Wellbore Cement Porosity Evolution in Response to Mineral Alteration during CO2 Flooding

Cheshire, Michael C.; Stack, Andrew G.; Carey, J. William; Anovitz, Lawrence M.; Prisk, Timothy R.; Ilavsky, Jan

doi:10.1021/acs.est.6b03290

Title: Wellbore Cement Porosity Evolution in Response to Mineral Alteration during CO₂ Flooding

Authors:

^[1]; Stack, Andrew G. ^[1];

^[2]; Anovitz, Lawrence M. ^[1]; Prisk, Timothy R. ^[1]; Ilavsky, Jan ^[3]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Tue Dec 13 00:00:00 EST 2016

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Argonne National Lab. (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Nanoscale Control of Geologic CO2 (NCGC)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Fossil Energy (FE)

OSTI Identifier:: 1338566

Alternate Identifier(s):: OSTI ID: 1373414; OSTI ID: 1407900

Report Number(s):: LA-UR-17-27502
Journal ID: ISSN 0013-936X; KC0307010; ERKCC67

Grant/Contract Number:: AC02-05CH11231; AC02-06CH11357; FE-371-14-FY16; AC52-06NA25396

Resource Type:: Accepted Manuscript

Journal Name:: Environmental Science and Technology

Additional Journal Information:: Journal Volume: 51; Journal Issue: 1; Journal ID: ISSN 0013-936X

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 54 ENVIRONMENTAL SCIENCES; 58 GEOSCIENCES; Earth Sciences; Energy Sciences

Citation Formats


                    Cheshire, Michael C., Stack, Andrew G., Carey, J. William, Anovitz, Lawrence M., Prisk, Timothy R., and Ilavsky, Jan. Wellbore Cement Porosity Evolution in Response to Mineral Alteration during CO2 Flooding.  United States: N. p., 2016. 
Web.  doi:10.1021/acs.est.6b03290.

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                    Cheshire, Michael C., Stack, Andrew G., Carey, J. William, Anovitz, Lawrence M., Prisk, Timothy R., & Ilavsky, Jan. Wellbore Cement Porosity Evolution in Response to Mineral Alteration during CO2 Flooding.  United States.  https://doi.org/10.1021/acs.est.6b03290

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                    Cheshire, Michael C., Stack, Andrew G., Carey, J. William, Anovitz, Lawrence M., Prisk, Timothy R., and Ilavsky, Jan. Tue .  
"Wellbore Cement Porosity Evolution in Response to Mineral Alteration during CO2 Flooding".  United States.  https://doi.org/10.1021/acs.est.6b03290.  https://www.osti.gov/servlets/purl/1338566.

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@article{osti_1338566,

  title        = {Wellbore Cement Porosity Evolution in Response to Mineral Alteration during CO2 Flooding},

  author       = {Cheshire, Michael C. and Stack, Andrew G. and Carey, J. William and Anovitz, Lawrence M. and Prisk, Timothy R. and Ilavsky, Jan},

  abstractNote = {},

  doi          = {10.1021/acs.est.6b03290},

  journal      = {Environmental Science and Technology},

  number       = 1,

  volume       = 51,

  place        = {United States},

  year         = {Tue Dec 13 00:00:00 EST 2016},

  month        = {Tue Dec 13 00:00:00 EST 2016}

}

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https://doi.org/10.1021/acs.est.6b03290

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Title: Wellbore Cement Porosity Evolution in Response to Mineral Alteration during CO2 Flooding

Citation Formats

Role and impact of CO2–rock interactions during CO2 storage in sedimentary rocks journal, January 2010

Pore-Size-Dependent Calcium Carbonate Precipitation Controlled by Surface Chemistry journal, May 2014

Precipitation in Pores: A Geochemical Frontier journal, January 2015

Numerical simulation of salt precipitation in the fractures of a CO2-enhanced geothermal system journal, October 2012

Mechanisms for mechanical trapping of geologically sequestered carbon dioxide journal, March 2015

Mineralization of carbon dioxide sequestered in volcanogenic sandstone reservoir rocks journal, October 2013

Site characterisation of a basin-scale CO2 geological storage system: Gippsland Basin, southeast Australia journal, August 2007

Pore Scale Processes Associated with Subsurface CO2 Injection and Sequestration journal, January 2013

Permeability Description by Characteristic Length, Tortuosity, Constriction and Porosity journal, April 2014

Spatial characterization of the location of potentially leaky wells penetrating a deep saline aquifer in a mature sedimentary basin journal, June 2004

Geochemistry of Wellbore Integrity in CO2 Sequestration: Portland Cement-Steel-Brine-CO2 Interactions journal, January 2013

Evaporite Caprock Integrity: An Experimental Study of Reactive Mineralogy and Pore-Scale Heterogeneity during Brine-CO 2 Exposure journal, August 2012

Observational evidence confirms modelling of the long-term integrity of CO2-reservoir caprocks journal, July 2016

