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Title: Activation, Deactivation and Reversibility in a Series of Homogeneous Iridium Dehydrogenation Catalysts

Authors:
 [1];  [1]
  1. Yale Chemistry Department, 225 Prospect St New Haven, CT 06520-8107
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1374669
Grant/Contract Number:  
FG02-84ER13297; SC0001298
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Israel Journal of Chemistry
Additional Journal Information:
Journal Name: Israel Journal of Chemistry Journal Volume: 57 Journal Issue: 10-11; Journal ID: ISSN 0021-2148
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Israel
Language:
English

Citation Formats

Sharninghausen, Liam S., and Crabtree, Robert H. Activation, Deactivation and Reversibility in a Series of Homogeneous Iridium Dehydrogenation Catalysts. Israel: N. p., 2017. Web. doi:10.1002/ijch.201700048.
Sharninghausen, Liam S., & Crabtree, Robert H. Activation, Deactivation and Reversibility in a Series of Homogeneous Iridium Dehydrogenation Catalysts. Israel. doi:10.1002/ijch.201700048.
Sharninghausen, Liam S., and Crabtree, Robert H. Thu . "Activation, Deactivation and Reversibility in a Series of Homogeneous Iridium Dehydrogenation Catalysts". Israel. doi:10.1002/ijch.201700048.
@article{osti_1374669,
title = {Activation, Deactivation and Reversibility in a Series of Homogeneous Iridium Dehydrogenation Catalysts},
author = {Sharninghausen, Liam S. and Crabtree, Robert H.},
abstractNote = {},
doi = {10.1002/ijch.201700048},
journal = {Israel Journal of Chemistry},
number = 10-11,
volume = 57,
place = {Israel},
year = {2017},
month = {8}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/ijch.201700048

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Cited by: 2 works
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Works referenced in this record:

Oxidative Synthesis of Amides and Pyrroles via Dehydrogenative Alcohol Oxidation by Ruthenium Diphosphine Diamine Complexes
journal, August 2011

  • Schley, Nathan D.; Dobereiner, Graham E.; Crabtree, Robert H.
  • Organometallics, Vol. 30, Issue 15
  • DOI: 10.1021/om2004755

Organic Synthesis Involving Iridium-Catalyzed Oxidation
journal, March 2011


Pincer-Type Complexes for Catalytic (De)Hydrogenation and Transfer (De)Hydrogenation Reactions: Recent Progress
journal, July 2015

  • Werkmeister, Svenja; Neumann, Jacob; Junge, Kathrin
  • Chemistry - A European Journal, Vol. 21, Issue 35
  • DOI: 10.1002/chem.201500937

Ruthenium-Catalyzed N -Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology
journal, February 2009

  • Hamid, M. Haniti S. A.; Allen, C. Liana; Lamb, Gareth W.
  • Journal of the American Chemical Society, Vol. 131, Issue 5
  • DOI: 10.1021/ja807323a

Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation
journal, January 2015

  • Yang, Qin; Wang, Qingfu; Yu, Zhengkun
  • Chemical Society Reviews, Vol. 44, Issue 8
  • DOI: 10.1039/C4CS00496E

Mechanism of Homogeneous Iridium-Catalyzed Alkylation of Amines with Alcohols from a DFT Study
journal, June 2008

  • Balcells, David; Nova, Ainara; Clot, Eric
  • Organometallics, Vol. 27, Issue 11
  • DOI: 10.1021/om800134d

A homogeneous transition metal complex for clean hydrogen production from methanol–water mixtures
journal, March 2013

  • Rodríguez-Lugo, Rafael E.; Trincado, Mónica; Vogt, Matthias
  • Nature Chemistry, Vol. 5, Issue 4
  • DOI: 10.1038/nchem.1595

The Iridium-Catalyzed Synthesis of Symmetrically and Unsymmetrically Alkylated Diamines under Mild Reaction Conditions
journal, March 2012

  • Michlik, Stefan; Hille, Toni; Kempe, Rhett
  • Advanced Synthesis & Catalysis, Vol. 354, Issue 5
  • DOI: 10.1002/adsc.201100554

Stereoselective Hydrogenation of Aromatic Alkynes Using Water, Triethylsilane, or Methanol, Mediated and Catalyzed by Ni(0) Complexes
journal, January 2009

  • Barrios-Francisco, Rigoberto; García, Juventino J.
  • Inorganic Chemistry, Vol. 48, Issue 1
  • DOI: 10.1021/ic801823x

