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Title: A Mixed-Valent Uranium Phosphonate Framework Containing UIV, UV, and UVI

Journal Article · · Chemistry - A European Journal
 [1];  [1];  [2];  [3];  [4];  [2];  [3];  [1];  [1];  [1];  [5];  [1]
  1. School for Radiological and interdisciplinary Sciences (RAD-X), Soochow University, 199 Renai Road Suzhou 215123 China, Collaborative Innovation Center of Radiation Medicine, Jiangsu Higher Education Institutions, 199 Renai Road Suzhou 215123 China
  2. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093 China
  3. Shanghai Institute of Applied Physics and, Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, 201800 Shanghai P. R. China
  4. Department of Chemistry, National Central University, Jhongli 320 Taiwan
  5. Department of Chemistry and Biochemistry, Florida State University, 95 Chieftain Way Tallahassee Florida 32306 USA

Not Available

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
SC0010677; SC0010677
OSTI ID:
1374668
Alternate ID(s):
OSTI ID: 22601310
Journal Information:
Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 34 Vol. 22; ISSN 0947-6539
Publisher:
ChemPubSoc EuropeCopyright Statement
Country of Publication:
Germany
Language:
English

References (54)

Mixed-Valence Uranium(V,VI) and Uranyl Oxyhydroxides Synthesized under High-Temperature, High-Pressure Hydrothermal Conditions: Na 5 [U 5 O 16 (OH) 2 ] and Na 5 [U 5 O 17 (OH)] journal August 2013
Pentavalent uranyl complexes journal August 2009
Pentavalent Uranium Oxide via Reduction of [UO 2 ] 2+ Under Hydrothermal Reaction Conditions journal November 2008
Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates journal November 2010
Uranium(VI) Adopts a Tetraoxido Core journal September 2009
Spectral studies of oxouranium(V) species journal May 1974
Magnetic Exchange Coupling in Chloride-Bridged 5f−3d Heterometallic Complexes Generated via Insertion into a Uranium(IV) Dimethylpyrazolate Dimer journal September 2007
(UO 2 ) 2 [UO 4 (trz) 2 ](OH) 2 : A U(VI) Coordination Intermediate between a Tetraoxido Core and a Uranyl Ion with Cation–Cation Interactions journal June 2012
Three-Dimensional MOF-Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U 6 O 8 ) journal January 2013
Synthesis and Structure of a Stable Pentavalent-Uranyl Coordination Polymer journal June 2006
Neptunium Diverges Sharply from Uranium and Plutonium in Crystalline Borate Matrixes: Insights into the Complex Behavior of the Early Actinides Relevant to Nuclear Waste Storage journal January 2010
Synthesis of Imido Analogs of the Uranyl Ion journal December 2005
Cs 3 UGe 7 O 18 : A Pentavalent Uranium Germanate Containing Four- and Six-Coordinate Germanium journal March 2012
High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of a Salt-Inclusion Mixed-Valence Uranium(V,VI) Silicate: [Na 9 F 2 ][(U V O 2 )(U VI O 2 ) 2 (Si 2 O 7 ) 2 ] journal May 2013
In Situ Hydrothermal Reduction of Neptunium(VI) as a Route to Neptunium(IV) Phosphonates journal December 2007
Bond-valence parameters for solids journal April 1991
Wyartite; crystallographic evidence for the first pentavalent-uranium mineral journal September 1999
Neptunium Diverges Sharply from Uranium and Plutonium in Crystalline Borate Matrixes: Insights into the Complex Behavior of the Early Actinides Relevant to Nuclear Waste Storage journal February 2010
A new chiral uranyl phosphonate framework consisting of achiral building units generated from ionothermal reaction: structure and spectroscopy characterizations journal January 2015
XPS determination of uranium oxidation states: XPS determination of uranium oxidation states journal October 2011
