Water Reactivity on the LaCoO3(001) Surface: An Ambient Pressure X-ray Photoelectron Spectroscopy Study

Stoerzinger, Kelsey A.; Hong, Wesley T.; Crumlin, Ethan J.; Bluhm, Hendrik; Biegalski, Michael D.; Shao-Horn, Yang

doi:10.1021/jp502970r

Title: Water Reactivity on the LaCoO₃(001) Surface: An Ambient Pressure X-ray Photoelectron Spectroscopy Study

Authors:

Stoerzinger, Kelsey A.; Hong, Wesley T.; Crumlin, Ethan J.; Bluhm, Hendrik; Biegalski, Michael D. ^[1]; Shao-Horn, Yang

Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States

Publication Date:: Mon Aug 18 00:00:00 EDT 2014

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1374899

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Published Article

Journal Name:: Journal of Physical Chemistry. C

Additional Journal Information:: Journal Name: Journal of Physical Chemistry. C Journal Volume: 118 Journal Issue: 34; Journal ID: ISSN 1932-7447

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Stoerzinger, Kelsey A., Hong, Wesley T., Crumlin, Ethan J., Bluhm, Hendrik, Biegalski, Michael D., and Shao-Horn, Yang. Water Reactivity on the LaCoO3(001) Surface: An Ambient Pressure X-ray Photoelectron Spectroscopy Study.  United States: N. p., 2014. 
Web.  doi:10.1021/jp502970r.

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                    Stoerzinger, Kelsey A., Hong, Wesley T., Crumlin, Ethan J., Bluhm, Hendrik, Biegalski, Michael D., & Shao-Horn, Yang. Water Reactivity on the LaCoO3(001) Surface: An Ambient Pressure X-ray Photoelectron Spectroscopy Study.  United States.  https://doi.org/10.1021/jp502970r

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                    Stoerzinger, Kelsey A., Hong, Wesley T., Crumlin, Ethan J., Bluhm, Hendrik, Biegalski, Michael D., and Shao-Horn, Yang. Mon .  
"Water Reactivity on the LaCoO3(001) Surface: An Ambient Pressure X-ray Photoelectron Spectroscopy Study".  United States.  https://doi.org/10.1021/jp502970r.

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@article{osti_1374899,

  title        = {Water Reactivity on the LaCoO3(001) Surface: An Ambient Pressure X-ray Photoelectron Spectroscopy Study},

  author       = {Stoerzinger, Kelsey A. and Hong, Wesley T. and Crumlin, Ethan J. and Bluhm, Hendrik and Biegalski, Michael D. and Shao-Horn, Yang},

  abstractNote = {},

  doi          = {10.1021/jp502970r},

  journal      = {Journal of Physical Chemistry. C},

  number       = 34,

  volume       = 118,

  place        = {United States},

  year         = {Mon Aug 18 00:00:00 EDT 2014},

  month        = {Mon Aug 18 00:00:00 EDT 2014}

}

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Title: Water Reactivity on the LaCoO3(001) Surface: An Ambient Pressure X-ray Photoelectron Spectroscopy Study

Citation Formats

Catalytically Active Oxygen Species in La 1 - x Sr x CoO 3 - δ Studied by XPS and XAFS Spectroscopy journal, August 2000

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Growth of Thin Film Water on α-Al 2 O 3 (0001): An FTIR Study journal, November 2008

The Nature of Water Nucleation Sites on TiO 2 (110) Surfaces Revealed by Ambient Pressure X-ray Photoelectron Spectroscopy journal, June 2007

Surface behaviour of reduced LaCoO3 as studied by TPD of CO, CO2 and H2 probes and by XPS journal, April 1988

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Non-stoichiometric surface behaviour of LaMO3 oxides as evidenced by XPS journal, January 1987

LDA+U evaluation of the stability of low-index facets of LaCoO3 perovskite journal, January 2014

X-ray Photoemission and Density Functional Theory Study of the Interaction of Water Vapor with the Fe 3 O 4 (001) Surface at Near-Ambient Conditions journal, February 2013

