Successive field-induced transitions in BiFeO3 around room temperature

Kawachi, Shiro; Miyake, Atsushi; Ito, Toshimitsu; Dissanayake, Sachith E.; Matsuda, Masaaki; Ratcliff, William; Xu, Zhijun; Zhao, Yang; Miyahara, Shin; Furukawa, Nobuo; Tokunaga, Masashi

doi:10.1103/PhysRevMaterials.1.024408

Title: Successive field-induced transitions in ${BiFeO}_{3}$ around room temperature

Abstract

The effects of high magnetic fields applied perpendicular to the spontaneous ferroelectric polarization on single crystals of BiFeO₃ were investigated in this paper through magnetization, magnetostriction, and neutron diffraction measurements. The magnetostriction measurements revealed lattice distortion of 2 x 10^-5 during the reorientation process of the cycloidal spin order by applied magnetic fields. Furthermore, anomalous changes in magnetostriction and electric polarization at a larger field demonstrate an intermediate phase between cycloidal and canted antiferromagnetic states, where a large magnetoelectric effect was observed. Neutron diffraction measurements clarified that incommensurate spin modulation along the [110]_hex direction in the cycloidal phase becomes Q = 0 commensurate along this direction in the intermediate phase. Finally, theoretical calculations based on the standard spin Hamiltonian of this material suggest an antiferromagnetic cone-type spin order in the intermediate phase.

Authors:

Kawachi, Shiro ^[1]; Miyake, Atsushi ^[1]; Ito, Toshimitsu ^[2]; Dissanayake, Sachith E. ^[3]; Matsuda, Masaaki ^[3]; Ratcliff, William ^[4]; Xu, Zhijun ^[5]; Zhao, Yang ^[5]; Miyahara, Shin ^[6]; Furukawa, Nobuo ^[7]; Tokunaga, Masashi ^[1]

Univ. of Tokyo, Kashiwa (Japan). The Inst. for Solid State Physics (ISSP)
National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). NIST Center for Neutron Research
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). NIST Center for Neutron Research; Univ. of Maryland, College Park, MD (United States). Dept. of Materials Science and Engineering
Fukuoka Univ. (Japan). Dept. of Applied Physics
Aoyama Gakuin Univ., Sagamihara (Japan). Dept. of Physics and Mathematics

Publication Date:: Fri Jul 21 00:00:00 EDT 2017

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Univ. of Tokyo, Kashiwa (Japan); National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Dept. of Commerce (United States); Japan Society for the Promotion of Science (JSPS) (Japan); Murata Science Foundation (Japan)

Contributing Org.:: Univ. of Maryland, College Park, MD (United States); Aoyama Gakuin Univ., Sagamihara (Japan); Fukuoka Univ. (Japan)

OSTI Identifier:: 1376426

Alternate Identifier(s):: OSTI ID: 1372421

Grant/Contract Number:: AC05-00OR22725; JP16K05413

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review Materials

Additional Journal Information:: Journal Volume: 1; Journal Issue: 2; Journal ID: ISSN 2475-9953

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE; magnetoelectric effect; magnetostriction; phase transitions by order; multiferroics; magnetization measurements; neutron diffraction; condensed matter and materials physics

Citation Formats


                    Kawachi, Shiro, Miyake, Atsushi, Ito, Toshimitsu, Dissanayake, Sachith E., Matsuda, Masaaki, Ratcliff, William, Xu, Zhijun, Zhao, Yang, Miyahara, Shin, Furukawa, Nobuo, and Tokunaga, Masashi. Successive field-induced transitions in BiFeO3 around room temperature.  United States: N. p., 2017. 
Web.  doi:10.1103/PhysRevMaterials.1.024408.

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                    Kawachi, Shiro, Miyake, Atsushi, Ito, Toshimitsu, Dissanayake, Sachith E., Matsuda, Masaaki, Ratcliff, William, Xu, Zhijun, Zhao, Yang, Miyahara, Shin, Furukawa, Nobuo, & Tokunaga, Masashi. Successive field-induced transitions in BiFeO3 around room temperature.  United States.  https://doi.org/10.1103/PhysRevMaterials.1.024408

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                    Kawachi, Shiro, Miyake, Atsushi, Ito, Toshimitsu, Dissanayake, Sachith E., Matsuda, Masaaki, Ratcliff, William, Xu, Zhijun, Zhao, Yang, Miyahara, Shin, Furukawa, Nobuo, and Tokunaga, Masashi. Fri .  
"Successive field-induced transitions in BiFeO3 around room temperature".  United States.  https://doi.org/10.1103/PhysRevMaterials.1.024408.  https://www.osti.gov/servlets/purl/1376426.

