- Coordination Chemistry Reviews, Vol. 287
Electrochemical and chemical insertion/deinsertion of magnesium in spinel-type MgMn 2 O 4 and lambda-MnO 2 for both aqueous and non-aqueous magnesium-ion batteries
journal, January 2015
- Cabello, M.; Alcántara, R.; Nacimiento, F.
- CrystEngComm, Vol. 17, Issue 45
Porous Manganese Oxide Octahedral Molecular Sieves and Octahedral Layered Materials
journal, April 2008
- Suib, Steven L.
- Accounts of Chemical Research, Vol. 41, Issue 4
Nanostructured cathode materials for rechargeable lithium batteries
journal, June 2015
- Myung, Seung-Taek; Amine, Khalil; Sun, Yang-Kook
- Journal of Power Sources, Vol. 283
Understanding the Electrochemical Mechanism of K-αMnO 2 for Magnesium Battery Cathodes
journal, May 2014
- Arthur, Timothy S.; Zhang, Ruigang; Ling, Chen
- ACS Applied Materials & Interfaces, Vol. 6, Issue 10
The High Performance of Crystal Water Containing Manganese Birnessite Cathodes for Magnesium Batteries
journal, May 2015
- Nam, Kwan Woo; Kim, Sangryun; Lee, Soyeon
- Nano Letters, Vol. 15, Issue 6
M x Mn 8 O 16 (M = Ag or K) as promising cathode materials for secondary Mg based batteries: the role of the cation M
journal, January 2016
- Huang, Jianping; Poyraz, Altug S.; Takeuchi, Kenneth J.
- Chemical Communications, Vol. 52, Issue 21
On the Utility of Spinel Oxide Hosts for Magnesium-Ion Batteries
journal, October 2015
- Knight, James C.; Therese, Soosairaj; Manthiram, Arumugam
- ACS Applied Materials & Interfaces, Vol. 7, Issue 41
Electrolyte roadblocks to a magnesium rechargeable battery
journal, January 2012
- Muldoon, John; Bucur, Claudiu B.; Oliver, Allen G.
- Energy & Environmental Science, Vol. 5, Issue 3, p. 5941-5950
Structural Changes in MgMn2O4 at High Temperatures
journal, January 1965
- Mănăilă, R.; Păuşescu, P.
- physica status solidi (b), Vol. 9, Issue 2
Atomic layer coating to mitigate capacity fading associated with manganese dissolution in lithium ion batteries
journal, July 2013
- Xiao, Xingcheng; Ahn, Dongjoon; Liu, Zhongyi
- Electrochemistry Communications, Vol. 32
Phase Stability of Post-spinel Compound AMn 2 O 4 (A = Li, Na, or Mg) and Its Application as a Rechargeable Battery Cathode
journal, July 2013
- Ling, Chen; Mizuno, Fuminori
- Chemistry of Materials, Vol. 25, Issue 15
Synthetic Routes to Microporous Manganese Oxides
journal, October 1997
- Ching, Stanton; Suib, Steven L.
- Comments on Inorganic Chemistry, Vol. 19, Issue 5
Works referencing / citing this record:
MgSc 2 Se 4 —A Magnesium Solid Ionic Conductor for All‐Solid‐State Mg Batteries?
journal, April 2019
- Wang, Li‐Ping; Zhao‐Karger, Zhirong; Klein, Franziska
- ChemSusChem, Vol. 12, Issue 10
Electrolyte Evolution Propelling the Development of Nonlithium Metal–Sulfur Batteries
journal, May 2019
- Pan, Yuede; Li, Suli; Yin, Miaomiao
- Energy Technology, Vol. 7, Issue 12
High magnesium mobility in ternary spinel chalcogenides
journal, November 2017
- Canepa, Pieremanuele; Bo, Shou-Hang; Sai Gautam, Gopalakrishnan
- Nature Communications, Vol. 8, Issue 1
Superior high rate capability of MgMn 2 O 4 /rGO nanocomposites as cathode materials for aqueous rechargeable magnesium ion batteries
journal, January 2018
- Liu, Guang; Chi, Qingguo; Zhang, Yongquan
- Chemical Communications, Vol. 54, Issue 68
Three-dimensional hollow spheres of the tetragonal-spinel MgMn 2 O 4 cathode for high-performance magnesium ion batteries
journal, January 2018
- Tao, Shi; Huang, Weifeng; Liu, Yushen
- Journal of Materials Chemistry A, Vol. 6, Issue 18
Hollow-sphere iron oxides exhibiting enhanced cycling performance as lithium-ion battery anodes
journal, January 2019
- Ren, Qingqing; Zhang, Yaping; Liu, Chang
- Chemical Communications, Vol. 55, Issue 77
Rapid room-temperature synthesis of ultrasmall cubic Mg–Mn spinel cathode materials for rechargeable Mg-ion batteries
journal, January 2019
- Kobayashi, Hiroaki; Yamaguchi, Kazuya; Honma, Itaru
- RSC Advances, Vol. 9, Issue 62