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Many Body Effect in Inner Shell Photoemission and Photoabsorption Spectra of La Compounds journal, February 1987

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Thousandfold Change in Resistivity in Magnetoresistive La-Ca-Mn-O Films journal, April 1994

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Systematic x-ray photoelectron spectroscopic study of La1?xSrx-based perovskite-type oxides journal, January 2002

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XPS study of the surface carbonation/hydroxylation state of metal oxides journal, September 1990

Electronic structures of active sites on metal oxide surfaces: definition of the copper-zinc oxide methanol synthesis catalyst by photoelectron spectroscopy journal, December 1993

In Situ Ambient Pressure X-ray Photoelectron Spectroscopy of Cobalt Perovskite Surfaces under Cathodic Polarization at High Temperatures journal, July 2013

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Electrolysis of water on oxide surfaces journal, September 2007

Primary and secondary oxygen-induced C1s binding energy shifts in x-ray photoelectron spectroscopy of polymers journal, August 1992

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Electronic structure and surface reactivity of La1-xSrxCoO3 journal, January 1999

Characterization of hydroxylated oxide film on iron surfaces and its acid-base properties using XPS journal, December 1992

Structural phenomena associated with the spin-state transition in LaCoO 3 journal, September 2002

XPS characterisation of in situ treated lanthanum oxide and hydroxide using tailored charge referencing and peak fitting procedures journal, July 2011

Photoelectron spectroscopy of surfaces under humid conditions journal, March 2010

Title: Water Reactivity on the LaCoO₃(001) Surface: An Ambient Pressure X-ray Photoelectron Spectroscopy Study

Catalytically Active Oxygen Species in La ₁ _- _x Sr _x CoO ₃ _- _δ Studied by XPS and XAFS Spectroscopy
journal, August 2000

The interaction of water with solid surfaces: Fundamental aspects
journal, October 1987

Photoelectron spectroscopy under ambient pressure and temperature conditions
journal, March 2009

In situ investigation of electrochemical devices using ambient pressure photoelectron spectroscopy
journal, October 2013

Revealing the atomic structure and strontium distribution in nanometer-thick La0.8Sr0.2CoO3−δ grown on (001)-oriented SrTiO3
journal, January 2014

Surface strontium enrichment on highly active perovskites for oxygen electrocatalysis in solid oxide fuel cells
journal, January 2012

Oxygen Permeation Through Perovskite-Type Oxides
journal, November 1985

XPS studies of the oxygen 1s and 2s levels in a wide range of functional polymers
journal, June 1993

Dynamics of Water Adsorption onto a Calcite Surface as a Function of Relative Humidity
journal, February 2008

Water adsorption on SrTiO3(001): II. Water, water, everywhere
journal, May 2012

Growth of Thin Film Water on α-Al ₂ O ₃ (0001): An FTIR Study
journal, November 2008

The Nature of Water Nucleation Sites on TiO ₂ (110) Surfaces Revealed by Ambient Pressure X-ray Photoelectron Spectroscopy
journal, June 2007

Surface behaviour of reduced LaCoO3 as studied by TPD of CO, CO2 and H2 probes and by XPS
journal, April 1988

X-ray photoelectron spectroscopic and ion scattering study of the SrTiO3(001) surface
journal, February 2001

X-ray photoelectron studies on some oxides and hydroxides of cobalt, nickel, and copper
journal, November 1975

Non-stoichiometric surface behaviour of LaMO3 oxides as evidenced by XPS
journal, January 1987

LDA+U evaluation of the stability of low-index facets of LaCoO3 perovskite
journal, January 2014

X-ray Photoemission and Density Functional Theory Study of the Interaction of Water Vapor with the Fe ₃ O ₄ (001) Surface at Near-Ambient Conditions
journal, February 2013

Adsorption of CO2 on the perovskite-type oxide LaCoO3
journal, January 1981

$d$ -Band Surface States on Transition-Metal Perovskite Crystals: I. Qualitative Features and Application to SrTi $O_{3}$
journal, February 1973