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@article{osti_1376426,

  title        = {Successive field-induced transitions in BiFeO3 around room temperature},

  author       = {Kawachi, Shiro and Miyake, Atsushi and Ito, Toshimitsu and Dissanayake, Sachith E. and Matsuda, Masaaki and Ratcliff, William and Xu, Zhijun and Zhao, Yang and Miyahara, Shin and Furukawa, Nobuo and Tokunaga, Masashi},

  abstractNote = {The effects of high magnetic fields applied perpendicular to the spontaneous ferroelectric polarization on single crystals of BiFeO3 were investigated in this paper through magnetization, magnetostriction, and neutron diffraction measurements. The magnetostriction measurements revealed lattice distortion of 2 x 10-5 during the reorientation process of the cycloidal spin order by applied magnetic fields. Furthermore, anomalous changes in magnetostriction and electric polarization at a larger field demonstrate an intermediate phase between cycloidal and canted antiferromagnetic states, where a large magnetoelectric effect was observed. Neutron diffraction measurements clarified that incommensurate spin modulation along the [110]hex direction in the cycloidal phase becomes Q = 0 commensurate along this direction in the intermediate phase. Finally, theoretical calculations based on the standard spin Hamiltonian of this material suggest an antiferromagnetic cone-type spin order in the intermediate phase.},

  doi          = {10.1103/PhysRevMaterials.1.024408},

  journal      = {Physical Review Materials},

  number       = 2,

  volume       = 1,

  place        = {United States},

  year         = {Fri Jul 21 00:00:00 EDT 2017},

  month        = {Fri Jul 21 00:00:00 EDT 2017}

}

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Works referencing / citing this record:

The structural origin of composition-driven magnetic transformation in BiFeO ₃ -based multiferroics: a neutron diffraction study
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Multiferroic behavior from synergetic response of multiple ordering parameters in BiFeO ₃ single crystal under high magnetic field up to 50 Tesla
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Direct coupling of ferromagnetic moment and ferroelectric polarization in ${BiFeO}_{3}$
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Kawachi, Shiro; Miyahara, Shin; Ito, Toshimitsu
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Title: Successive field-induced transitions in BiFeO 3 around room temperature

Abstract

Citation Formats

Resistive memory effects in BiFeO3 single crystals controlled by transverse electric fields journal, April 2016

Growth of Highly Insulating Bulk Single Crystals of Multiferroic BiFeO 3 and Their Inherent Internal Strains in the Domain-Switching Process journal, November 2011

A Resistive Memory in Semiconducting BiFeO3 Thin-Film Capacitors journal, January 2011

Giant Spin-Driven Ferroelectric Polarization in BiFeO 3 at Room Temperature journal, November 2015

Canted-spin-caused electric dipoles: A local symmetry theory journal, May 2011

Single ferroelectric and chiral magnetic domain of single-crystalline BiFeO 3 in an electric field journal, September 2008

Spin cycloid quenching in Nd 3 + -substituted BiFeO 3 journal, July 2012

Crystal and Magnetic Structure in Co-Substituted BiFeO 3 journal, November 2013

High field studies on BiFeO 3 single crystals grown by the laser-diode heating floating zone method journal, June 2015

Photovoltaic effects in BiFeO3 journal, August 2009

Theory of antisymmetric spin-pair-dependent electric polarization in multiferroics journal, January 2016

Field-induced phase transitions and phase diagrams in BiFeO 3 -like multiferroics journal, June 2013

Coherent Magnetoelastic Domains in Multiferroic BiFeO 3 Films journal, October 2016

Reversible electric control of exchange bias in a multiferroic field-effect device journal, July 2010

Spin Wave Measurements over the Full Brillouin Zone of Multiferroic BiFeO 3 journal, February 2012

Magnetoelectric studies of antiferromagnetic crystals in strong magnetic fields journal, January 1995

