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Title: Magnesium-ion battery-relevant electrochemistry of MgMn 2O 4: crystallite size effects and the notable role of electrolyte water content

Abstract

MgMn 2O 4 nanoparticles with crystallite sizes of 11 (MMO-1) and 31 nm (MMO-2) were synthesized and their magnesium-ion battery-relevant electrochemistry was investigated. Here, MMO-1 delivered an initial capacity of 220 mA h g –1 (678 mW h g –1). Electrolyte water content had a profound effect on cycle retention.

Authors:
 [1];  [1];  [2]; ORCiD logo [1];  [1]
  1. Stony Brook Univ., Stony Brook, NY (United States)
  2. Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Electricity Delivery and Energy Reliability (OE); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1376671
Report Number(s):
BNL-114103-2017-JA
Journal ID: ISSN 1359-7345; CHCOFS
Grant/Contract Number:  
SC00112704
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 53; Journal Issue: 26; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Yin, Jiefu, Brady, Alexander B., Takeuchi, Esther S., Marschilok, Amy C., and Takeuchi, Kenneth J. Magnesium-ion battery-relevant electrochemistry of MgMn2O4: crystallite size effects and the notable role of electrolyte water content. United States: N. p., 2017. Web. doi:10.1039/c7cc00265c.
Yin, Jiefu, Brady, Alexander B., Takeuchi, Esther S., Marschilok, Amy C., & Takeuchi, Kenneth J. Magnesium-ion battery-relevant electrochemistry of MgMn2O4: crystallite size effects and the notable role of electrolyte water content. United States. doi:10.1039/c7cc00265c.
Yin, Jiefu, Brady, Alexander B., Takeuchi, Esther S., Marschilok, Amy C., and Takeuchi, Kenneth J. Mon . "Magnesium-ion battery-relevant electrochemistry of MgMn2O4: crystallite size effects and the notable role of electrolyte water content". United States. doi:10.1039/c7cc00265c. https://www.osti.gov/servlets/purl/1376671.
@article{osti_1376671,
title = {Magnesium-ion battery-relevant electrochemistry of MgMn2O4: crystallite size effects and the notable role of electrolyte water content},
author = {Yin, Jiefu and Brady, Alexander B. and Takeuchi, Esther S. and Marschilok, Amy C. and Takeuchi, Kenneth J.},
abstractNote = {MgMn2O4 nanoparticles with crystallite sizes of 11 (MMO-1) and 31 nm (MMO-2) were synthesized and their magnesium-ion battery-relevant electrochemistry was investigated. Here, MMO-1 delivered an initial capacity of 220 mA h g–1 (678 mW h g–1). Electrolyte water content had a profound effect on cycle retention.},
doi = {10.1039/c7cc00265c},
journal = {ChemComm},
number = 26,
volume = 53,
place = {United States},
year = {2017},
month = {3}
}

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Cited by: 9 works
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Works referenced in this record:

Effective ionic radii in oxides and fluorides
journal, May 1969

  • Shannon, R. D.; Prewitt, C. T.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 25, Issue 5
  • DOI: 10.1107/S0567740869003220

How General is the Conversion Reaction in Mg Battery Cathode: A Case Study of the Magnesiation of α-MnO 2
journal, August 2015


Role of Structural H 2 O in Intercalation Electrodes: The Case of Mg in Nanocrystalline Xerogel-V 2 O 5
journal, March 2016

  • Sai Gautam, Gopalakrishnan; Canepa, Pieremanuele; Richards, William Davidson
  • Nano Letters, Vol. 16, Issue 4
  • DOI: 10.1021/acs.nanolett.5b05273

Express and low-cost microwave synthesis of the ternary Chevrel phase Cu2Mo6S8 for application in rechargeable magnesium batteries
journal, October 2016

  • Murgia, Fabrizio; Antitomaso, Philippe; Stievano, Lorenzo
  • Journal of Solid State Chemistry, Vol. 242
  • DOI: 10.1016/j.jssc.2016.07.022

RF sputtering deposition of MgMn 2 O 4 spinel thin films
journal, March 2004


Communication—Sol-Gel Synthesized Magnesium Vanadium Oxide, Mg x V 2 O 5 · nH 2 O: The Role of Structural Mg 2+ on Battery Performance
journal, January 2016

