skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Removal or storage of environmental pollutants and alternative fuel sources with inorganic adsorbents via host–guest encapsulation

Abstract

The ever-increasing demands of the modern world continue to place substantial strain on the environment. To help alleviate the damage done to the natural world, the encapsulation of small molecules or ions (guests) into porous inorganic structural frameworks (hosts) provides a potential remedy for some of the environmental concerns facing us today. These concerns include the removal of harmful pollutants from water or air, the safe entrapment of nuclear waste materials, or the purification and storage of small molecules that act as alternative fuel sources. For this study, we review the trends in using inorganic materials as hostmedia for the removal or storage of various wastes and alternative fuels. In conclusion, we cover the treatment of water contaminated with dyes or heavy metals, air pollution alleviation via CO2, SOx, NOx, and volatile organic compound containment, nuclear waste immobilization, and storage for H2 and methane as alternative fuels.

Authors:
 [1]; ORCiD logo [2]
  1. Univ. of Cambridge (United Kingdom). Cavendish Lab. Department of Physics
  2. Univ. of Cambridge (United Kingdom). Cavendish Lab. Department of Physics; Rutherford Appleton Laboratory (United Kingdom). ISIS Neutron and Muon Source; Univ. of Cambridge (United Kingdom). Department of Chemical Engineering and Biotechnology; Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1374716
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 5; Journal Issue: 22; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES

Citation Formats

Cramer, Alisha J., and Cole, Jacqueline M. Removal or storage of environmental pollutants and alternative fuel sources with inorganic adsorbents via host–guest encapsulation. United States: N. p., 2017. Web. doi:10.1039/c7ta02401k.
Cramer, Alisha J., & Cole, Jacqueline M. Removal or storage of environmental pollutants and alternative fuel sources with inorganic adsorbents via host–guest encapsulation. United States. doi:10.1039/c7ta02401k.
Cramer, Alisha J., and Cole, Jacqueline M. Mon . "Removal or storage of environmental pollutants and alternative fuel sources with inorganic adsorbents via host–guest encapsulation". United States. doi:10.1039/c7ta02401k. https://www.osti.gov/servlets/purl/1374716.
@article{osti_1374716,
title = {Removal or storage of environmental pollutants and alternative fuel sources with inorganic adsorbents via host–guest encapsulation},
author = {Cramer, Alisha J. and Cole, Jacqueline M.},
abstractNote = {The ever-increasing demands of the modern world continue to place substantial strain on the environment. To help alleviate the damage done to the natural world, the encapsulation of small molecules or ions (guests) into porous inorganic structural frameworks (hosts) provides a potential remedy for some of the environmental concerns facing us today. These concerns include the removal of harmful pollutants from water or air, the safe entrapment of nuclear waste materials, or the purification and storage of small molecules that act as alternative fuel sources. For this study, we review the trends in using inorganic materials as hostmedia for the removal or storage of various wastes and alternative fuels. In conclusion, we cover the treatment of water contaminated with dyes or heavy metals, air pollution alleviation via CO2, SOx, NOx, and volatile organic compound containment, nuclear waste immobilization, and storage for H2 and methane as alternative fuels.},
doi = {10.1039/c7ta02401k},
journal = {Journal of Materials Chemistry. A},
number = 22,
volume = 5,
place = {United States},
year = {2017},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 8 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Removal of a cationic dye from aqueous solutions by adsorption onto bentonite clay
journal, June 2006


Metal−Diboride Nanotubes as High-Capacity Hydrogen Storage Media
journal, March 2007

  • Meng, Sheng; Kaxiras, Efthimios; Zhang, Zhenyu
  • Nano Letters, Vol. 7, Issue 3
  • DOI: 10.1021/nl062692g

Adsorptive removal of thorium(IV) from aqueous solutions using poly(methacrylic acid)-grafted chitosan/bentonite composite matrix: Process design and equilibrium studies
journal, September 2010

  • Anirudhan, Thayyath Sreenivasan; Rijith, Sreenivasan; Tharun, Abdul Rauf
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 368, Issue 1-3
  • DOI: 10.1016/j.colsurfa.2010.07.005

Controlled fabrication of ultrathin-shell BN hollow spheres with excellent performance in hydrogen storage and wastewater treatment
journal, January 2012

  • Lian, Gang; Zhang, Xiao; Zhang, Shunjie
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee03240f

Ion exchangers in radioactive waste management. Part XI. Removal of barium and strontium ions from aqueous solutions by hydrous ferric oxide
journal, October 1999


Recovery of Lithium from Seawater Using Manganese Oxide Adsorbent (H1.6Mn1.6O4) Derived from Li1.6Mn1.6O4
journal, May 2001

  • Chitrakar, Ramesh; Kanoh, Hirofumi; Miyai, Yoshitaka
  • Industrial & Engineering Chemistry Research, Vol. 40, Issue 9, p. 2054-2058
  • DOI: 10.1021/ie000911h

Arsenic removal from water/wastewater using adsorbents—A critical review
journal, April 2007


Application of Silver Impregnated Iodine Adsorbent to Nuclear Facilities
journal, January 2008

  • Fukasawa, Tetsuo; Nakamura, Tomotaka; Kondo, Yoshikazu
  • Journal of Power and Energy Systems, Vol. 2, Issue 1
  • DOI: 10.1299/jpes.2.67

Thermodynamics of High-Pressure Adsorption of Argon, Nitrogen, and Methane on Microporous Adsorbents
journal, June 1998