Efficient transfer hydrogenation of alkynes and alkenes with methanol catalysed by hydrido(methoxo)iridium(III) complexes
journal, January 1999

  • Tani, Kazuhide; Iseki, Aika; Yamagata, Tsuneaki
  • Chemical Communications, Issue 18
  • DOI: 10.1039/a905765j

Facile N-Alkylation of Anilines with Alcohols Over Raney Nickle Under Microwave Irradiation
journal, January 1996


The Uses of Crystal Growth in Gels and other Diffusing-Reacting Systems
journal, January 1991


Selective Hydrogen Production from Methanol with a Defined Iron Pincer Catalyst under Mild Conditions
journal, December 2013

  • Alberico, Elisabetta; Sponholz, Peter; Cordes, Christoph
  • Angewandte Chemie International Edition, Vol. 52, Issue 52
  • DOI: 10.1002/anie.201307224

Hydrogen-Transfer Catalysis with Cp*Ir III Complexes: The Influence of the Ancillary Ligands
journal, December 2013

  • Hintermair, Ulrich; Campos, Jesús; Brewster, Timothy P.
  • ACS Catalysis, Vol. 4, Issue 1
  • DOI: 10.1021/cs400834q

Transition metal catalysed reactions of alcohols using borrowing hydrogen methodology
journal, January 2009

  • Nixon, Tracy D.; Whittlesey, Michael K.; Williams, Jonathan M. J.
  • Dalton Trans., Issue 5
  • DOI: 10.1039/B813383B

A Carbene-Rich but Carbonyl-Poor [Ir 6 (IMe) 8 (CO) 2 H 14 ] 2+ Polyhydride Cluster as a Deactivation Product from Catalytic Glycerol Dehydrogenation
journal, September 2014

  • Campos, Jesús; Sharninghausen, Liam S.; Crabtree, Robert H.
  • Angewandte Chemie International Edition, Vol. 53, Issue 47
  • DOI: 10.1002/anie.201407997

Methanol Dehydrogenation by Iridium N-Heterocyclic Carbene Complexes
journal, January 2015

  • Campos, Jesús; Sharninghausen, Liam S.; Manas, Michael G.
  • Inorganic Chemistry, Vol. 54, Issue 11
  • DOI: 10.1021/ic502521c

Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure
journal, November 2014


A Prolific Catalyst for Selective Conversion of Neat Glycerol to Lactic Acid
journal, February 2016


Transition-Metal-Catalyzed Hydrogen-Transfer Annulations: Access to Heterocyclic Scaffolds
journal, August 2015

  • Nandakumar, Avanashiappan; Midya, Siba Prasad; Landge, Vinod Gokulkrishna
  • Angewandte Chemie International Edition, Vol. 54, Issue 38
  • DOI: 10.1002/anie.201503247

Resolving Heterogeneity Problems and Impurity Artifacts in Operationally Homogeneous Transition Metal Catalysts
journal, October 2011


Towards a methanol economy based on homogeneous catalysis: methanol to H 2 and CO 2 to methanol
journal, January 2015

  • Alberico, E.; Nielsen, M.
  • Chemical Communications, Vol. 51, Issue 31
  • DOI: 10.1039/C4CC09471A

Liquid Organic Hydrogen Carriers as an efficient vector for the transport and storage of renewable energy
journal, December 2012

  • Teichmann, Daniel; Arlt, Wolfgang; Wasserscheid, Peter
  • International Journal of Hydrogen Energy, Vol. 37, Issue 23
  • DOI: 10.1016/j.ijhydene.2012.08.066

Beyond Oil and Gas: The Methanol Economy
journal, April 2005


Molecular catalysts for hydrogen production from alcohols
journal, January 2014

  • Trincado, Monica; Banerjee, Dipshikha; Grützmacher, Hansjörg
  • Energy Environ. Sci., Vol. 7, Issue 8
  • DOI: 10.1039/C4EE00389F

Solvent-induced reductive elimination of pentamethylcyclopentadiene from a (pentamethylcyclopentadienyl)metal hydride
journal, August 1993


PNP pincer osmium polyhydrides for catalytic dehydrogenation of primary alcohols
journal, January 2011

  • Bertoli, Marcello; Choualeb, Aldjia; Gusev, Dmitry G.
  • Dalton Transactions, Vol. 40, Issue 35
  • DOI: 10.1039/c1dt10342c

