Design and Demonstration of Three-Electrode Pouch Cells for Lithium-Ion Batteries
Abstract
Simple three-electrode pouch cells which can be used in distinguishing the voltage and resistance in individual electrodes of lithium ion batteries have been designed. Baseline (1 mm-staggered alignment, cathode away from a reference electrode) and aligned electrodes to a reference electrode located outside of the anode and cathode were studied to see alignment effects on resistance analysis. Cells composed of A12 graphite anodes, LiNi0.5Mn0.3Co0.2O2 (NMC 532 or NCM 523) cathodes, lithium foil references, microporous tri-layer membranes, and electrolytes, were cycled with cathode cutoff voltages between 3.0 V and 4.3 V for formation cycles or 4.6 V for C-rate performance testing. By applying a hybrid pulse power characterization (HPPC) technique to the cells, resistances of the baseline cells contributed by the anode and cathode were found to be different from those of the aligned cells, although overall resistances were close to ones from aligned cells. As a result, resistances obtained via electrochemical impedance spectroscopy (EIS) and 2D simulation were also compared with those obtained from HPPC.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1376322
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 164; Journal Issue: 7; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; electrochemical impedance spectroscopy; electrode alignment; hybrid pulse power characterization; simulation; three-electrode pouch cell
Citation Formats
An, Seong Jin, Li, Jianlin, Daniel, Claus, Kalnaus, Sergiy, and Wood, III, David L. Design and Demonstration of Three-Electrode Pouch Cells for Lithium-Ion Batteries. United States: N. p., 2017.
Web. doi:10.1149/2.0031709jes.
An, Seong Jin, Li, Jianlin, Daniel, Claus, Kalnaus, Sergiy, & Wood, III, David L. Design and Demonstration of Three-Electrode Pouch Cells for Lithium-Ion Batteries. United States. https://doi.org/10.1149/2.0031709jes
An, Seong Jin, Li, Jianlin, Daniel, Claus, Kalnaus, Sergiy, and Wood, III, David L. Wed .
"Design and Demonstration of Three-Electrode Pouch Cells for Lithium-Ion Batteries". United States. https://doi.org/10.1149/2.0031709jes. https://www.osti.gov/servlets/purl/1376322.
@article{osti_1376322,
title = {Design and Demonstration of Three-Electrode Pouch Cells for Lithium-Ion Batteries},
author = {An, Seong Jin and Li, Jianlin and Daniel, Claus and Kalnaus, Sergiy and Wood, III, David L.},
abstractNote = {Simple three-electrode pouch cells which can be used in distinguishing the voltage and resistance in individual electrodes of lithium ion batteries have been designed. Baseline (1 mm-staggered alignment, cathode away from a reference electrode) and aligned electrodes to a reference electrode located outside of the anode and cathode were studied to see alignment effects on resistance analysis. Cells composed of A12 graphite anodes, LiNi0.5Mn0.3Co0.2O2 (NMC 532 or NCM 523) cathodes, lithium foil references, microporous tri-layer membranes, and electrolytes, were cycled with cathode cutoff voltages between 3.0 V and 4.3 V for formation cycles or 4.6 V for C-rate performance testing. By applying a hybrid pulse power characterization (HPPC) technique to the cells, resistances of the baseline cells contributed by the anode and cathode were found to be different from those of the aligned cells, although overall resistances were close to ones from aligned cells. As a result, resistances obtained via electrochemical impedance spectroscopy (EIS) and 2D simulation were also compared with those obtained from HPPC.},
doi = {10.1149/2.0031709jes},
journal = {Journal of the Electrochemical Society},
number = 7,
volume = 164,
place = {United States},
year = {Wed Jun 14 00:00:00 EDT 2017},
month = {Wed Jun 14 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
AC impedance and state-of-charge analysis of a sealed lithium-ion rechargeable battery
journal, September 1999
- Rodrigues, Shalini; Munichandraiah, N.; Shukla, A. K.
- Journal of Solid State Electrochemistry, Vol. 3, Issue 7-8
Studies on the cycle life of commercial lithium ion batteries during rapid charge–discharge cycling
journal, December 2001
- Li, J.; Murphy, E.; Winnick, J.