  • Salem, M. M. K.; Braeuer, P.; Szombathely, M. v.
  • Langmuir, Vol. 14, Issue 12
  • DOI: 10.1021/la970119u

Adsorbent materials commonly used in air analysis for adsorptive enrichment and thermal desorption of volatile organic compounds
journal, June 2002


VOC Removal:  Comparison of MCM-41 with Hydrophobic Zeolites and Activated Carbon
journal, November 1998

  • Zhao, X. S.; Ma, Q.; Lu, G. Q. (Max)
  • Energy & Fuels, Vol. 12, Issue 6
  • DOI: 10.1021/ef980113s

Dye removal from wastewater by adsorption on ‘waste’ Fe(III)/Cr(III) hydroxide
journal, January 1994


Selective Adsorption of SO 2 from Flue Gas on Triethanolamine-Modified Large Pore SBA-15
journal, July 2011

  • Zhi, Yongting; Zhou, Yaping; Su, Wei
  • Industrial & Engineering Chemistry Research, Vol. 50, Issue 14
  • DOI: 10.1021/ie2004658

Sorbent trapping of volatile organic compounds from air
journal, July 2000


Adsorption of thorium from aqueous solutions by perlite
journal, February 2009


New sorbents for hydrogen storage by hydrogen spillover – a review
journal, January 2008

  • Wang, Lifeng; Yang, Ralph T.
  • Energy & Environmental Science, Vol. 1, Issue 2
  • DOI: 10.1039/b807957a

Adsorption of methylene blue and orange II onto unmodified and surfactant-modified zeolite
journal, December 2008

  • Jin, Xiaoying; Jiang, Ming-qin; Shan, Xaio-quan
  • Journal of Colloid and Interface Science, Vol. 328, Issue 2
  • DOI: 10.1016/j.jcis.2008.08.066

Adsorption of basic dyes on granular acivated carbon and natural zeolite
journal, October 2001


Assessment of a Sodium Nonatitanate and Pharmacosiderite-Type Ion Exchangers for Strontium and Cesium Removal from DOE Waste Simulants
journal, January 1998

  • Behrens, Elizabeth A.; Sylvester, Paul; Clearfield, Abraham
  • Environmental Science & Technology, Vol. 32, Issue 1
  • DOI: 10.1021/es9704794

Phosphates as Nuclear Waste Forms
journal, January 2002


Glass fabrication and product consistency testing of lanthanide borosilicate glass for plutonium disposition
journal, October 2007


Recent progress in hydrogen storage alloys for nickel/metal hydride secondary batteries
journal, June 2009


Decolorization of textile wastewater by photo-fenton oxidation technology
journal, October 2000


Comparison of the adsorption characteristics of azo-reactive dyes on mezoporous minerals
journal, July 2004


Use of silicotitanates for removing cesium and strontium from defense waste
journal, November 1994

  • Anthony, Rayford G.; Dosch, Robert G.; Gu, Ding
  • Industrial & Engineering Chemistry Research, Vol. 33, Issue 11
  • DOI: 10.1021/ie00035a020

Adsorption of CH 4 −CF 4 Mixtures in Silicalite:  Simulation, Experiment, and Theory
journal, December 1997

  • Heuchel, Matthias; Snurr, Randall Q.; Buss, Eckhard
  • Langmuir, Vol. 13, Issue 25
  • DOI: 10.1021/la9708039

Study of thermal and CH4 adsorption properties
journal, June 2015


Mechanism of High-Temperature CO 2 Sorption on Lithium Zirconate
journal, May 2003

  • Ida, Jun-ichi; Lin, Y. S.
  • Environmental Science & Technology, Vol. 37, Issue 9
  • DOI: 10.1021/es0259032

Removal of crystal violet dye from wastewater by surfactant-modified alumina
journal, July 2005


Adsorption and Hydrophobic Properties of Mesostructured MCM-41 and SBA-15 Materials for Volatile Organic Compound Removal
journal, October 2004

  • Serrano, David P.; Calleja, Guillermo; Botas, Juan A.
  • Industrial & Engineering Chemistry Research, Vol. 43, Issue 22
  • DOI: 10.1021/ie040108d

Borosilicate and lead silicate glass matrix composites containing pyrochlore phases for nuclear waste encapsulation
journal, May 2004


Inorganic adsorbent containing polymeric membrane reservoir for the recovery of lithium from seawater
journal, December 2008


Application of zeolite MCM-22 for basic dye removal from wastewater
journal, March 2006

  • Wang, Shaobin; Li, Huiting; Xu, Longya
  • Journal of Colloid and Interface Science, Vol. 295, Issue 1
  • DOI: 10.1016/j.jcis.2005.08.006

Separation of Methane and Carbon Dioxide Gas Mixtures by Pressure Swing Adsorption
journal, May 1988


A practical review of the performance of organic and inorganic adsorbents for the treatment of contaminated waters
journal, January 2006

  • San Miguel, Guillermo; Lambert, Steven D.; Graham, Nigel JD
  • Journal of Chemical Technology & Biotechnology, Vol. 81, Issue 10
  • DOI: 10.1002/jctb.1600

Recent developments in novel sorbents for flue gas clean up
journal, October 2010


The Design and Evaluation of Nuclear-Waste Forms: Clues from Mineralogy
journal, June 2001


Low-cost adsorbents for heavy metals uptake from contaminated water: a review
journal, February 2003


Influence of acid and heavy metal cation exchange treatments on methane adsorption properties of mordenite
journal, January 2015

