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Title: Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials

Abstract

Since the discovery of Dirac physics in graphene, research in 2D materials has exploded with the aim of finding new materials and harnessing their unique and tunable electronic and optical properties. The follow-on work on 2D dielectrics and semiconductors has led to the emergence and development of hexagonal boron nitride, black phosphorus, and transition metal disulfides. However, the spectrum of good insulating materials is still very narrow. Likewise, 2D materials exhibiting correlated phenomena such as superconductivity, magnetism, and ferroelectricity have yet to be developed or discovered. These properties will significantly enrich the spectrum of functional 2D materials, particularly in the case of high phase-transition temperatures. They will also advance a fascinating fundamental frontier of size and proximity effects on correlated ground states. In this work, a broad family of layered metal thio(seleno)phosphate materials that are moderate- to wide-bandgap semiconductors with incipient ionic conductivity and a host of ferroic properties are reviewed. It is argued that this material class has the potential to merge the sought-after properties of complex oxides with electronic functions of 2D and quasi-2D electronic materials, as well as to create new avenues for both applied and fundamental materials research in structural and magnetic correlations.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [2]
  1. Air Force Research Lab. (AFRL), Wright-Patterson AFB, OH (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); UES Inc., Beavercreek, OH (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1842642
Alternate Identifier(s):
OSTI ID: 1375659
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 29; Journal Issue: 38; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 2D materials; ferroelectrics; ferroic materials; magnetic materials; metal thiophosphates

Citation Formats

Susner, Michael A., Chyasnavichyus, Marius, McGuire, Michael A., Ganesh, Panchapakesan, and Maksymovych, Petro. Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials. United States: N. p., 2017. Web. doi:10.1002/adma.201602852.
Susner, Michael A., Chyasnavichyus, Marius, McGuire, Michael A., Ganesh, Panchapakesan, & Maksymovych, Petro. Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials. United States. https://doi.org/10.1002/adma.201602852
Susner, Michael A., Chyasnavichyus, Marius, McGuire, Michael A., Ganesh, Panchapakesan, and Maksymovych, Petro. Mon . "Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials". United States. https://doi.org/10.1002/adma.201602852. https://www.osti.gov/servlets/purl/1842642.
@article{osti_1842642,
title = {Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials},
author = {Susner, Michael A. and Chyasnavichyus, Marius and McGuire, Michael A. and Ganesh, Panchapakesan and Maksymovych, Petro},
abstractNote = {Since the discovery of Dirac physics in graphene, research in 2D materials has exploded with the aim of finding new materials and harnessing their unique and tunable electronic and optical properties. The follow-on work on 2D dielectrics and semiconductors has led to the emergence and development of hexagonal boron nitride, black phosphorus, and transition metal disulfides. However, the spectrum of good insulating materials is still very narrow. Likewise, 2D materials exhibiting correlated phenomena such as superconductivity, magnetism, and ferroelectricity have yet to be developed or discovered. These properties will significantly enrich the spectrum of functional 2D materials, particularly in the case of high phase-transition temperatures. They will also advance a fascinating fundamental frontier of size and proximity effects on correlated ground states. In this work, a broad family of layered metal thio(seleno)phosphate materials that are moderate- to wide-bandgap semiconductors with incipient ionic conductivity and a host of ferroic properties are reviewed. It is argued that this material class has the potential to merge the sought-after properties of complex oxides with electronic functions of 2D and quasi-2D electronic materials, as well as to create new avenues for both applied and fundamental materials research in structural and magnetic correlations.},
doi = {10.1002/adma.201602852},
journal = {Advanced Materials},
number = 38,
volume = 29,
place = {United States},
year = {Mon Aug 21 00:00:00 EDT 2017},
month = {Mon Aug 21 00:00:00 EDT 2017}
}

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  • Cheng, Zhongzhou; Shifa, Tofik Ahmed; Wang, Fengmei
  • Advanced Materials, Vol. 30, Issue 26
  • DOI: 10.1002/adma.201707433

Probing and controlling magnetic states in 2D layered magnetic materials
journal, September 2019


Robust two-dimensional ferroelectricity in single-layer γ-SbP and γ-SbAs
journal, January 2019

  • Shen, Shiying; Liu, Chang; Ma, Yandong
  • Nanoscale, Vol. 11, Issue 24
  • DOI: 10.1039/c9nr02265a

Photochemical HER activity of layered metal phospho-sulfides and -selenides
journal, January 2019

  • Barua, Manaswee; Ayyub, Mohd Monis; Vishnoi, Pratap
  • Journal of Materials Chemistry A, Vol. 7, Issue 39
  • DOI: 10.1039/c9ta06044h

NiPS 3 nanosheets for passive pulse generation in an Er-doped fiber laser
journal, January 2019

  • Wang, Jin; Wang, Tao; Shi, Xinyao
  • Journal of Materials Chemistry C, Vol. 7, Issue 46
  • DOI: 10.1039/c9tc04722k

Suppression of magnetic ordering in XXZ-type antiferromagnetic monolayer NiPS3
text, January 2019