  • Yin, Jiefu; Pelliccione, Christopher J.; Lee, Shu Han
  • Journal of The Electrochemical Society, Vol. 163, Issue 9
  • DOI: 10.1149/2.0781609jes

Advanced hybrid battery with a magnesium metal anode and a spinel LiMn 2 O 4 cathode
journal, January 2016

  • Pan, Baofei; Feng, Zhenxing; Sa, Niya
  • Chemical Communications, Vol. 52, Issue 64
  • DOI: 10.1039/C6CC04133G

Hydrothermal synthesis of LiMn2O4/C composite as a cathode for rechargeable lithium-ion battery with excellent rate capability
journal, September 2009


Phase Diagram of Mg Insertion into Chevrel Phases, Mg x Mo 6 T 8 (T = S, Se). 1. Crystal Structure of the Sulfides
journal, November 2006

  • Levi, E.; Lancry, E.; Mitelman, A.
  • Chemistry of Materials, Vol. 18, Issue 23
  • DOI: 10.1021/cm061656f

Comparison of Metal Ion Dissolutions from Lithium Ion Battery Cathodes
journal, January 2006

  • Choi, W.; Manthiram, A.
  • Journal of The Electrochemical Society, Vol. 153, Issue 9
  • DOI: 10.1149/1.2219710

Critical Evaluation and Thermodynamic Modeling of the Mg-Mn-O (MgO-MnO-MnO 2 ) System
journal, July 2014

  • Panda, Sourav Kumar; Jung, In-Ho
  • Journal of the American Ceramic Society, Vol. 97, Issue 10
  • DOI: 10.1111/jace.13106

Solvation of Mg2+ ions in methanol–water mixtures: Molecular dynamics simulation
journal, May 2012


The Coupling between Stability and Ion Pair Formation in Magnesium Electrolytes from First-Principles Quantum Mechanics and Classical Molecular Dynamics
journal, February 2015

  • Rajput, Nav Nidhi; Qu, Xiaohui; Sa, Niya
  • Journal of the American Chemical Society, Vol. 137, Issue 9, p. 3411-3420
  • DOI: 10.1021/jacs.5b01004

Electrochemical Conversion of LiMn[sub 2]O[sub 4] to MgMn[sub 2]O[sub 4] in Aqueous Electrolytes
journal, January 2008

  • Sinha, Nupur Nikkan; Munichandraiah, N.
  • Electrochemical and Solid-State Letters, Vol. 11, Issue 11
  • DOI: 10.1149/1.2972990

Prototype systems for rechargeable magnesium batteries
journal, October 2000

  • Aurbach, D.; Lu, Z.; Schechter, A.
  • Nature, Vol. 407, Issue 6805, p. 724-727
  • DOI: 10.1038/35037553

Synthetic control of manganese birnessite: Impact of crystallite size on Li, Na, and Mg based electrochemistry
journal, November 2016


Solvation Structures and Dynamics of the Magnesium Chloride (Mg 2+ –Cl ) Ion Pair in Water–Ethanol Mixtures
journal, July 2013

  • Chatterjee, Anupam; Dixit, Mayank Kumar; Tembe, B. L.
  • The Journal of Physical Chemistry A, Vol. 117, Issue 36
  • DOI: 10.1021/jp4031706

Sol Gel Based Synthesis and Electrochemistry of Magnesium Vanadium Oxide: A Promising Cathode Material for Secondary Magnesium Ion Batteries
journal, January 2014

  • Lee, S. H.; DiLeo, R. A.; Marschilok, A. C.
  • ECS Electrochemistry Letters, Vol. 3, Issue 8
  • DOI: 10.1149/2.0021408eel

Solvothermal synthesis of GO/V 2 O 5 composites as a cathode material for rechargeable magnesium batteries
journal, January 2015

  • Du, Xinchuan; Huang, Gang; Qin, Yuling
  • RSC Advances, Vol. 5, Issue 93
  • DOI: 10.1039/C5RA15284D

Investigation of the Mechanism of Mg Insertion in Birnessite in Nonaqueous and Aqueous Rechargeable Mg-Ion Batteries
journal, January 2016


α-MnO2 as a cathode material for rechargeable Mg batteries
journal, September 2012