The effect of carbonate contaminations on the XPS O 1s band structure in metal oxides
journal, March 1991

Complex Interaction of Hydrogen with the RuO ₂ (110) Surface
journal, March 2007

The interaction of water with solid surfaces: fundamental aspects revisited
journal, May 2002

Oxygen adsorption at ${La}_{1 - x} {Sr}_{x} {MnO}_{3}$ (001) surfaces: Predictions from first principles
journal, February 2011

Polar surfaces of oxides: reactivity and reconstruction
journal, September 1995

Relationship between surface dipole, work function and charge transfer: Some exceptions to an established rule
journal, November 2003

Formation of hydroxyl and water layers on MgO films studied with ambient pressure XPS
journal, January 2011

Many Body Effect in Inner Shell Photoemission and Photoabsorption Spectra of La Compounds
journal, February 1987

A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles
journal, October 2011

Thousandfold Change in Resistivity in Magnetoresistive La-Ca-Mn-O Films
journal, April 1994

Concepts of Modern Catalysis and Kinetics
book, October 2003

Systematic x-ray photoelectron spectroscopic study of La1?xSrx-based perovskite-type oxides
journal, January 2002

Electron-spectroscopy study of rare-earth trihalides
journal, November 1993

XPS study of the surface carbonation/hydroxylation state of metal oxides
journal, September 1990

Electronic structures of active sites on metal oxide surfaces: definition of the copper-zinc oxide methanol synthesis catalyst by photoelectron spectroscopy
journal, December 1993

In Situ Ambient Pressure X-ray Photoelectron Spectroscopy of Cobalt Perovskite Surfaces under Cathodic Polarization at High Temperatures
journal, July 2013

Low-cost Oxygen Electrode Material
journal, May 1970

Investigation of solid/vapor interfaces using ambient pressure X-ray photoelectron spectroscopy
journal, January 2013

Reversible Compositional Control of Oxide Surfaces by Electrochemical Potentials
journal, December 2011

Determination of the concentration of surface hydroxyl groups on metal oxide films by a quantitative XPS method
journal, July 1998

Ferroelectric and antiferroelectric coupling in superlattices of paraelectric perovskites at room temperature
journal, July 2003

Electrolysis of water on oxide surfaces
journal, September 2007

Primary and secondary oxygen-induced C1s binding energy shifts in x-ray photoelectron spectroscopy of polymers
journal, August 1992

Water Dissociation on Ru(001): An Activated Process
journal, November 2004

Steady state oxygenreduction and cyclic voltammetry
journal, January 2009

Surface Electronic Structure Transitions at High Temperature on Perovskite Oxides: The Case of Strained La _0.8 Sr _0.2 CoO ₃ Thin Films
journal, November 2011

Note: Fixture for characterizing electrochemical devices in-operando in traditional vacuum systems
journal, August 2010

An Emergent Change of Phase for Electronics
journal, March 2010

Water Adsorption on α-Fe ₂ O ₃ (0001) at near Ambient Conditions
journal, January 2010

Chemisorption of water and carbon dioxide on nanostructured BaTiO3–SrTiO3(001) surfaces
journal, September 2009

The stability of LaMnO3 surfaces: a hybrid exchange density functional theory study of an alkaline fuel cell catalyst
journal, January 2013

The stability of ionic crystal surfaces
journal, November 1979

Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries
journal, June 2011

Electronic structure and surface reactivity of La1-xSrxCoO3
journal, January 1999

Characterization of hydroxylated oxide film on iron surfaces and its acid-base properties using XPS
journal, December 1992

Structural phenomena associated with the spin-state transition in ${LaCoO}_{3}$
journal, September 2002

XPS characterisation of in situ treated lanthanum oxide and hydroxide using tailored charge referencing and peak fitting procedures
journal, July 2011

Photoelectron spectroscopy of surfaces under humid conditions
journal, March 2010