  • Sakizci, Meryem; ÖZgÜL Tanriverdİ, Leyla
  • TURKISH JOURNAL OF CHEMISTRY, Vol. 39
  • DOI: 10.3906/kim-1501-71

Study of the behaviour of thorium adsorption on PAN/zeolite composite adsorbent
journal, August 2007


Techniques for transformation of biogas to biomethane
journal, May 2011


Hydrogen sulfide removal from biogas by zeolite adsorption. Part II. MD simulations
journal, December 2008


De-NOx reactor and NOx sensor using In3+-doped SnP2O7 with PtRhBa/C electrode
journal, September 2008

  • Nagao, Masahiro; Yoshii, Takeshi; Namekata, Yousuke
  • Solid State Ionics, Vol. 179, Issue 27-32
  • DOI: 10.1016/j.ssi.2008.03.033

Tungsten bronze-based nuclear waste form ceramics. Part 3: The system Cs0.3MxW1−xO3 for the immobilization of radio cesium
journal, November 2006


Tungsten bronze-based nuclear waste form ceramics. Part 2: Conversion of granular microporous tungstate–polyacrylonitrile (PAN) composite adsorbents to leach resistant ceramics
journal, November 2006

  • Griffith, Christopher S.; Sebesta, Ferdinand; Hanna, John V.
  • Journal of Nuclear Materials, Vol. 358, Issue 2-3
  • DOI: 10.1016/j.jnucmat.2006.06.018

Complex Hydrides for Hydrogen Storage
journal, October 2007

  • Orimo, Shin-ichi; Nakamori, Yuko; Eliseo, Jennifer R.
  • Chemical Reviews, Vol. 107, Issue 10
  • DOI: 10.1021/cr0501846

Tungsten bronze-based nuclear waste form ceramics. Part 1. Conversion of microporous tungstates to leach resistant ceramics
journal, November 2006

  • Luca, Vittorio; Griffith, Christopher S.; Drabarek, Elizabeth
  • Journal of Nuclear Materials, Vol. 358, Issue 2-3
  • DOI: 10.1016/j.jnucmat.2006.06.017

Novel hydrogen storage materials: A review of lightweight complex hydrides
journal, August 2010


Liquid Radioactive Wastes Treatment: A Review
journal, May 2011

  • Rahman, R. O. Abdel; Ibrahium, H. A.; Hung, Yung-Tse
  • Water, Vol. 3, Issue 2
  • DOI: 10.3390/w3020551

Comparison of Cadmium Adsorption by Inorganic Adsorbents in Column Systems
journal, May 2014

  • Gutiérrez-Segura, E.; Solache-Ríos, M.; Colín-Cruz, A.
  • Water, Air, & Soil Pollution, Vol. 225, Issue 6
  • DOI: 10.1007/s11270-014-1943-8

Removal of Cs1+, Sr2+ and Co2+ from aqueous solutions by adsorption on natural clinoptilolite
journal, January 2007


Radiation effects in nuclear waste forms for high-level radioactive waste
journal, January 1995


Complex Rare-Earth Aluminum Hydrides: Mechanochemical Preparation, Crystal Structure and Potential for Hydrogen Storage
journal, November 2009

  • Weidenthaler, Claudia; Pommerin, André; Felderhoff, Michael
  • Journal of the American Chemical Society, Vol. 131, Issue 46
  • DOI: 10.1021/ja9042565

Novel Polyethylenimine-Modified Mesoporous Molecular Sieve of MCM-41 Type as High-Capacity Adsorbent for CO2 Capture
journal, November 2002

  • Xu, Xiaochun; Song, Chunshan; Andresen, John M.
  • Energy & Fuels, Vol. 16, Issue 6, p. 1463-1469
  • DOI: 10.1021/ef020058u

Mercury removal from incineration flue gas by organic and inorganic adsorbents
journal, June 2002


Heavy metal removal from motorway stormwater using zeolites
journal, December 2004


The removal of heavy metal cations by natural zeolites
journal, December 2004


Removal of Volatile Organic Compounds from polluted air
journal, November 2000


CO2 capture by solid adsorbents and their applications: current status and new trends
journal, January 2011

  • Wang, Qiang; Luo, Jizhong; Zhong, Ziyi
  • Energy Environ. Sci., Vol. 4, Issue 1
  • DOI: 10.1039/C0EE00064G

Molecular dynamics simulations of binary mixtures of methane and hydrogen in zeolite A and a novel zinc phosphate
journal, November 2001


Hydrogen storage in binary and ternary Mg-based alloys: A comprehensive experimental study
journal, March 2010


Equilibrium studies on the adsorption of reactive azo dyes into zeolite
journal, October 2004


Adsorption of Carbon Dioxide on Basic Alumina at High Temperatures
journal, November 2000

  • Yong, Zou; Mata, Vera; Rodrigues, Alírio E.
  • Journal of Chemical & Engineering Data, Vol. 45, Issue 6
  • DOI: 10.1021/je000075i

Chemically durable iron phosphate glass wasteforms
journal, November 1998


Batch kinetics and thermodynamics of chromium ions removal from waste solutions using synthetic adsorbents
journal, April 2007


Phosphate removal from wastewater using red mud
journal, October 2008


China clay as an adsorbent for dye house wastewaters
journal, October 1992


Purification of landfill biogases from siloxanes by adsorption: A study of silica and 13X zeolite adsorbents on hexamethylcyclotrisiloxane separation
journal, December 2010

  • Montanari, Tania; Finocchio, Elisabetta; Bozzano, Irene
  • Chemical Engineering Journal, Vol. 165, Issue 3
  • DOI: 10.1016/j.cej.2010.10.032