- Journal of Power Sources, Vol. 102, Issue 1-2
Interplay of Operational Parameters on Lithium Deposition in Lithium-Ion Cells: Systematic Measurements with Reconstructed 3-Electrode Pouch Full Cells
journal, January 2016
- Waldmann, Thomas; Hogg, Björn-Ingo; Kasper, Michael
- Journal of The Electrochemical Society, Vol. 163, Issue 7
Understanding the Anomalous Capacity of Li / Li [ NixLi ( 1 / 3 − 2x / 3 ) Mn ( 2 / 3 − x / 3 ) ] O2 Cells Using In Situ X-Ray Diffraction and Electrochemical Studies
journal, January 2002
- Lu, Zhonghua; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 149, Issue 7, p. A815-A822
Kinetics of Lithium Ion Transfer at the Interface between Graphite and Liquid Electrolytes: Effects of Solvent and Surface Film
journal, November 2009
- Yamada, Yuki; Iriyama, Yasutoshi; Abe, Takeshi
- Langmuir, Vol. 25, Issue 21
Frumkin intercalation isotherm — a tool for the description of lithium insertion into host materials: a review
journal, September 1999
- Levi, M. D.; Aurbach, D.
- Electrochimica Acta, Vol. 45, Issue 1-2
Correlation of Electrolyte Volume and Electrochemical Performance in Lithium-Ion Pouch Cells with Graphite Anodes and NMC532 Cathodes
journal, January 2017
- An, Seong Jin; Li, Jianlin; Mohanty, Debasish
- Journal of The Electrochemical Society, Vol. 164, Issue 6
Charge–discharge stability of graphite anodes for lithium-ion batteries
journal, February 2001
- Wang, Chunsheng; Appleby, A. John; Little, Frank E.
- Journal of Electroanalytical Chemistry, Vol. 497, Issue 1-2
Materials and processing for lithium-ion batteries
journal, September 2008
- Daniel, Claus
- JOM, Vol. 60, Issue 9
Current density distribution in cylindrical Li-Ion cells during impedance measurements
journal, May 2016
- Osswald, P. J.; Erhard, S. V.; Noel, A.
- Journal of Power Sources, Vol. 314
Comparison of Modeling Predictions with Experimental Data from Plastic Lithium Ion Cells
journal, January 1996
- Doyle, Marc
- Journal of The Electrochemical Society, Vol. 143, Issue 6
Alternating Current Impedance Electrochemical Modeling of Lithium-Ion Positive Electrodes
journal, January 2005
- Dees, Dennis; Gunen, Evren; Abraham, Daniel
- Journal of The Electrochemical Society, Vol. 152, Issue 7
Optimization of reference electrode position in a three-electrode cell for impedance measurements in lithium-ion rechargeable battery by finite element method
journal, August 2015
- Hoshi, Yoshinao; Narita, Yuki; Honda, Keiichiro
- Journal of Power Sources, Vol. 288
Simulation and Optimization of the Dual Lithium Ion Insertion Cell
journal, January 1994
- Fuller, Thomas F.
- Journal of The Electrochemical Society, Vol. 141, Issue 1
Fast formation cycling for lithium ion batteries
journal, February 2017
- An, Seong Jin; Li, Jianlin; Du, Zhijia
- Journal of Power Sources, Vol. 342
Modeling of Galvanostatic Charge and Discharge of the Lithium/Polymer/Insertion Cell
journal, January 1993
- Doyle, Marc
- Journal of The Electrochemical Society, Vol. 140, Issue 6
Studies of Aluminum-Doped LiNi 0.5 Co 0.2 Mn 0.3 O 2 : Electrochemical Behavior, Aging, Structural Transformations, and Thermal Characteristics
journal, January 2015
- Aurbach, Doron; Srur-Lavi, Onit; Ghanty, Chandan
- Journal of The Electrochemical Society, Vol. 162, Issue 6
The importance of cell geometry for electrochemical impedance spectroscopy in three-electrode lithium ion battery test cells
journal, August 2012
- Klink, Stefan; Madej, Edyta; Ventosa, Edgar
- Electrochemistry Communications, Vol. 22
Electrode Behavior RE-Visited: Monitoring Potential Windows, Capacity Loss, and Impedance Changes in Li 1.03 (Ni 0.5 Co 0.2 Mn 0.3 ) 0.97 O 2 /Silicon-Graphite Full Cells
journal, January 2016
- Klett, Matilda; Gilbert, James A.; Trask, Stephen E.