Switchable diode effect and ferroelectric resistive switching in epitaxial BiFeO3 thin films journal, May 2011

Large bulk polarization and regular domain structure in ceramic BiFeO3 journal, April 2007

Monoclinic Deformation of Crystal Lattice of Bulk α-BiFeO 3 : High Resolution Synchrotron Radiation Studies journal, April 2012

Spin state and spectroscopic modes of multiferroic BiFeO 3 journal, April 2013

First-principles study of spontaneous polarization in multiferroic Bi Fe O 3 journal, January 2005

Optical Diode Effect at Spin-Wave Excitations of the Room-Temperature Multiferroic BiFeO 3 journal, September 2015

Magnetic-field-induced phase transition in BiFeO 3 observed by high-field electron spin resonance: Cycloidal to homogeneous spin order journal, February 2004

High field magnetostriction in intermetallic compounds journal, March 1989

Physics and Applications of Bismuth Ferrite journal, June 2009

Impact of Bi Deficiencies on Ferroelectric Resistive Switching Characteristics Observed at p-Type Schottky-Like Pt/Bi1-δFeO3 Interfaces journal, January 2012

Destruction of spin cycloid in (111)c-oriented BiFeO3 thin films by epitiaxial constraint: Enhanced polarization and release of latent magnetization journal, January 2005

Spiral magnetic ordering in bismuth ferrite journal, August 1982

Room-temperature coexistence of large electric polarization and magnetic order in Bi Fe O 3 single crystals journal, July 2007

Spin Structure Change in Co-Substituted BiFeO 3 journal, June 2016

Switchable Ferroelectric Diode and Photovoltaic Effect in BiFeO 3 journal, February 2009

Large Resistive Switching in Ferroelectric BiFeO 3 Nano-Island Based Switchable Diodes journal, February 2013

Measurement of the Quadratic Magnetoelectric Effect on Single Crystalline BiFeO 3 journal, January 1985

Double-Focusing Thermal Triple-Axis Spectrometer at the NCNR journal, January 2012

Crafting the magnonic and spintronic response of BiFeO3 films by epitaxial strain journal, April 2013

Spin density wave and field induced phase transitions in magnetoelectric antiferromagnets journal, May 1995

Magnetic control of transverse electric polarization in BiFeO3 journal, January 2015

Influence of parasitic phases on the properties of BiFeO3 epitaxial thin films journal, August 2005

Electric-field control of local ferromagnetism using a magnetoelectric multiferroic journal, April 2008

Magnetic Dispersion and Anisotropy in Multiferroic BiFeO 3 journal, August 2012

Giant Effect of Uniaxial Pressure on Magnetic Domain Populations in Multiferroic Bismuth Ferrite journal, August 2011

A highly CMOS compatible hafnia-based ferroelectric diode journal, March 2020

Canted-spin-caused electric dipoles: a local symmetry theory text, January 2008

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The structural origin of composition-driven magnetic transformation in BiFeO 3 -based multiferroics: a neutron diffraction study journal, January 2019

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Title: Successive field-induced transitions in ${BiFeO}_{3}$ around room temperature

Resistive memory effects in BiFeO3 single crystals controlled by transverse electric fields
journal, April 2016

Growth of Highly Insulating Bulk Single Crystals of Multiferroic BiFeO ₃ and Their Inherent Internal Strains in the Domain-Switching Process
journal, November 2011

A Resistive Memory in Semiconducting BiFeO3 Thin-Film Capacitors
journal, January 2011

Giant Spin-Driven Ferroelectric Polarization in ${BiFeO}_{3}$ at Room Temperature
journal, November 2015

Canted-spin-caused electric dipoles: A local symmetry theory
journal, May 2011

Single ferroelectric and chiral magnetic domain of single-crystalline ${BiFeO}_{3}$ in an electric field
journal, September 2008

Spin cycloid quenching in Nd $^{3 +}$ -substituted BiFeO $_{3}$
journal, July 2012

Crystal and Magnetic Structure in Co-Substituted BiFeO ₃
journal, November 2013

High field studies on BiFeO 3 single crystals grown by the laser-diode heating floating zone method
journal, June 2015