A study of the uptake of copper ions by nanostructured calcium silicate
journal, October 2006


Adsorption of acid dyes from aqueous solutions onto acid-activated bentonite
journal, August 2004


Application of low-cost adsorbents for dye removal – A review
journal, June 2009


Dynamics of CO 2 Adsorption on Amine Adsorbents. 2. Insights Into Adsorbent Design
journal, November 2012

  • Bollini, Praveen; Brunelli, Nicholas A.; Didas, Stephanie A.
  • Industrial & Engineering Chemistry Research, Vol. 51, Issue 46
  • DOI: 10.1021/ie3017913

Radiation effects in crystalline ceramics for the immobilization of high-level nuclear waste and plutonium
journal, June 1998

  • Weber, W. J.; Ewing, R. C.; Catlow, C. R. A.
  • Journal of Materials Research, Vol. 13, Issue 6
  • DOI: 10.1557/JMR.1998.0205

Hydrogen storage in ion-exchanged zeolites
journal, December 2005


Applications of Pore-Expanded Mesoporous Silica. 2. Development of a High-Capacity, Water-Tolerant Adsorbent for CO 2
journal, October 2005

  • Franchi, Robert S.; Harlick, Peter J. E.; Sayari, Abdelhamid
  • Industrial & Engineering Chemistry Research, Vol. 44, Issue 21
  • DOI: 10.1021/ie0504194

Metal hydride materials for solid hydrogen storage: A review☆
journal, June 2007


Adsorption of hydrogen and deuterium in MnO2 modified NaX zeolites
journal, April 2012


The removal of uranium (VI) from aqueous solutions onto natural sepiolite
journal, July 2009


Removal of synthetic dyes from wastewaters: a review
journal, September 2004


Heavy metal adsorption by a formulated zeolite-Portland cement mixture
journal, August 2007


Adsorption of SOx by oxide materials: A review
journal, October 2013


Performance of Natural Zeolites for the Treatment of Mixed Metal-Contaminated Effluents
journal, August 1997


Reversible Storage of Molecular Hydrogen by Sorption into Multilayered TiO 2 Nanotubes
journal, October 2005

  • Bavykin, Dmitry V.; Lapkin, Alexei A.; Plucinski, Pawel K.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 41
  • DOI: 10.1021/jp0536394

Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources
journal, September 2009

  • Choi, Sunho; Drese, Jeffrey H.; Jones, Christopher W.
  • ChemSusChem, Vol. 2, Issue 9, p. 796-854
  • DOI: 10.1002/cssc.200900036

Microbial decolorization of textile-dyecontaining effluents: A review
journal, December 1996


Thorium and uranium uptake by natural zeolitic materials
journal, December 1995


Tungstate-based glass–ceramics for the immobilization of radio cesium
journal, February 2009


Studies on the feasibility of using crystalline silicotitanates for the separation of cesium-137 from fast reactor high-level liquid waste
journal, March 2009

  • Venkatesan, K. A.; Sukumaran, V.; Antony, M. P.
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 280, Issue 1
  • DOI: 10.1007/s10967-008-7422-1

Computing Adsorption Isotherms for Benzene, Toluene, and p -Xylene in Heulandite Zeolite
journal, December 1999

  • Laboy, Michelle M.; Santiago, Ivonne; López, Gustavo E.
  • Industrial & Engineering Chemistry Research, Vol. 38, Issue 12
  • DOI: 10.1021/ie980732o

Adsorption of volatile organic compounds in Y zeolites and pillared clays
journal, May 2001


Design of New Materials for Methane Storage
journal, March 2004

  • Düren, Tina; Sarkisov, Lev; Yaghi, Omar M.
  • Langmuir, Vol. 20, Issue 7, p. 2683-2689
  • DOI: 10.1021/la0355500

The Influence of Non-framework Sodium Cations on the Adsorption of Alkanes in MFI- and MOR-Type Zeolites
journal, October 2002

  • Beerdsen, Edith; Smit, Berend; Calero, Sofía
  • The Journal of Physical Chemistry B, Vol. 106, Issue 41
  • DOI: 10.1021/jp026257w

Lead-Iron Phosphate Glass: A Stable Storage Medium for High-Level Nuclear Waste
journal, October 1984


Alkali-activated slag cement based radioactive waste forms
journal, January 1991


Adsorption of Hydrogen Isotopes on Micro- and Mesoporous Adsorbents with Orderly Structure
journal, November 2006

  • Chu, Xiao-Zhong; Zhou, Ya-Ping; Zhang, Yu-Zhe
  • The Journal of Physical Chemistry B, Vol. 110, Issue 45
  • DOI: 10.1021/jp064745o

Heavy metal removal from water/wastewater by nanosized metal oxides: A review
journal, April 2012


Polyethylenimine-impregnated siliceous mesocellular foam particles as high capacity CO2 adsorbents
journal, January 2012

  • Zhao, Junqi; Simeon, Fritz; Wang, Yujun
  • RSC Advances, Vol. 2, Issue 16
  • DOI: 10.1039/c2ra20149f

Role of Zr 4+ Cations in NO 2 Adsorption on Ce 1- x Zr x O 2 Mixed Oxides at Ambient Conditions
journal, August 2011

  • Levasseur, Benoit; Ebrahim, Amani M.; Bandosz, Teresa J.
  • Langmuir, Vol. 27, Issue 15
  • DOI: 10.1021/la201338w

Adsorption of phosphate ions on novel inorganic ion exchangers
journal, March 2005

