TEM study of the martensitic phases in the ductile DyCu and YCu intermetallic compounds [The martensitic phase transformation in ductile DyCu and YCu intermetallic compounds]

Cao, G. H.; Oertel, C. -G.; Schaarschuch, R.; Skrotzki, W.; Russell, A. M.

doi:10.1016/j.actamat.2017.05.005

Title: TEM study of the martensitic phases in the ductile DyCu and YCu intermetallic compounds [The martensitic phase transformation in ductile DyCu and YCu intermetallic compounds]

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Abstract

DyCu and YCu are representatives of the family of CsCl-type B2 rare earth intermetallic compounds that exhibit high room temperature ductility. Structure, orientation relationship, and morphology of the martensites in the equiatomic compounds DyCu and YCu are examined using transmission electron microscopy (TEM). TEM studies show that the martensite structures in DyCu and YCu alloys are virtually identical. The martensite is of orthorhombic CrB-type B33 structure with lattice parameters a = 0.38 nm, b = 1.22 nm, and c = 0.40 nm. (021¯) twins were observed in the B33 DyCu and YCu martensites. The orientation relationship of B33 and B2 phases is (111¯)[112]B33 || (110)[001]B2. The simulated electron diffraction patterns of the B33 phase are consistent with those of experimental observations. TEM investigations also reveal that a dominant orthorhombic FeB-type B27 martensite with lattice parameters a = 0.71 nm, b = 0.45 nm, and c = 0.54 nm exists in YCu alloy. (11¯ 1) twins were observed in the B27 YCu martensite. As a result, the formation mechanism of B2 to B33 and B2 to B27 phase transformation is discussed.

Authors:

Cao, G. H. ^[1]; Oertel, C. -G. ^[2]; Schaarschuch, R. ^[2]; Skrotzki, W. ^[2]; Russell, A. M. ^[3]

Shanghai Univ., Shanghai (China)
Technische Univ. Dresden, Dresden (Germany)
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)

Publication Date:: 2017-05-03

Research Org.:: Ames Lab., Ames, IA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1374742

Alternate Identifier(s):: OSTI ID: 1398631

Report Number(s):: IS-J-9402
Journal ID: ISSN 1359-6454; PII: S1359645417303828

Grant/Contract Number:: AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: Acta Materialia

Additional Journal Information:: Journal Volume: 132; Journal Issue: C; Journal ID: ISSN 1359-6454

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; Intermetallic compounds; Phase transformation; Microstructure; Transmission electron microscopy (TEM)

Citation Formats


                    Cao, G. H., Oertel, C. -G., Schaarschuch, R., Skrotzki, W., and Russell, A. M. TEM study of the martensitic phases in the ductile DyCu and YCu intermetallic compounds [The martensitic phase transformation in ductile DyCu and YCu intermetallic compounds].  United States: N. p., 2017. 
        Web.  doi:10.1016/j.actamat.2017.05.005.

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                    Cao, G. H., Oertel, C. -G., Schaarschuch, R., Skrotzki, W., & Russell, A. M. TEM study of the martensitic phases in the ductile DyCu and YCu intermetallic compounds [The martensitic phase transformation in ductile DyCu and YCu intermetallic compounds].  United States.  doi:https://doi.org/10.1016/j.actamat.2017.05.005

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                    Cao, G. H., Oertel, C. -G., Schaarschuch, R., Skrotzki, W., and Russell, A. M. Wed .  
        "TEM study of the martensitic phases in the ductile DyCu and YCu intermetallic compounds [The martensitic phase transformation in ductile DyCu and YCu intermetallic compounds]".  United States.  doi:https://doi.org/10.1016/j.actamat.2017.05.005.  https://www.osti.gov/servlets/purl/1374742.

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@article{osti_1374742,

  title        = {TEM study of the martensitic phases in the ductile DyCu and YCu intermetallic compounds [The martensitic phase transformation in ductile DyCu and YCu intermetallic compounds]},

  author       = {Cao, G. H. and Oertel, C. -G. and Schaarschuch, R. and Skrotzki, W. and Russell, A. M.},

  abstractNote = {DyCu and YCu are representatives of the family of CsCl-type B2 rare earth intermetallic compounds that exhibit high room temperature ductility. Structure, orientation relationship, and morphology of the martensites in the equiatomic compounds DyCu and YCu are examined using transmission electron microscopy (TEM). TEM studies show that the martensite structures in DyCu and YCu alloys are virtually identical. The martensite is of orthorhombic CrB-type B33 structure with lattice parameters a = 0.38 nm, b = 1.22 nm, and c = 0.40 nm. (021¯) twins were observed in the B33 DyCu and YCu martensites. The orientation relationship of B33 and B2 phases is (111¯)[112]B33 || (110)[001]B2. The simulated electron diffraction patterns of the B33 phase are consistent with those of experimental observations. TEM investigations also reveal that a dominant orthorhombic FeB-type B27 martensite with lattice parameters a = 0.71 nm, b = 0.45 nm, and c = 0.54 nm exists in YCu alloy. (11¯ 1) twins were observed in the B27 YCu martensite. As a result, the formation mechanism of B2 to B33 and B2 to B27 phase transformation is discussed.},

  doi          = {10.1016/j.actamat.2017.05.005},

  journal      = {Acta Materialia},

  number       = C,

  volume       = 132,

  place        = {United States},

  year         = {2017},

  month        = {5}

}

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DOI: https://doi.org/10.1016/j.actamat.2017.05.005

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