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Title: Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. UCSD-CNRS Joint Research Chemistry Laboratory, UMI 3555, Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla CA 92093-0358 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1374470
Grant/Contract Number:  
SC0009376
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition) Journal Volume: 56 Journal Issue: 34; Journal ID: ISSN 1433-7851
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Melaimi, Mohand, Jazzar, Rodolphe, Soleilhavoup, Michèle, and Bertrand, Guy. Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments. Germany: N. p., 2017. Web. doi:10.1002/anie.201702148.
Melaimi, Mohand, Jazzar, Rodolphe, Soleilhavoup, Michèle, & Bertrand, Guy. Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments. Germany. doi:10.1002/anie.201702148.
Melaimi, Mohand, Jazzar, Rodolphe, Soleilhavoup, Michèle, and Bertrand, Guy. Mon . "Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments". Germany. doi:10.1002/anie.201702148.
@article{osti_1374470,
title = {Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments},
author = {Melaimi, Mohand and Jazzar, Rodolphe and Soleilhavoup, Michèle and Bertrand, Guy},
abstractNote = {},
doi = {10.1002/anie.201702148},
journal = {Angewandte Chemie (International Edition)},
number = 34,
volume = 56,
place = {Germany},
year = {2017},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/anie.201702148

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Cited by: 108 works
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(Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents
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A Stable N-Heterocyclic Carbene with a Diboron Backbone
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An Isolable and Monomeric Phosphorus Radical That Is Resonance-Stabilized by the Vanadium(IV/V) Redox Couple
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Bonding and Reactivity of a μ-Hydrido Dicopper Cation
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The Synthesis of B 2 (SIDip) 2 and its Reactivity Between the Diboracumulenic and Diborynic Extremes
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A Stable Neutral Radical in the Coordination Sphere of Aluminum
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Stable Radicals from Commonly Used Precursors Trichlorosilane and Diphenylchlorophosphine
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Synthesis and Thermal Properties of Novel NHC-Stabilized Cobalt Carbonyl Nitrosyl Complexes
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Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis
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A stable chiral diaminocyclopropenylidene
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C 4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication
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Synthesis of a Bent 2-Silaallene with a Perturbed Electronic Structure from a Cyclic Alkyl(amino) Carbene-Diiodosilylene
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Carbene Stabilization of Diarsenic: From Hypervalency to Allotropy
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Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters
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A Cyclic Diaminocarbene with a Pyramidalized Nitrogen Atom: A Stable N-Heterocyclic Carbene with Enhanced Electrophilicity
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A Triatomic Silicon(0) Cluster Stabilized by a Cyclic Alkyl(amino) Carbene
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A Two-Coordinate Cyclic (Alkyl)(amino)silylene: Balancing Thermal Stability and Reactivity
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Isolation of a Neutral Boron-Containing Radical Stabilized by a Cyclic (Alkyl)(Amino)Carbene
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(CAAC)CuX-catalyzed hydroboration of terminal alkynes with pinacolborane directed by the X-ligand
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A Rigid Cyclic (Alkyl)(amino)carbene Ligand Leads to Isolation of Low-Coordinate Transition-Metal Complexes
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Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes
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Tuning Ground States of Bis(triarylamine) Dications: From a Closed-Shell Singlet to a Diradicaloid with an Excited Triplet State
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New Avenues in s-Block Chemistry: Beryllium(0) Complexes
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The first metal complexes of bis(diisopropylamino)carbene: synthesis, structure and ligand properties
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Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride
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Stable singlet carbenes as mimics for transition metal centers
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Low-Temperature N 2 Binding to Two-Coordinate L 2 Fe 0 Enables Reductive Trapping of L 2 FeN 2 and NH 3 Generation
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Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis
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