Case study of geochemical reactions at the Nagaoka CO2 injection site, Japan journal, July 2008

Petrophysical and geochemical properties of Columbia River flood basalt: Implications for carbon sequestration journal, November 2012

Mineral sequestration of carbon dioxide in basalt: A pre-injection overview of the CarbFix project journal, May 2010

Rapid carbon mineralization for permanent disposal of anthropogenic carbon dioxide emissions journal, June 2016

Analysis and performance of oil well cement with 30 years of CO2 exposure from the SACROC Unit, West Texas, USA journal, April 2007

Reactive transport modelling of CO 2 storage in saline aquifers to elucidate fundamental processes, trapping mechanisms and sequestration partitioning journal, January 2004

Ultra-small-angle X-ray scattering at the Advanced Photon Source journal, April 2009

Irena : tool suite for modeling and analysis of small-angle scattering journal, February 2009

Multi-scale characterization of pore evolution in a combustion metamorphic complex, Hatrurim basin, Israel: Combining (ultra) small-angle neutron scattering and image analysis journal, November 2013

Diagenetic changes in macro- to nano-scale porosity in the St. Peter Sandstone: An (ultra) small angle neutron scattering and backscattered electron imaging analysis journal, February 2013

Approximations Leading to a Unified Exponential/Power-Law Approach to Small-Angle Scattering journal, December 1995

Characterization and Analysis of Porosity and Pore Structures journal, January 2015

Degradation of Well Cement by CO 2 under Geologic Sequestration Conditions journal, July 2007

Rate of CO 2 Attack on Hydrated Class H Well Cement under Geologic Sequestration Conditions journal, August 2008

CO 2 Reaction with Hydrated Class H Well Cement under Geologic Sequestration Conditions: Effects of Flyash Admixtures journal, May 2009

Review: Role of chemistry, mechanics, and transport on well integrity in CO2 storage environments journal, June 2016

Reactive transport of CO2-saturated water in a cement fracture: Application to wellbore leakage during geologic CO2 storage journal, January 2016

Characterization of the Mechanisms Controlling the Permeability Changes of Fractured Cements Flowed Through by CO 2 -Rich Brine journal, September 2013

Experimental calibration of a numerical model describing the alteration of cement/caprock interfaces by carbonated brine journal, March 2014

Mechanical and hydraulic coupling in cement–caprock interfaces exposed to carbonated brine journal, June 2014

Model for the Developing Microstructure in Portland Cement Pastes journal, December 1994

Pore structure characterization of North American shale gas reservoirs using USANS/SANS, gas adsorption, and mercury intrusion journal, January 2013

The effect of w/c ratio and curing temperature on the permeability of hardened cement paste journal, July 1981

Permeability and pore structure of OPC paste journal, February 2001

Heterogeneous porosity distribution in Portland cement exposed to CO2-rich fluids journal, August 2008

Scattering from fractals journal, April 1987

Small Angle Neutron Scattering Studies Of Pore And Gel Structures, Diffusivity, Permeability And Damage Effects journal, January 1988

A new approach to quantification of metamorphism using ultra-small and small angle neutron scattering journal, December 2009

Effect of quartz overgrowth precipitation on the multiscale porosity of sandstone: A (U)SANS and imaging analysis journal, June 2015

Effect of moisture on fractal dimension and specific surface of hardened cement paste by small-angle X-ray scattering journal, January 1994

The fractal arrangement of hydrated cement paste journal, January 1995

Influence of porosity on compressive and tensile strength of cement mortar journal, March 2013

Effects of the Storage of CO2 on Multiaxial Mechanical and Hydraulic Behaviors of Oil-Well Cement journal, June 2011

Chemical Reactions of Portland Cement with Aqueous CO 2 and Their Impacts on Cement’s Mechanical Properties under Geologic CO 2 Sequestration Conditions journal, May 2015

Effect of carbonation on the hydro-mechanical properties of Portland cements journal, December 2009

Defining the Brittle Failure Envelopes of Individual Reaction Zones Observed in CO 2 -Exposed Wellbore Cement journal, December 2015

Title: Wellbore Cement Porosity Evolution in Response to Mineral Alteration during CO₂ Flooding

Role and impact of CO2–rock interactions during CO2 storage in sedimentary rocks
journal, January 2010

Pore-Size-Dependent Calcium Carbonate Precipitation Controlled by Surface Chemistry
journal, May 2014

Precipitation in Pores: A Geochemical Frontier
journal, January 2015

Numerical simulation of salt precipitation in the fractures of a CO2-enhanced geothermal system
journal, October 2012

Mechanisms for mechanical trapping of geologically sequestered carbon dioxide
journal, March 2015

Mineralization of carbon dioxide sequestered in volcanogenic sandstone reservoir rocks
journal, October 2013

Site characterisation of a basin-scale CO2 geological storage system: Gippsland Basin, southeast Australia
journal, August 2007

