A Spontaneous Structural Transition of {U24Pp12} Clusters Triggered by Alkali Counterion Replacement in Dilute Solution

Gao, Yunyi; Dembowski, Mateusz; Szymanowski, Jennifer E. S.; Yin, Wenbin; Chuang, Steven S. C.; Burns, Peter C.; Liu, Tianbo

doi:10.1002/chem.201701972

Title: A Spontaneous Structural Transition of {U₂₄Pp₁₂} Clusters Triggered by Alkali Counterion Replacement in Dilute Solution

Authors:

Gao, Yunyi ^[1]; Dembowski, Mateusz ^[2]; Szymanowski, Jennifer E. S. ^[3]; Yin, Wenbin ^[1]; Chuang, Steven S. C. ^[1]; Burns, Peter C. ^[4];

^[1]

Department of Polymer Science, University of Akron, Akron OH 44325 USA
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame IN 46556 USA
Department of Civil and Environmental Engineering and Earth Science, University of Notre Dame, Notre Dame IN 46556 USA
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame IN 46556 USA, Department of Civil and Environmental Engineering and Earth Science, University of Notre Dame, Notre Dame IN 46556 USA

Publication Date:: Tue May 30 00:00:00 EDT 2017

Sponsoring Org.:: USDOE

OSTI Identifier:: 1373975

Grant/Contract Number:: SC0001089

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Chemistry - A European Journal

Additional Journal Information:: Journal Name: Chemistry - A European Journal Journal Volume: 23 Journal Issue: 33; Journal ID: ISSN 0947-6539

Publisher:: ChemPubSoc Europe

Country of Publication:: Germany

Language:: English

Citation Formats


                    Gao, Yunyi, Dembowski, Mateusz, Szymanowski, Jennifer E. S., Yin, Wenbin, Chuang, Steven S. C., Burns, Peter C., and Liu, Tianbo. A Spontaneous Structural Transition of {U24Pp12} Clusters Triggered by Alkali Counterion Replacement in Dilute Solution.  Germany: N. p., 2017. 
Web.  doi:10.1002/chem.201701972.

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                    Gao, Yunyi, Dembowski, Mateusz, Szymanowski, Jennifer E. S., Yin, Wenbin, Chuang, Steven S. C., Burns, Peter C., & Liu, Tianbo. A Spontaneous Structural Transition of {U24Pp12} Clusters Triggered by Alkali Counterion Replacement in Dilute Solution.  Germany.  https://doi.org/10.1002/chem.201701972

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                    Gao, Yunyi, Dembowski, Mateusz, Szymanowski, Jennifer E. S., Yin, Wenbin, Chuang, Steven S. C., Burns, Peter C., and Liu, Tianbo. Tue .  
"A Spontaneous Structural Transition of {U24Pp12} Clusters Triggered by Alkali Counterion Replacement in Dilute Solution".  Germany.  https://doi.org/10.1002/chem.201701972.

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@article{osti_1373975,

  title        = {A Spontaneous Structural Transition of {U24Pp12} Clusters Triggered by Alkali Counterion Replacement in Dilute Solution},

  author       = {Gao, Yunyi and Dembowski, Mateusz and Szymanowski, Jennifer E. S. and Yin, Wenbin and Chuang, Steven S. C. and Burns, Peter C. and Liu, Tianbo},

  abstractNote = {},

  doi          = {10.1002/chem.201701972},

  journal      = {Chemistry - A European Journal},

  number       = 33,

  volume       = 23,

  place        = {Germany},

  year         = {Tue May 30 00:00:00 EDT 2017},

  month        = {Tue May 30 00:00:00 EDT 2017}

}

Copy to clipboard

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Title: A Spontaneous Structural Transition of {U24Pp12} Clusters Triggered by Alkali Counterion Replacement in Dilute Solution

Citation Formats

Equilibria between α and β Isomers of Keggin Heteropolytungstates journal, May 1999