- Journal of The Electrochemical Society, Vol. 163, Issue 6
The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling
journal, August 2016
- An, Seong Jin; Li, Jianlin; Daniel, Claus
- Carbon, Vol. 105
Long-Term Lithium-Ion Battery Performance Improvement via Ultraviolet Light Treatment of the Graphite Anode
journal, January 2016
- An, Seong Jin; Li, Jianlin; Sheng, Yangping
- Journal of The Electrochemical Society, Vol. 163, Issue 14
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries
journal, August 2000
- Aurbach, Doron
- Journal of Power Sources, Vol. 89, Issue 2
Simultaneous Measurements and Modeling of the Electrochemical Impedance and the Cyclic Voltammetric Characteristics of Graphite Electrodes Doped with Lithium
journal, June 1997
- Levi, M. D.; Aurbach, D.
- The Journal of Physical Chemistry B, Vol. 101, Issue 23
Development of a lifetime prediction model for lithium-ion batteries based on extended accelerated aging test data
journal, October 2012
- Ecker, Madeleine; Gerschler, Jochen B.; Vogel, Jan
- Journal of Power Sources, Vol. 215
Electrochemical Characterization and Temperature Dependency of Mass-Transport Properties of LiPF 6 in EC:DEC
journal, December 2014
- Lundgren, Henrik; Behm, Mårten; Lindbergh, Göran
- Journal of The Electrochemical Society, Vol. 162, Issue 3
Evaluation Residual Moisture in Lithium-Ion Battery Electrodes and Its Effect on Electrode Performance
journal, January 2016
- Li, Jianlin; Daniel, Claus; An, Seong Jin
- MRS Advances, Vol. 1, Issue 15
Structural and Kinetic Characterization of Lithium Intercalation into Carbon Anodes for Secondary Lithium Batteries
journal, January 1995
- Takami, Norio
- Journal of The Electrochemical Society, Vol. 142, Issue 2
On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries
journal, September 1999
- Aurbach, D.; Markovsky, B.; Weissman, I.
- Electrochimica Acta, Vol. 45, Issue 1-2
Li-insertion into thin monolithic V2O5 films electrodes characterized by a variety of electroanalytical techniques
journal, July 2001
- Levi, M. D.; Lu, Z.; Aurbach, D.
- Journal of Power Sources, Vol. 97-98
Structural transformation of a lithium-rich Li1.2Co0.1Mn0.55Ni0.15O2 cathode during high voltage cycling resolved by in situ X-ray diffraction
journal, May 2013
- Mohanty, Debasish; Kalnaus, Sergiy; Meisner, Roberta A.
- Journal of Power Sources, Vol. 229
Three-Dimensional Thermal Modeling of a Lithium-Ion Battery Considering the Combined Effects of the Electrical and Thermal Contact Resistances between Current Collecting Tab and Lead Wire
journal, January 2013
- Yi, Jaeshin; Kim, Ui Seong; Shin, Chee Burm
- Journal of The Electrochemical Society, Vol. 160, Issue 3
Thermal modeling of cylindrical lithium ion battery during discharge cycle
journal, August 2011
- Jeon, Dong Hyup; Baek, Seung Man
- Energy Conversion and Management, Vol. 52, Issue 8-9
Electrochemical impedance study of Li-ion insertion into mesocarbon microbead single particle electrode
journal, December 2001
- Umeda, M.; Dokko, K.; Fujita, Y.
- Electrochimica Acta, Vol. 47, Issue 6
Suppression of staging in lithium-intercalated carbon by disorder in the host
journal, October 1990
- Dahn, J. R.; Fong, Rosamaria; Spoon, M. J.
- Physical Review B, Vol. 42, Issue 10
Understanding Long-Term Cycling Performance of Li 1.2 Ni 0.15 Mn 0.55 Co 0.1 O 2 –Graphite Lithium-Ion Cells
journal, January 2013
- Li, Y.; Bettge, M.; Polzin, B.
- Journal of The Electrochemical Society, Vol. 160, Issue 5
18650 Li-ion cells with reference electrode and in situ characterization of electrodes
journal, October 2005
- Nagasubramanian, G.; Doughty, D. H.
- Journal of Power Sources, Vol. 150
The Effect of Slow Interfacial Kinetics on the Chronoamperometric Response of Composite Lithiated Graphite Electrodes and on the Calculation of the Chemical Diffusion Coefficient of Li Ions in Graphite
journal, April 2005
- Levi, M. D.; Markevich, E.; Aurbach, D.