Raman spectroscopy of AMn2O4 (A = Mn, Mg and Zn) spinels
journal, June 2002

  • Malavasi, Lorenzo; Galinetto, Pietro; Mozzati, Maria C.
  • Physical Chemistry Chemical Physics, Vol. 4, Issue 15
  • DOI: 10.1039/b203520k

High capacity positive electrodes for secondary Mg-ion batteries
journal, November 2012


Mg Intercalation Properties into V[sub 2]O[sub 5] gel/Carbon Composites under High-Rate Condition
journal, January 2003

  • Imamura, Daichi; Miyayama, Masaru; Hibino, Mitsuhiro
  • Journal of The Electrochemical Society, Vol. 150, Issue 6
  • DOI: 10.1149/1.1571531

Activation of a MnO 2 cathode by water-stimulated Mg 2+ insertion for a magnesium ion battery
journal, January 2015

  • Song, Jaehee; Noked, Malakhi; Gillette, Eleanor
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 7
  • DOI: 10.1039/C4CP05591H

Structural and Transport Properties of Mg1−xMnxMn2O4±δ Spinels
journal, June 2002

  • Malavasi, Lorenzo; Ghigna, Paolo; Chiodelli, Gaetano
  • Journal of Solid State Chemistry, Vol. 166, Issue 1
  • DOI: 10.1006/jssc.2002.9577

Composite Anodes for Secondary Magnesium Ion Batteries Prepared via Electrodeposition of Nanostructured Bismuth on Carbon Nanotube Substrates
journal, October 2014

  • DiLeo, R. A.; Zhang, Q.; Marschilok, A. C.
  • ECS Electrochemistry Letters, Vol. 4, Issue 1
  • DOI: 10.1149/2.0081501eel

High-pressure stability of the tetragonal spinel MgMn 2 O 4 : Role of inversion
journal, May 2005


Cathode materials for magnesium and magnesium-ion based batteries
journal, March 2015

  • Huie, Matthew M.; Bock, David C.; Takeuchi, Esther S.
  • Coordination Chemistry Reviews, Vol. 287
  • DOI: 10.1016/j.ccr.2014.11.005

Porous Manganese Oxide Octahedral Molecular Sieves and Octahedral Layered Materials
journal, April 2008

  • Suib, Steven L.
  • Accounts of Chemical Research, Vol. 41, Issue 4
  • DOI: 10.1021/ar7001667

Nanostructured cathode materials for rechargeable lithium batteries
journal, June 2015


Understanding the Electrochemical Mechanism of K-αMnO 2 for Magnesium Battery Cathodes
journal, May 2014

  • Arthur, Timothy S.; Zhang, Ruigang; Ling, Chen
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 10
  • DOI: 10.1021/am5015327

The High Performance of Crystal Water Containing Manganese Birnessite Cathodes for Magnesium Batteries
journal, May 2015


M x Mn 8 O 16 (M = Ag or K) as promising cathode materials for secondary Mg based batteries: the role of the cation M
journal, January 2016

  • Huang, Jianping; Poyraz, Altug S.; Takeuchi, Kenneth J.
  • Chemical Communications, Vol. 52, Issue 21
  • DOI: 10.1039/C6CC00025H

On the Utility of Spinel Oxide Hosts for Magnesium-Ion Batteries
journal, October 2015

  • Knight, James C.; Therese, Soosairaj; Manthiram, Arumugam
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 41
  • DOI: 10.1021/acsami.5b06179

Electrolyte roadblocks to a magnesium rechargeable battery
journal, January 2012

  • Muldoon, John; Bucur, Claudiu B.; Oliver, Allen G.
  • Energy & Environmental Science, Vol. 5, Issue 3, p. 5941-5950
  • DOI: 10.1039/c2ee03029b

Structural Changes in MgMn2O4 at High Temperatures
journal, January 1965


Atomic layer coating to mitigate capacity fading associated with manganese dissolution in lithium ion batteries
journal, July 2013


Phase Stability of Post-spinel Compound AMn 2 O 4 (A = Li, Na, or Mg) and Its Application as a Rechargeable Battery Cathode
journal, July 2013

  • Ling, Chen; Mizuno, Fuminori
  • Chemistry of Materials, Vol. 25, Issue 15
  • DOI: 10.1021/cm401250c

Synthetic Routes to Microporous Manganese Oxides
journal, October 1997