Effects of coating solvent and thermal treatment on transport and morphological characteristics of PDMS / T orlon composite hollow fiber membrane

Rownaghi, Ali A.; Bhandari, Dhaval; Burgess, Steven K.; Mikkilineni, Dharmik S.

doi:10.1002/app.45418

Title: Effects of coating solvent and thermal treatment on transport and morphological characteristics of PDMS / T orlon composite hollow fiber membrane

Journal Article · 23 June 2017 · Journal of Applied Polymer Science

DOI: https://doi.org/10.1002/app.45418 · OSTI ID:1374091

^[1]; Bhandari, Dhaval ^[2]; Burgess, Steven K. ^[3]; Mikkilineni, Dharmik S. ^[3]

Department of Chemical and Biochemical Engineering Missouri University of Science and Technology 1401 N Pine Street Rolla Missouri 65409, School of Chemical and Biomolecular Engineering Georgia Institute of Technology 311 Ferst Drive NW Atlanta Georgia 30332
General Electric Global Research Center 1 Research Circle Niskayuna New York 12309
School of Chemical and Biomolecular Engineering Georgia Institute of Technology 311 Ferst Drive NW Atlanta Georgia 30332

ABSTRACT A new approach for formation of the polydimethylsiloxane (PDMS) layer on Torlon polyamide‐imide hollow fiber (PAI‐HF) support has been developed by directly after fiber spinning without the need to undergo the final conventional solvent exchange and drying step, thereby saving postspinning processing steps. The produced PDMS/PAI‐HF composite membranes were found to have high CO ₂ permeance (i.e., 1100 GPU) and exhibited good CO ₂ /N ₂ selectivities of 8–10 which is close to 90% of that of a PDMS dense film. The effects of coating solution, rewetting and crosslinking temperature on the PAI‐HF morphological features, that is, gas transport, skin thickness, skin integrity, and substructure resistance are investigated. The rewetting and thermal treatment of the PAI‐HF caused the densification of the skin layer and reduced the pore sizes on the top layer. In addition, the potential use of the PAI‐HF support with polymers that are insoluble in hexane is also considered. Effects of water, methanol, and hexane exposure of PAI‐HF to these solvents are considered. This evaluation calls attention to issues that must be addressed in any eventual use of the PAI‐HF with water‐soluble or methanol‐soluble selective layer polymers, rather than simple hexane‐soluble polymers such as PDMS. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45418.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FE0007514

OSTI ID:: 1374091

Journal Information:: Journal of Applied Polymer Science, Journal Name: Journal of Applied Polymer Science Journal Issue: 42 Vol. 134; ISSN 0021-8995

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United States

Language:: English

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