Gel-assisted crystallization of [Ir 4 (IMe) 7 (CO)H 10 ] 2+ and [Ir 4 (IMe) 8 H 9 ] 3+ clusters derived from catalytic glycerol dehydrogenation
journal, January 2015

  • Sharninghausen, Liam S.; Mercado, Brandon Q.; Crabtree, Robert H.
  • Dalton Transactions, Vol. 44, Issue 42
  • DOI: 10.1039/C5DT03302K

Selective catalytic oxidation of sugar alcohols to lactic acid
journal, January 2015

  • Manas, Michael G.; Campos, Jesús; Sharninghausen, Liam S.
  • Green Chemistry, Vol. 17, Issue 1
  • DOI: 10.1039/C4GC01694G

Selective conversion of glycerol to lactic acid with iron pincer precatalysts
journal, January 2015

  • Sharninghausen, Liam S.; Mercado, Brandon Q.; Crabtree, Robert H.
  • Chemical Communications, Vol. 51, Issue 90
  • DOI: 10.1039/C5CC06857F

Catalyst Activation by Loss of Cyclopentadienyl Ligands in Hydrogen Transfer Catalysis with Cp*Ir III Complexes
journal, January 2014

  • Campos, Jesús; Hintermair, Ulrich; Brewster, Timothy P.
  • ACS Catalysis, Vol. 4, Issue 3
  • DOI: 10.1021/cs401138f

Borrowing Hydrogen in the Activation of Alcohols
journal, July 2007

  • Hamid, Malai Haniti S. A.; Slatford, Paul A.; Williams, Jonathan M. J.
  • Advanced Synthesis & Catalysis, Vol. 349, Issue 10
  • DOI: 10.1002/adsc.200600638

Synthesis and Characterization of Hydrotris(pyrazolyl)borate Dihydrogen/Hydride Complexes of Rhodium and Iridium
journal, November 1997

  • Oldham, Warren J.; Hinkle, Amber S.; Heinekey, D. M.
  • Journal of the American Chemical Society, Vol. 119, Issue 45
  • DOI: 10.1021/ja971627t

The organometallic chemistry of alkanes
journal, August 1985


Liquid organic and inorganic chemical hydrides for high-capacity hydrogen storage
journal, January 2015

  • Zhu, Qi-Long; Xu, Qiang
  • Energy & Environmental Science, Vol. 8, Issue 2
  • DOI: 10.1039/C4EE03690E

Catalytic interconversion between hydrogen and formic acid at ambient temperature and pressure
journal, January 2012

  • Maenaka, Yuta; Suenobu, Tomoyoshi; Fukuzumi, Shunichi
  • Energy & Environmental Science, Vol. 5, Issue 6
  • DOI: 10.1039/c2ee03315a

Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis
journal, July 2013


Hydrogen Autotransfer in the N -Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles
journal, November 2009

  • Guillena, Gabriela; Ramón, Diego J.; Yus, Miguel
  • Chemical Reviews, Vol. 110, Issue 3
  • DOI: 10.1021/cr9002159

Ruthenium-catalyzed hydrogen generation from glycerol and selective synthesis of lactic acid
journal, January 2015

  • Li, Yang; Nielsen, Martin; Li, Bin
  • Green Chemistry, Vol. 17, Issue 1
  • DOI: 10.1039/C4GC01707B

Crystal growth in gels: Principle and applications
journal, July 1988


Reductive elimination reaction of rhenium complexes trans-(η5-C5Me5)Re(CO)2(chloroaryl)Cl
journal, May 2006


Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry
journal, June 2012

  • Ayoub, Muhammad; Abdullah, Ahmad Zuhairi
  • Renewable and Sustainable Energy Reviews, Vol. 16, Issue 5
  • DOI: 10.1016/j.rser.2012.01.054

Efficient selective and atom economic catalytic conversion of glycerol to lactic acid
journal, October 2014

  • Sharninghausen, Liam S.; Campos, Jesús; Manas, Michael G.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6084

Thermocatalytic formation of molecular hydrogen and cyclo-octene from cyclo-octane by rhodium complexes
journal, January 1990

  • Fujii, Takahiro; Saito, Yasukazu
  • Journal of the Chemical Society, Chemical Communications, Issue 10
  • DOI: 10.1039/c39900000757

Reversible Hydrogenation of Carbon Dioxide to Formic Acid and Methanol: Lewis Acid Enhancement of Base Metal Catalysts
journal, February 2017