  • Chubar, N. I.; Kanibolotskyy, V. A.; Strelko, V. V.
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 255, Issue 1-3
  • DOI: 10.1016/j.colsurfa.2004.12.015

A review of potentially low-cost sorbents for heavy metals
journal, August 1999


Adsorption equilibrium for sulfur dioxide, nitric oxide, carbon dioxide, nitrogen on 13X and 5A zeolites
journal, April 2012


Chemical hydrides: A solution to high capacity hydrogen storage and supply
journal, January 2008


Adsorption of heavy metals from acid mine drainage by natural zeolite
journal, July 2009

  • Motsi, T.; Rowson, N. A.; Simmons, M. J. H.
  • International Journal of Mineral Processing, Vol. 92, Issue 1-2
  • DOI: 10.1016/j.minpro.2009.02.005

Removal of basic dye from waste-water using silica as adsorbent
journal, January 1992


Hazards of heavy metal contamination
journal, December 2003


Adsorption Equilibria of C 1 to C 4 Alkanes, CO 2 , and SF 6 on Silicalite
journal, February 1998

  • Sun, Matthew S.; Shah, D. B.; Xu, Heather H.
  • The Journal of Physical Chemistry B, Vol. 102, Issue 8
  • DOI: 10.1021/jp9730196

TiO2 functionalization for efficient NOx removal in photoactive cement
journal, November 2014


Involvement of water and visible light in the enhancement in SO2 adsorption at ambient conditions on the surface of zinc (hydr)oxide/graphite oxide composites
journal, May 2013

  • Seredych, Mykola; Mabayoje, Oluwaniyi; Bandosz, Teresa J.
  • Chemical Engineering Journal, Vol. 223
  • DOI: 10.1016/j.cej.2013.03.026

Radioactive cesium removal from nuclear wastewater by novel inorganic and conjugate adsorbents
journal, April 2014

  • Awual, Md. Rabiul; Suzuki, Shinichi; Taguchi, Tomitsugu
  • Chemical Engineering Journal, Vol. 242
  • DOI: 10.1016/j.cej.2013.12.072

Hydrogen Storage on Carbon-Based Adsorbents and Storage at Ambient Temperature by Hydrogen Spillover
journal, October 2010


Boron- and nitrogen-based chemical hydrogen storage materials
journal, March 2009


Removal of congo red from wastewater by adsorption onto waste red mud
journal, January 1997


Adsorption Kinetics of CO 2 , O 2 , N 2 , and CH 4 in Cation-Exchanged Clinoptilolite
journal, February 2001

  • Aguilar-Armenta, Gelacio; Hernandez-Ramirez, Guadalupe; Flores-Loyola, Erika
  • The Journal of Physical Chemistry B, Vol. 105, Issue 7
  • DOI: 10.1021/jp9934331

Mechanism of aqueous uranium (VI) uptake by natural zeolitic tuff
journal, December 2003


Removal of uranium(VI) from aqueous solutions by manganese oxide coated zeolite: discussion of adsorption isotherms and pH effect
journal, January 2007


Adsorption of Bezanyl Red and Nylomine Green from aqueous solutions by natural and acid-activated bentonite
journal, January 2009


Synthesis, Experimental Studies, and Analysis of a New Calcium-Based Carbon Dioxide Absorbent
journal, July 2005

  • Li, Zhen-shan; Cai, Ning-sheng; Huang, Yu-yu
  • Energy & Fuels, Vol. 19, Issue 4
  • DOI: 10.1021/ef0496799

Adsorption of thorium(IV) on MX-80 bentonite: Effect of pH, ionic strength and temperature
journal, September 2008


Adsorption Equilibrium of Methane, Carbon Dioxide, and Nitrogen on Zeolite 13X at High Pressures
journal, July 2004

  • Cavenati, Simone; Grande, Carlos A.; Rodrigues, Alírio E.
  • Journal of Chemical & Engineering Data, Vol. 49, Issue 4
  • DOI: 10.1021/je0498917

On competitive uptake of SO2 and CO2 from air by porous carbon containing CaO and MgO
journal, June 2013

  • Czyżewski, Adam; Kapica, Joanna; Moszyński, Dariusz
  • Chemical Engineering Journal, Vol. 226
  • DOI: 10.1016/j.cej.2013.04.061

A Comparative Study of Adsorbents Prepared from Industrial Wastes for Removal of Dyes
journal, January 2003

  • Jain, A. K.; Gupta, V. K.; Bhatnagar, A.
  • Separation Science and Technology, Vol. 38, Issue 2
  • DOI: 10.1081/SS-120016585

Hydrogen Spillover. Facts and Fiction
journal, February 2012


Study of sulfur dioxide adsorption on Y zeolite
journal, January 2004

  • Marcu, Ioan-Cezar; Sdjndulescu, I.
  • Journal of the Serbian Chemical Society, Vol. 69, Issue 7
  • DOI: 10.2298/JSC0407563M

Crystallization of neodymium-rich phases in silicate glasses developed for nuclear waste immobilization
journal, August 2006


Adsorption of hydrogen on porous materials of activated carbon and zeolite NaX crossover critical temperature
journal, June 2009


Zeolites as media for hydrogen storage*1
journal, December 1995


Comparisons of low-cost adsorbents for treating wastewaters laden with heavy metals
journal, August 2006


Atomistic Simulations of CO 2 and N 2 Adsorption in Silica Zeolites:  The Impact of Pore Size and Shape
journal, August 2002