Photovoltaic effects in BiFeO3
journal, August 2009

Theory of antisymmetric spin-pair-dependent electric polarization in multiferroics
journal, January 2016

Field-induced phase transitions and phase diagrams in BiFeO $_{3}$ -like multiferroics
journal, June 2013

Coherent Magnetoelastic Domains in Multiferroic ${BiFeO}_{3}$ Films
journal, October 2016

Reversible electric control of exchange bias in a multiferroic field-effect device
journal, July 2010

Spin Wave Measurements over the Full Brillouin Zone of Multiferroic ${BiFeO}_{3}$
journal, February 2012

Magnetoelectric studies of antiferromagnetic crystals in strong magnetic fields
journal, January 1995

Switchable diode effect and ferroelectric resistive switching in epitaxial BiFeO3 thin films
journal, May 2011

Large bulk polarization and regular domain structure in ceramic BiFeO3
journal, April 2007

Monoclinic Deformation of Crystal Lattice of Bulk α-BiFeO ₃ : High Resolution Synchrotron Radiation Studies
journal, April 2012

Spin state and spectroscopic modes of multiferroic BiFeO $_{3}$
journal, April 2013

First-principles study of spontaneous polarization in multiferroic $Bi Fe O_{3}$
journal, January 2005

Optical Diode Effect at Spin-Wave Excitations of the Room-Temperature Multiferroic ${BiFeO}_{3}$
journal, September 2015

Magnetic-field-induced phase transition in ${BiFeO}_{3}$ observed by high-field electron spin resonance: Cycloidal to homogeneous spin order
journal, February 2004

High field magnetostriction in intermetallic compounds
journal, March 1989

Physics and Applications of Bismuth Ferrite
journal, June 2009

Impact of Bi Deficiencies on Ferroelectric Resistive Switching Characteristics Observed at p-Type Schottky-Like Pt/Bi1-δFeO3 Interfaces
journal, January 2012

Destruction of spin cycloid in (111)c-oriented BiFeO3 thin films by epitiaxial constraint: Enhanced polarization and release of latent magnetization
journal, January 2005

Spiral magnetic ordering in bismuth ferrite
journal, August 1982

Room-temperature coexistence of large electric polarization and magnetic order in $Bi Fe O_{3}$ single crystals
journal, July 2007

Spin Structure Change in Co-Substituted BiFeO ₃
journal, June 2016

Switchable Ferroelectric Diode and Photovoltaic Effect in BiFeO ₃
journal, February 2009

Large Resistive Switching in Ferroelectric BiFeO ₃ Nano-Island Based Switchable Diodes
journal, February 2013

Measurement of the Quadratic Magnetoelectric Effect on Single Crystalline BiFeO ₃
journal, January 1985

Double-Focusing Thermal Triple-Axis Spectrometer at the NCNR
journal, January 2012

Crafting the magnonic and spintronic response of BiFeO3 films by epitaxial strain
journal, April 2013

Spin density wave and field induced phase transitions in magnetoelectric antiferromagnets
journal, May 1995

Magnetic control of transverse electric polarization in BiFeO3
journal, January 2015

Influence of parasitic phases on the properties of BiFeO3 epitaxial thin films
journal, August 2005

Electric-field control of local ferromagnetism using a magnetoelectric multiferroic
journal, April 2008

Magnetic Dispersion and Anisotropy in Multiferroic ${BiFeO}_{3}$
journal, August 2012

Giant Effect of Uniaxial Pressure on Magnetic Domain Populations in Multiferroic Bismuth Ferrite
journal, August 2011

A highly CMOS compatible hafnia-based ferroelectric diode
journal, March 2020

Canted-spin-caused electric dipoles: a local symmetry theory
text, January 2008

Coherent magneto-elastic domains in multiferroic BiFeO3 films
text, January 2015

Influence of parasitic phases on the properties of BiFeO3 epitaxial thin films
text, January 2005

The structural origin of composition-driven magnetic transformation in BiFeO ₃ -based multiferroics: a neutron diffraction study
journal, January 2019

Multiferroic behavior from synergetic response of multiple ordering parameters in BiFeO ₃ single crystal under high magnetic field up to 50 Tesla
journal, January 2020

Direct coupling of ferromagnetic moment and ferroelectric polarization in ${BiFeO}_{3}$
journal, October 2019