Pore Scale Processes Associated with Subsurface CO2 Injection and Sequestration
journal, January 2013

Permeability Description by Characteristic Length, Tortuosity, Constriction and Porosity
journal, April 2014

Spatial characterization of the location of potentially leaky wells penetrating a deep saline aquifer in a mature sedimentary basin
journal, June 2004

Geochemistry of Wellbore Integrity in CO2 Sequestration: Portland Cement-Steel-Brine-CO2 Interactions
journal, January 2013

Evaporite Caprock Integrity: An Experimental Study of Reactive Mineralogy and Pore-Scale Heterogeneity during Brine-CO ₂ Exposure
journal, August 2012

Observational evidence confirms modelling of the long-term integrity of CO2-reservoir caprocks
journal, July 2016

Case study of geochemical reactions at the Nagaoka CO2 injection site, Japan
journal, July 2008

Petrophysical and geochemical properties of Columbia River flood basalt: Implications for carbon sequestration
journal, November 2012

Mineral sequestration of carbon dioxide in basalt: A pre-injection overview of the CarbFix project
journal, May 2010

Rapid carbon mineralization for permanent disposal of anthropogenic carbon dioxide emissions
journal, June 2016

Analysis and performance of oil well cement with 30 years of CO2 exposure from the SACROC Unit, West Texas, USA
journal, April 2007

Reactive transport modelling of CO ₂ storage in saline aquifers to elucidate fundamental processes, trapping mechanisms and sequestration partitioning
journal, January 2004

Ultra-small-angle X-ray scattering at the Advanced Photon Source
journal, April 2009

Irena : tool suite for modeling and analysis of small-angle scattering
journal, February 2009

Multi-scale characterization of pore evolution in a combustion metamorphic complex, Hatrurim basin, Israel: Combining (ultra) small-angle neutron scattering and image analysis
journal, November 2013

Diagenetic changes in macro- to nano-scale porosity in the St. Peter Sandstone: An (ultra) small angle neutron scattering and backscattered electron imaging analysis
journal, February 2013

Approximations Leading to a Unified Exponential/Power-Law Approach to Small-Angle Scattering
journal, December 1995

Characterization and Analysis of Porosity and Pore Structures
journal, January 2015

Degradation of Well Cement by CO ₂ under Geologic Sequestration Conditions
journal, July 2007

Rate of CO ₂ Attack on Hydrated Class H Well Cement under Geologic Sequestration Conditions
journal, August 2008

CO ₂ Reaction with Hydrated Class H Well Cement under Geologic Sequestration Conditions: Effects of Flyash Admixtures
journal, May 2009

Review: Role of chemistry, mechanics, and transport on well integrity in CO2 storage environments
journal, June 2016

Reactive transport of CO2-saturated water in a cement fracture: Application to wellbore leakage during geologic CO2 storage
journal, January 2016

Characterization of the Mechanisms Controlling the Permeability Changes of Fractured Cements Flowed Through by CO ₂ -Rich Brine
journal, September 2013

Experimental calibration of a numerical model describing the alteration of cement/caprock interfaces by carbonated brine
journal, March 2014

Mechanical and hydraulic coupling in cement–caprock interfaces exposed to carbonated brine
journal, June 2014

Model for the Developing Microstructure in Portland Cement Pastes
journal, December 1994

Pore structure characterization of North American shale gas reservoirs using USANS/SANS, gas adsorption, and mercury intrusion
journal, January 2013

The effect of w/c ratio and curing temperature on the permeability of hardened cement paste
journal, July 1981

Permeability and pore structure of OPC paste
journal, February 2001

Heterogeneous porosity distribution in Portland cement exposed to CO2-rich fluids
journal, August 2008

Scattering from fractals
journal, April 1987

Small Angle Neutron Scattering Studies Of Pore And Gel Structures, Diffusivity, Permeability And Damage Effects
journal, January 1988

A new approach to quantification of metamorphism using ultra-small and small angle neutron scattering
journal, December 2009

Effect of quartz overgrowth precipitation on the multiscale porosity of sandstone: A (U)SANS and imaging analysis
journal, June 2015

Effect of moisture on fractal dimension and specific surface of hardened cement paste by small-angle X-ray scattering
journal, January 1994

The fractal arrangement of hydrated cement paste
journal, January 1995

Influence of porosity on compressive and tensile strength of cement mortar
journal, March 2013

Effects of the Storage of CO2 on Multiaxial Mechanical and Hydraulic Behaviors of Oil-Well Cement
journal, June 2011

Chemical Reactions of Portland Cement with Aqueous CO ₂ and Their Impacts on Cement’s Mechanical Properties under Geologic CO ₂ Sequestration Conditions
journal, May 2015

Effect of carbonation on the hydro-mechanical properties of Portland cements
journal, December 2009

Defining the Brittle Failure Envelopes of Individual Reaction Zones Observed in CO ₂ -Exposed Wellbore Cement
journal, December 2015