  • Goj, Anne; Sholl, David S.; Akten, E. Demet
  • The Journal of Physical Chemistry B, Vol. 106, Issue 33
  • DOI: 10.1021/jp025895b

Selective Removal of Cesium from Simulated High-level Liquid Wastes by Insoluble Ferrocyanides
journal, June 1997


Zeolites developed from mixed alkali modified coal fly ash for adsorption of volatile organic compounds
journal, March 2014


Materials for hydrogen storage
journal, September 2003


Hydrogen storage in several microporous zeolites
journal, December 2007


Complex Ammine Titanium(III) Borohydrides as Advanced Solid Hydrogen-Storage Materials with Favorable Dehydrogenation Properties
journal, August 2012

  • Yuan, Feng; Gu, Qinfen; Chen, Xiaowei
  • Chemistry of Materials, Vol. 24, Issue 17
  • DOI: 10.1021/cm301387d

Removal of dyes from aqueous solution using fly ash and red mud
journal, January 2005


SO x /NO x Removal from Flue Gas Streams by Solid Adsorbents: A Review of Current Challenges and Future Directions
journal, August 2015


Porous boron nitride with a high surface area: hydrogen storage and water treatment
journal, March 2013


Comparison absorption of new methylene blue dye in zeolite and nanocrystal zeolite
journal, June 2010


Glass-ceramics: Their production from wastes—A Review
journal, February 2006

  • Rawlings, R. D.; Wu, J. P.; Boccaccini, A. R.
  • Journal of Materials Science, Vol. 41, Issue 3
  • DOI: 10.1007/s10853-006-6554-3

Zirconium Pillared Clays for Carbon Dioxide/Methane Separation. 1. Preparation of Adsorbent Materials and Pure Gas Adsorption
journal, August 1998

  • Pereira, P. R.; Pires, J.; Brotas de Carvalho, M.
  • Langmuir, Vol. 14, Issue 16
  • DOI: 10.1021/la980209e

Structural stability of metal hydrides, alanates and borohydrides of alkali and alkali- earth elements: A review
journal, June 2010


Thorium removal by different adsorbents
journal, February 2003

  • Metaxas, Michail; Kasselouri-Rigopoulou, Vasilia; Galiatsatou, Polymnia
  • Journal of Hazardous Materials, Vol. 97, Issue 1-3
  • DOI: 10.1016/S0304-3894(02)00245-5

Siloxane removal from landfill and digester gas – A technology overview
journal, May 2010


Removal of Rhodamine B, Fast Green, and Methylene Blue from Wastewater Using Red Mud, an Aluminum Industry Waste
journal, March 2004

  • Gupta, V. K.; Ali, Imran
  • Industrial & Engineering Chemistry Research, Vol. 43, Issue 7
  • DOI: 10.1021/ie034218g

Mesoporous materials for the removal of SO2 from gas streams
journal, July 2012


Characterization of nano-crystalline Mg–Ni–Al hydrotalcite derived mixed oxides as hydrogen adsorbent
journal, October 2013


Separation of Radioactive Strontium from Alkaline Nuclear Waste Solutions with the Highly Effective Ion Exchanger SrTreat
journal, July 1999

  • Lehto, Jukka; Brodkin, Leena; Harjula, Risto
  • Nuclear Technology, Vol. 127, Issue 1
  • DOI: 10.13182/NT99-A2985

Hydrogen storage using physisorption – materials demands
journal, May 2001

  • Nijkamp, M. G.; Raaymakers, J. E. M. J.; van Dillen, A. J.
  • Applied Physics A Materials Science & Processing, Vol. 72, Issue 5
  • DOI: 10.1007/s003390100847

Adsorption of arsenite and selenite using an inorganic ion exchanger based on Fe–Mn hydrous oxide
journal, January 2012

  • Szlachta, Małgorzata; Gerda, Vasyl; Chubar, Natalia
  • Journal of Colloid and Interface Science, Vol. 365, Issue 1
  • DOI: 10.1016/j.jcis.2011.09.023

Pyrochlore based glass-ceramics for the immobilization of actinide-rich nuclear wastes: From concept to reality
journal, January 2013


Methane storage on aluminum-doped single wall BNNTs
journal, August 2014


Sorption Behavior of Radionuclides on Crystalline Synthetic Tunnel Manganese Oxides
journal, December 2000

  • Dyer, Alan; Pillinger, Martyn; Newton, Jon
  • Chemistry of Materials, Vol. 12, Issue 12
  • DOI: 10.1021/cm001142v

Adsorption of reactive dyes on titania–silica mesoporous materials
journal, July 2006


Physical and chemical regeneration of zeolitic adsorbents for dye removal in wastewater treatment
journal, September 2006


Adsorption of Cesium, Strontium, and Cobalt Ions on Magnetite and a Magnetite−Silica Composite
journal, April 2001

  • Ebner, Armin D.; Ritter, James A.; Navratil, James D.
  • Industrial & Engineering Chemistry Research, Vol. 40, Issue 7
  • DOI: 10.1021/ie000695c

Membrane techniques for treatment in nuclear waste processing: global experience
journal, November 2008


An Inorganic Microsphere Composite for the Selective Removal of 137 Cesium from Acidic Nuclear Waste Solutions. 1: Equilibrium Capacity and Kinetic Properties of the Sorbent
journal, March 2009

  • Tranter, T. J.; Vereshchagina, T. A.; Utgikar, V.
  • Solvent Extraction and Ion Exchange, Vol. 27, Issue 2
  • DOI: 10.1080/07366290802674549

