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Title: A Mononuclear Nonheme Iron(V)-Imido Complex

Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)Fe V(NTs)] . The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe—N bond length of 1.65(4) Å, and an Fe—N vibration at 817 cm –1. In conclusion, the reactivity of 1 was demonstrated in C—H bond functionalization and nitrene transfer reactions.
Authors:
 [1] ;  [2] ;  [3] ; ORCiD logo [2] ;  [3] ; ORCiD logo [3] ;  [3] ;  [3] ;  [4] ;  [4] ; ORCiD logo [5] ; ORCiD logo [6]
  1. Ewha Womans Univ., Seoul (Korea); Sookmyung Women's Univ., Seoul (Korea)
  2. Stanford Univ., Stanford, CA (United States)
  3. Ewha Womans Univ., Seoul (Korea)
  4. Univ. of Hyogo, Hyogo (Japan)
  5. Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
  6. Ewha Womans Univ., Seoul (Korea); Chinese Academy of Sciences, Lanzhou (China)
Publication Date:
Grant/Contract Number:
AC02-76SF00515; 1-1603-2054; NRF-2010-00353; NRF-2012R1A3A2048842; NRF-2017R1C1B2002037; 15H00960; GM40392
Type:
Accepted Manuscript
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 139; Journal Issue: 26; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Research Org:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1374342