- The Journal of Physical Chemistry B, Vol. 109, Issue 15
Determination of the chemical diffusion coefficient of lithium in LiFePO4
journal, May 2002
- Prosini, P.
- Solid State Ionics, Vol. 148, Issue 1-2
Solid‐State Electrochemical Kinetics of Li‐Ion Intercalation into Li1 − xCoO2: Simultaneous Application of Electroanalytical Techniques SSCV, PITT, and EIS
journal, January 1999
- Levi, M. D.; Salitra, G.; Markovsky, B.
- Journal of The Electrochemical Society, Vol. 146, Issue 4, p. 1279-1289
Electrochemical Modeling and Performance of a Lithium- and Manganese-Rich Layered Transition-Metal Oxide Positive Electrode
journal, January 2015
- Dees, Dennis W.; Abraham, Daniel P.; Lu, Wenquan
- Journal of The Electrochemical Society, Vol. 162, Issue 4
Analysis of Three-Electrode Setups for AC-Impedance Measurements on Lithium-Ion Cells by FEM simulations
journal, January 2011
- Ender, Moses; Weber, André; Ellen, Ivers-Tiffée
- Journal of The Electrochemical Society, Vol. 159, Issue 2
Diffusion Coefficients of Lithium Ions during Intercalation into Graphite Derived from the Simultaneous Measurements and Modeling of Electrochemical Impedance and Potentiostatic Intermittent Titration Characteristics of Thin Graphite Electrodes
journal, June 1997
- Levi, M. D.; Aurbach, D.
- The Journal of Physical Chemistry B, Vol. 101, Issue 23
The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013
- Goodenough, John B.; Park, Kyu-Sung
- Journal of the American Chemical Society, Vol. 135, Issue 4
Electrolyte Volume Effects on Electrochemical Performance and Solid Electrolyte Interphase in Si-Graphite/NMC Lithium-Ion Pouch Cells
journal, May 2017
- An, Seong Jin; Li, Jianlin; Daniel, Claus
- ACS Applied Materials & Interfaces, Vol. 9, Issue 22
Current density and state of charge inhomogeneities in Li-ion battery cells with LiFePO4 as cathode material due to temperature gradients
journal, May 2011
- Fleckenstein, Matthias; Bohlen, Oliver; Roscher, Michael A.
- Journal of Power Sources, Vol. 196, Issue 10
A review on the separators of liquid electrolyte Li-ion batteries
journal, January 2007
- Zhang, Sheng Shui
- Journal of Power Sources, Vol. 164, Issue 1
Minimally Invasive Insertion of Reference Electrodes into Commercial Lithium-Ion Pouch Cells
journal, January 2015
- McTurk, E.; Birkl, C. R.; Roberts, M. R.
- ECS Electrochemistry Letters, Vol. 4, Issue 12
Electrochemical Modeling and Performance of a Lithium- and Manganese-Rich Layered Transition-Metal Oxide Positive Electrode
journal, April 2015
- Dees, Dennis W.; Abraham, Daniel P.; Lu, Wenquan
- ECS Meeting Abstracts, Vol. MA2015-01, Issue 2
Works referencing / citing this record:
Investigation of the Influence of Deposition Accuracy of Electrodes on the Electrochemical Properties of Lithium‐Ion Batteries
journal, May 2019
- Leithoff, Ruben; Fröhlich, Arian; Dröder, Klaus
- Energy Technology, Vol. 8, Issue 2
Identifying rate limitation and a guide to design of fast‐charging Li‐ion battery
journal, December 2019
- Zhang, Sheng S.
- InfoMat, Vol. 2, Issue 5
Fast Charging of Li-Ion Cells: Part I. Using Li/Cu Reference Electrodes to Probe Individual Electrode Potentials
journal, January 2019
- Rodrigues, Marco-Tulio F.; Kalaga, Kaushik; Trask, Stephen E.
- Journal of The Electrochemical Society, Vol. 166, Issue 6
Critical Review of the Use of Reference Electrodes in Li-Ion Batteries: A Diagnostic Perspective
journal, January 2019
- Raccichini, Rinaldo; Amores, Marco; Hinds, Gareth
- Batteries, Vol. 5, Issue 1