Disposal of high-level nuclear wastes: a geological perspective
journal, April 1985


Hydrogen Uptake in Boron Nitride Nanotubes at Room Temperature
journal, July 2002

  • Ma, Renzhi; Bando, Yoshio; Zhu, Hongwei
  • Journal of the American Chemical Society, Vol. 124, Issue 26, p. 7672-7673
  • DOI: 10.1021/ja026030e

Adsorption of Radionuclides from Aqueous Solutions by Inorganic Adsorbents
journal, September 1995


Efficient removal of cesium from low-level radioactive liquid waste using natural and impregnated zeolite minerals
journal, December 2009


Titanate Nanofibers as Intelligent Absorbents for the Removal of Radioactive Ions from Water
journal, July 2008

  • Yang, Dong Jiang; Zheng, Zhan Feng; Zhu, Huai Yong
  • Advanced Materials, Vol. 20, Issue 14
  • DOI: 10.1002/adma.200702055

Removal of siloxanes in biogases
journal, May 2001


Decomposition of hexamethylcyclotrisiloxane over solid oxides
journal, August 2008


Hydrogen storage properties of LiBH4
journal, August 2003


Calcium Oxide Doped Sorbents for CO 2 Uptake in the Presence of SO 2 at High Temperatures
journal, June 2009

  • Lu, Hong; Smirniotis, Panagiotis G.
  • Industrial & Engineering Chemistry Research, Vol. 48, Issue 11
  • DOI: 10.1021/ie900162k

Adsorption equilibrium and kinetics for SO2, NO, CO2 on zeolites FAU and LTA
journal, February 2012


Adsorption studies of a water soluble dye, Reactive Red MF-3B, using sonication-surfactant-modified attapulgite clay
journal, May 2007


Treatment of radioactive liquid waste by sorption on natural zeolite in Turkey
journal, September 2006


Ion exchange of 85Sr, 134Cs and 57Co in sodium titanosilicate and the effect of crystallinity on selectivity
journal, July 2002


Color Removal from Dye Wastewater Using Vermiculite
journal, November 1996


Immobilization of spent nuclear fuel in iron phosphate glass
journal, June 1999


Uranium removal from groundwater by natural clinoptilolite zeolite: Effects of pH and initial feed concentration
journal, March 2010


Immobilization of cesium and strontium radionuclides in zeolite-cement blends
journal, August 2006


Removal of mixed heavy metal ions in wastewater by zeolite 4A and residual products from recycled coal fly ash
journal, December 2005


The adsorption kinetics and removal of cationic dye, Toluidine Blue O, from aqueous solution with Turkish zeolite
journal, February 2008


Separation of Heat-Generating Nuclides from High-Level Liquid Wastes through Zeolite Columns
journal, May 1994

  • Mimura, Hitoshi; Akiba, Kenichi; Kawamura, Kazuhiro
  • Journal of Nuclear Science and Technology, Vol. 31, Issue 5
  • DOI: 10.1080/18811248.1994.9735176

Adsorption studies of Toluidine Blue from aqueous solutions onto gypsum
journal, July 2009

  • Rauf, M. A.; Qadri, Shahnaz M.; Ashraf, Sarmadia
  • Chemical Engineering Journal, Vol. 150, Issue 1
  • DOI: 10.1016/j.cej.2008.12.008

Immobilization of stimulated high level wastes into AASC waste form
journal, January 1994


Hydrogen-storage materials for mobile applications
journal, November 2001

  • Schlapbach, Louis; Züttel, Andreas
  • Nature, Vol. 414, Issue 6861
  • DOI: 10.1038/35104634

Altering Hydrogen Storage Properties by Hydride Destabilization through Alloy Formation:  LiH and MgH 2 Destabilized with Si
journal, September 2004

  • Vajo, John J.; Mertens, Florian; Ahn, Channing C.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 37
  • DOI: 10.1021/jp040060h

MgAlFeCu mixed oxides for SO2 removal capacity: Influence of the copper and aluminum incorporation method
journal, June 2012


Preparation of dealuminated faujasites for adsorption of volatile organic compounds
journal, September 2002

  • Pires, Jo??o; Carvalho, Ana; Veloso, Patr??cia
  • Journal of Materials Chemistry, Vol. 12, Issue 10
  • DOI: 10.1039/b205367e

Sodium-doped lithium zirconate nano squares: synthesis, characterization and applications for CO2 sequestration
journal, November 2011

  • Khokhani, Mrinal; Khomane, Ramdas B.; Kulkarni, Bhaskar D.
  • Journal of Sol-Gel Science and Technology, Vol. 61, Issue 2
  • DOI: 10.1007/s10971-011-2629-y

Progress and problems in hydrogen storage methods
journal, August 2005


Adsorption of chlorinated volatile organic compounds on hydrophobic faujasite: correlation between the thermodynamic and kinetic properties and the prediction of air cleaning
journal, December 1998

  • Clausse, Benoı̂t; Garrot, Bénédicte; Cornier, Cédric
  • Microporous and Mesoporous Materials, Vol. 25, Issue 1-3
  • DOI: 10.1016/S1387-1811(98)00202-9

Natural zeolites as effective adsorbents in water and wastewater treatment
journal, January 2010


Separation of Cesium from Nuclear Waste Solutions with Hexacyanoferrate(Ii)S and Ammonium Phosphomolybdate
journal, April 1987


Adsorption Separation of Low Concentrations of CO 2 and NO 2 by Synthetic Zeolites
journal, November 1998