A cationic 24-MC-8 manganese cluster with ring metals possessing three oxidation states [Mn II 4 Mn III 6 Mn IV 24 -O) 23 -O) 43 -OH) 43 -OCH 3 ) 2 (pko) 12 ](OH)(ClO 4 ) 3 journal January 2003
K(UO)Si 2 O 6 :  A Pentavalent−Uranium Silicate journal September 2005
THE CRYSTAL STRUCTURE OF DEHYDRATED WYARTITE, Ca (CO3) [U5+ (U6+O2)2 O4 (OH)] (H2O)3 journal December 2006
Infrared spectroscopy of Sc + (H 2 O) and Sc 2+ (H 2 O) via argon complex predissociation: The charge dependence of cation hydration journal January 2011
Reduction and selective oxo group silylation of the uranyl dication journal January 2008
Further Evidence for the Stabilization of U(V) within a Tetraoxo Core journal May 2014
Polynuclear Cation−Cation Complexes of Pentavalent Uranyl: Relating Stability and Magnetic Properties to Structure journal December 2008
Long-term storage of spent nuclear fuel journal February 2015
[Na7UIVO2(UVO)2(UV/VIO2)2Si4O16]: A Mixed-Valence Uranium Silicate journal May 2010
Synthesis of Divalent Europium Borate via in Situ Reductive Techniques journal June 2013
Probing the Influence of Phosphonate Bonding Modes to Uranium(VI) on Structural Topology and Stability: A Complementary Experimental and Computational Investigation journal March 2015
Chemistry of uranium (V) journal October 1969
Structural Chemistry of Transuranium Phosphonates book January 2011
Electrolytic preparation, redox titration and stability of pentavalent state of uranyl tetraketonate in dimethyl sulfoxide journal February 2006
Strongly coupled binuclear uranium–oxo complexes from uranyl oxo rearrangement and reductive silylation journal February 2012
Mixed-Valent Uranium(IV,VI) Diphosphonate: Synthesis, Structure, and Spectroscopy journal March 2012
Paramagnetic resonance study of single crystals of UF6Li, UF6Na and UF6Cs journal September 1968
Pentavalent uranium chemistry—synthetic pursuit of a rare oxidation state journal January 2009
Mica Surfaces Stabilize Pentavalent Uranium journal May 2005
Cs 2 K(UO) 2 Si 4 O 12 : A Mixed-Valence Uranium(IV,V) Silicate journal October 2009
[Na7UIVO2(UVO)2(UV/VIO2)2Si4O16]: A Mixed-Valence Uranium Silicate journal May 2010
Electronic Structure and Bonding in Actinyl Ions and their Analogs journal May 2007
Self-Assembly of a 3d-5f Trinuclear Single-Molecule Magnet from a Pentavalent Uranyl Complex journal October 2014
Resonance Paramagnetique Dans Les Fluorures Complexes D'Uranium (V) De Type UF6M journal January 1967
Self-Assembly of a 3d-5f Trinuclear Single-Molecule Magnet from a Pentavalent Uranyl Complex journal October 2014
Electron paramagnetic resonance and optical studies of pentavalent uranium journal July 1973
Crystal Growth, Structural Characterization, and Magnetic Properties of New Uranium(IV) Containing Mixed Metal Oxalates: Na 2 U 2 M(C 2 O 4 ) 6 (H 2 O) 4 (M = Mn 2+ , Fe 2+ , Co 2+ , and Zn 2+ ) journal January 2013
Uranium and manganese assembled in a wheel-shaped nanoscale single-molecule magnet with high spin-reversal barrier journal November 2012
K 3 (U 3 O 6 )(Si 2 O 7 ) and Rb 3 (U 3 O 6 )(Ge 2 O 7 ): A Pentavalent-Uranium Silicate and Germanate journal June 2008
Autoxidation of Uranium(V). Catalysis and Inhibition by Copper Ions journal March 1995
Structural and spectroscopic characterization of two new layered uranyl(VI) p-xylenediphosphonate compounds synthesized via ionothermal method journal August 2015
Covalency effects on the ligand field splittings of octahedral 5f7 compounds journal March 1974
Structural chemistry of uranium phosphonates journal November 2015
Bioreduction of Uranium:  Environmental Implications of a Pentavalent Intermediate journal August 2005