Selective Monovalent Cation Association and Exchange around Keplerate Polyoxometalate Macroanions in Dilute Aqueous Solutions journal, June 2010

Investigating the Transformations of Polyoxoanions Using Mass Spectrometry and Molecular Dynamics journal, July 2016

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Thermal Responsive Ion Selectivity of Uranyl Peroxide Nanocages: An Inorganic Mimic of K + Ion Channels journal, April 2016

Solution 31 P NMR Study of the Acid-Catalyzed Formation of a Highly Charged {U 24 Pp 12 } Nanocluster, [(UO 2 ) 24 (O 2 ) 24 (P 2 O 7 ) 12 ] 48– , and Its Structural Characterization in the Solid State Using Single-Crystal Neutron Diffraction journal, June 2016

Spontaner Aufbau einer organisch-anorganischen Nukleinsäure-Z-DNA-Doppelhelix-Struktur journal, November 2016

DFT Study on the Five Isomers of PW 12 O 40 3 - : Relative Stabilization upon Reduction journal, November 2004

Exploring the Effect of Surface Functionality on the Self-Assembly of Polyoxopalladate Macroions journal, May 2015

Nuclear Fuel in a Reactor Accident journal, March 2012

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Trapping Cations in Specific Positions in Tuneable“Artificial Cell” Channels: New Nanochemistry Perspectives journal, October 2003

Cation behavior at an artificial cell interface: binding distinguished by ion hydration energetics and size journal, January 2008

Polyoxometalate macroion induced phase and morphology instability of lipid membrane journal, January 2013

Biomimetic Approach for Ion Channels Based on Surfactant Encapsulated Spherical Porous Metal-Oxide Capsules journal, August 2015

Selective Permeability of Uranyl Peroxide Nanocages to Different Alkali Ions: Influences from Surface Pores and Hydration Shells journal, November 2015

Thermal Responsive Ion Selectivity of Uranyl Peroxide Nanocages: An Inorganic Mimic of K + Ion Channels journal, April 2016

Dynamics of a Nanometer-Sized Uranyl Cluster in Solution journal, June 2013

Relative Energies of α and β Isomers of Keggin Dodecatungstogallate journal, February 2006

Flexible Pores of a Metal Oxide-Based Capsule Permit Entry of Comparatively Larger Organic Guests journal, May 2009

Uranyl peroxide enhanced nuclear fuel corrosion in seawater journal, January 2012

Experimental measurements of U60 nanocluster stability in aqueous solution journal, May 2015

Spontaneous Assembly of an Organic-Inorganic Nucleic Acid Z-DNA Double-Helix Structure journal, November 2016

Spontaneous Self-Assembly of γ-Cyclodextrins in Dilute Solutions with Tunable Sizes and Thermodynamic Stability journal, May 2015

Cation-Directed Structure Changes in Polyoxometalate Chemistry. Equilibria between Isomers of Bis(9-tungstophosphatodioxouranate(VI)) Complexes journal, September 1999

New fundamental type of inorganic complex: hybrid between heteropoly and conventional coordination complexes. Possibilities for geometrical isomerisms in 11-, 12-, 17-, and 18-heteropoly derivatives journal, June 1970

Structure of a heteropoly blue. The four-electron reduced .beta.-12-molybdophosphate anion journal, March 1985

Dynamics of a Nanometer-Sized Uranyl Cluster in Solution journal, June 2013

Trapping Cations in Specific Positions in Tuneable“Artificial Cell” Channels: New Nanochemistry Perspectives journal, October 2003

Title: A Spontaneous Structural Transition of {U₂₄Pp₁₂} Clusters Triggered by Alkali Counterion Replacement in Dilute Solution

Equilibria between α and β Isomers of Keggin Heteropolytungstates
journal, May 1999

Selective Monovalent Cation Association and Exchange around Keplerate Polyoxometalate Macroanions in Dilute Aqueous Solutions
journal, June 2010