  • Wang, Zheng-Ming; Arai, Tsuyoshi; Kumagai, Mikio
  • Energy & Fuels, Vol. 12, Issue 6
  • DOI: 10.1021/ef980109g

Adsorption of sulfur dioxide on natural clinoptilolite chemically modified with salt solutions
journal, August 2009


Nuclear waste forms for actinides
journal, March 1999


Application of natural zeolites in environmental remediation: A short review
journal, October 2011


Sulphate incorporation and glass formation in phosphate systems for nuclear and toxic waste immobilization
journal, July 2008


Hydrogen adsorption study on mixed oxides using the density functional theory
journal, April 2013

  • Salam, M. Abdus; Sufian, Suriati; Lwin, Ye
  • Journal of Physics and Chemistry of Solids, Vol. 74, Issue 4
  • DOI: 10.1016/j.jpcs.2012.12.004

Utilization of industrial waste products as adsorbents for the removal of dyes
journal, July 2003


Modeling and Simulation of the Polymeric Nanocapsule Formation Process
journal, January 2009


Adsorption characterisation of different volatile organic compounds over alumina, zeolites and activated carbon using inverse gas chromatography
journal, September 2004


Adsorption of Th(IV) onto Al-pillared rectorite: Effect of pH, ionic strength, temperature, soil humic acid and fulvic acid
journal, February 2008


Hydrogen adsorption in zeolites A, X, Y and RHO
journal, August 2003


Glassy Wasteforms for Nuclear Waste Immobilization
journal, November 2010

  • Ojovan, Michael I.; Lee, William E.
  • Metallurgical and Materials Transactions A, Vol. 42, Issue 4
  • DOI: 10.1007/s11661-010-0525-7

Separation of Cesium and Strontium from Acidic Radioactive Waste Simulants Using a Microporous Tungstate/Polyacrylonitrile (PAN) Composite Adsorbent
journal, July 2005

  • Griffith, Christopher S.; Luca, Vittorio; Šebesta, Ferdinand
  • Separation Science and Technology, Vol. 40, Issue 9
  • DOI: 10.1081/SS-200064561

Adsorbents for Dioxins:  A New Technique for Sorbent Screening for Low-Volatile Organics
journal, July 1999

  • Yang, Ralph T.; Long, Richard Q.; Padin, Joel
  • Industrial & Engineering Chemistry Research, Vol. 38, Issue 7
  • DOI: 10.1021/ie990170o

CO2 separation and landfill biogas upgrading: A comparison of 4A and 13X zeolite adsorbents
journal, January 2011


Application of natural zeolites in the purification and separation of gases
journal, July 2003


Cryoadsorption of hydrogen on divalent cation-exchanged X-zeolites
journal, July 2009


Rethinking High-Level Waste Disposal: Separate Disposal of High-Heat Radionuclides ( 90 Sr and 137 Cs)
journal, August 2000


Structure directed reversible adsorption of organic dye on mesoporous silica in aqueous solution
journal, December 2006


Computer simulations of adsorption and diffusion for binary mixtures of methane and hydrogen in titanosilicates
journal, July 2004

  • Mitchell, Martha C.; Gallo, Marco; Nenoff, Tina M.
  • The Journal of Chemical Physics, Vol. 121, Issue 4
  • DOI: 10.1063/1.1766019

The Adsorption of SO 2 by Zeolites Synthesized from Fly Ash
journal, May 1999

  • Srinivasan, Anand; Grutzeck, Michael W.
  • Environmental Science & Technology, Vol. 33, Issue 9
  • DOI: 10.1021/es9802091

Layered metal sulfides: Exceptionally selective agents for radioactive strontium removal
journal, March 2008

  • Manos, M. J.; Ding, N.; Kanatzidis, M. G.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 10
  • DOI: 10.1073/pnas.0711528105

Cesium sorption by clinoptilolite-rich tuffs in batch and fixed-bed systems
journal, August 2010


Evaluation of inorganic adsorbents for the removal of problematic textile dyes and pesticides
journal, July 1997

  • Lambert, S. D.; Graham, N. J. D.; Sollars, C. J.
  • Water Science and Technology, Vol. 36, Issue 2-3
  • DOI: 10.2166/wst.1997.0512

    Works referencing / citing this record:

    A new paradigm of ultrathin 2D nanomaterial adsorbents in aqueous media: graphene and GO, MoS 2 , MXenes, and 2D MOFs
    journal, January 2019

    • Zhao, Pin; Jian, Meipeng; Zhang, Qi
    • Journal of Materials Chemistry A, Vol. 7, Issue 28
    • DOI: 10.1039/c9ta02935d

    Membrane adsorber containing a new Sm( iii )–organic framework for dye removal
    journal, January 2019

    • Lee, Li-Wei; Pao, Szu-Ying; Pathak, Abhishek
    • Environmental Science: Nano, Vol. 6, Issue 4
    • DOI: 10.1039/c9en00018f

    Membrane adsorber containing a new Sm( iii )–organic framework for dye removal
    journal, January 2019

    • Lee, Li-Wei; Pao, Szu-Ying; Pathak, Abhishek
    • Environmental Science: Nano, Vol. 6, Issue 4
    • DOI: 10.1039/c9en00018f

    A new paradigm of ultrathin 2D nanomaterial adsorbents in aqueous media: graphene and GO, MoS 2 , MXenes, and 2D MOFs
    journal, January 2019

    • Zhao, Pin; Jian, Meipeng; Zhang, Qi
    • Journal of Materials Chemistry A, Vol. 7, Issue 28
    • DOI: 10.1039/c9ta02935d