The glycerin glut: Options for the value-added conversion of crude glycerol resulting from biodiesel production
journal, January 2007

  • Johnson, Duane T.; Taconi, Katherine A.
  • Environmental Progress, Vol. 26, Issue 4
  • DOI: 10.1002/ep.10225

Formic acid as a hydrogen storage material – development of homogeneous catalysts for selective hydrogen release
journal, January 2016

  • Mellmann, Dörthe; Sponholz, Peter; Junge, Henrik
  • Chemical Society Reviews, Vol. 45, Issue 14
  • DOI: 10.1039/C5CS00618J

Iridium catalyzed reversible dehydrogenation – Hydrogenation of quinoline derivatives under mild conditions
journal, September 2015


Oxyfunctionalization with Cp*Ir III (NHC)(Me)(Cl) with O 2 : Identification of a Rare Bimetallic Ir IV μ-Oxo Intermediate
journal, March 2015

  • Lehman, Matthew C.; Pahls, Dale R.; Meredith, Joseph M.
  • Journal of the American Chemical Society, Vol. 137, Issue 10
  • DOI: 10.1021/ja512905t

Low-temperature aqueous-phase methanol dehydrogenation to hydrogen and carbon dioxide
journal, February 2013

  • Nielsen, Martin; Alberico, Elisabetta; Baumann, Wolfgang
  • Nature, Vol. 495, Issue 7439
  • DOI: 10.1038/nature11891

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis
journal, February 2010

  • Dobereiner, Graham E.; Crabtree, Robert H.
  • Chemical Reviews, Vol. 110, Issue 2
  • DOI: 10.1021/cr900202j

Perfluorobenzyl Complexes of Cobalt and Rhodium. Unusual Coupling between Pentafluorophenyl and Pentamethylcyclopentadienyl Rings
journal, January 1996

  • Hughes, Russell P.; Lindner, Danielle C.; Rheingold, Arnold L.
  • Organometallics, Vol. 15, Issue 26
  • DOI: 10.1021/om9607255

Homogeneous Catalytic System for Reversible Dehydrogenation−Hydrogenation Reactions of Nitrogen Heterocycles with Reversible Interconversion of Catalytic Species
journal, June 2009

  • Yamaguchi, Ryohei; Ikeda, Chikako; Takahashi, Yoshinori
  • Journal of the American Chemical Society, Vol. 131, Issue 24
  • DOI: 10.1021/ja9022623

Amine-Free Reversible Hydrogen Storage in Formate Salts Catalyzed by Ruthenium Pincer Complex without pH Control or Solvent Change
journal, March 2015

  • Kothandaraman, Jotheeswari; Czaun, Miklos; Goeppert, Alain
  • ChemSusChem, Vol. 8, Issue 8
  • DOI: 10.1002/cssc.201403458

The Golden Age of Transfer Hydrogenation
journal, June 2015


Towards Oil Independence Through Renewable Methanol Chemistry
journal, December 2012


Base-Free Methanol Dehydrogenation Using a Pincer-Supported Iron Compound and Lewis Acid Co-catalyst
journal, March 2015

  • Bielinski, Elizabeth A.; Förster, Moritz; Zhang, Yuanyuan
  • ACS Catalysis, Vol. 5, Issue 4
  • DOI: 10.1021/acscatal.5b00137

Hydrogen storage in liquid organic heterocycles
journal, January 2008

  • Crabtree, Robert H.
  • Energy & Environmental Science, Vol. 1, Issue 1
  • DOI: 10.1039/b805644g

Recent Advances in α - Alkylation Reactions using Alcohols with Hydrogen Borrowing Methodologies
journal, October 2014


Poly(ethylene) oxide for small-molecule crystal growth in gelled organic solvents
journal, January 2011

  • Choquesillo-Lazarte, Duane; García-Ruiz, Juan Manuel
  • Journal of Applied Crystallography, Vol. 44, Issue 1
  • DOI: 10.1107/S0021889810054725

Nickel-Catalyzed Alkylation and Transfer Hydrogenation of α,β-Unsaturated Enones with Methanol
journal, January 2012

  • Castellanos-Blanco, Nahury; Flores-Alamo, Marcos; García, Juventino J.
  • Organometallics, Vol. 31, Issue 2
  • DOI: 10.1021/om2010222

Selective N-monoalkylation of anilines catalyzed by a cationic ruthenium(II) compound
journal, May 2007