Investigating the Transformations of Polyoxoanions Using Mass Spectrometry and Molecular Dynamics
journal, July 2016

An overview of selected current approaches to the characterization of aqueous inorganic clusters
journal, January 2015

Solution behaviors and self-assembly of polyoxometalates as models of macroions and amphiphilic polyoxometalate–organic hybrids as novel surfactants
journal, January 2012

Thermal Responsive Ion Selectivity of Uranyl Peroxide Nanocages: An Inorganic Mimic of K ⁺ Ion Channels
journal, April 2016

Solution ³¹ P NMR Study of the Acid-Catalyzed Formation of a Highly Charged {U ₂₄ Pp ₁₂ } Nanocluster, [(UO ₂ ) ₂₄ (O ₂ ) ₂₄ (P ₂ O ₇ ) ₁₂ ] ^48– , and Its Structural Characterization in the Solid State Using Single-Crystal Neutron Diffraction
journal, June 2016

Spontaner Aufbau einer organisch-anorganischen Nukleinsäure-Z-DNA-Doppelhelix-Struktur
journal, November 2016

DFT Study on the Five Isomers of PW ₁₂ O ₄₀ ³ ^- : Relative Stabilization upon Reduction
journal, November 2004

Exploring the Effect of Surface Functionality on the Self-Assembly of Polyoxopalladate Macroions
journal, May 2015

Nuclear Fuel in a Reactor Accident
journal, March 2012

Cu-based Polyoxometalate Catalyst for Efficient Catalytic Hydrogen Evolution
journal, June 2016

Trapping Cations in Specific Positions in Tuneable“Artificial Cell” Channels: New Nanochemistry Perspectives
journal, October 2003

Cation behavior at an artificial cell interface: binding distinguished by ion hydration energetics and size
journal, January 2008

Polyoxometalate macroion induced phase and morphology instability of lipid membrane
journal, January 2013

Biomimetic Approach for Ion Channels Based on Surfactant Encapsulated Spherical Porous Metal-Oxide Capsules
journal, August 2015

Selective Permeability of Uranyl Peroxide Nanocages to Different Alkali Ions: Influences from Surface Pores and Hydration Shells
journal, November 2015

Thermal Responsive Ion Selectivity of Uranyl Peroxide Nanocages: An Inorganic Mimic of K ⁺ Ion Channels
journal, April 2016

Dynamics of a Nanometer-Sized Uranyl Cluster in Solution
journal, June 2013

Relative Energies of α and β Isomers of Keggin Dodecatungstogallate
journal, February 2006

Flexible Pores of a Metal Oxide-Based Capsule Permit Entry of Comparatively Larger Organic Guests
journal, May 2009

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journal, January 2012

Experimental measurements of U60 nanocluster stability in aqueous solution
journal, May 2015

Spontaneous Assembly of an Organic-Inorganic Nucleic Acid Z-DNA Double-Helix Structure
journal, November 2016

Spontaneous Self-Assembly of γ-Cyclodextrins in Dilute Solutions with Tunable Sizes and Thermodynamic Stability
journal, May 2015

Cation-Directed Structure Changes in Polyoxometalate Chemistry. Equilibria between Isomers of Bis(9-tungstophosphatodioxouranate(VI)) Complexes
journal, September 1999

New fundamental type of inorganic complex: hybrid between heteropoly and conventional coordination complexes. Possibilities for geometrical isomerisms in 11-, 12-, 17-, and 18-heteropoly derivatives
journal, June 1970

Structure of a heteropoly blue. The four-electron reduced .beta.-12-molybdophosphate anion
journal, March 1985

Dynamics of a Nanometer-Sized Uranyl Cluster in Solution
journal, June 2013

Trapping Cations in Specific Positions in Tuneable“Artificial Cell” Channels: New Nanochemistry Perspectives
journal, October 2003