Floating zone growth of α-Na0.90MnO2 single crystals
Abstract
Here, single crystal growth of α-NaxMnO2 (x=0.90) is reported via the floating zone technique. The conditions required for stable growth and intergrowth-free crystals are described along with the results of trials under alternate growth atmospheres. Chemical and structural characterizations of the resulting α-Na0.90MnO2 crystals are performed using ICP-AES NMR, XANES, XPS, and neutron diffraction measurements. As a layered transition metal oxide with large ionic mobility and strong correlation effects, α-NaxMnO2 is of interest to many communities, and the implications of large volume, high purity, single crystal growth are discussed.
- Authors:
-
- Boston College, Chestnut Hill, MA (United States); Univ. of California, Santa Barbara, CA (United States)
- Univ. of Cambridge, Cambridge (United Kingdom)
- National Institute of Standards and Technology, Gaithersburg, MD (United States)
- Univ. of California, Santa Barbara, CA (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- U.S. Army Research Laboratory, U.S. Army Research Office (ARO); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Scientific User Facilities Division; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)
- OSTI Identifier:
- 1372403
- Alternate Identifier(s):
- OSTI ID: 1396715
- Grant/Contract Number:
- AC02-06CH11357; AC02-05CH11231; 7057154
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Crystal Growth
- Additional Journal Information:
- Journal Volume: 459; Journal Issue: C; Journal ID: ISSN 0022-0248
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; A1 characterization; A2 floating zone technique; B1 manganites; A2 single crystal growth
Citation Formats
Dally, Rebecca, Clement, Raphaele J., Chisnell, Robin, Taylor, Stephanie, Butala, Megan M., Doan-Nguyen, Vicky V. T., Balasubramanian, Mahalingam, Lynn, Jeffrey W., Grey, Clare P., and Wilson, Stephen D. Floating zone growth of α-Na0.90MnO2 single crystals. United States: N. p., 2016.
Web. doi:10.1016/j.jcrysgro.2016.12.010.
Dally, Rebecca, Clement, Raphaele J., Chisnell, Robin, Taylor, Stephanie, Butala, Megan M., Doan-Nguyen, Vicky V. T., Balasubramanian, Mahalingam, Lynn, Jeffrey W., Grey, Clare P., & Wilson, Stephen D. Floating zone growth of α-Na0.90MnO2 single crystals. United States. https://doi.org/10.1016/j.jcrysgro.2016.12.010
Dally, Rebecca, Clement, Raphaele J., Chisnell, Robin, Taylor, Stephanie, Butala, Megan M., Doan-Nguyen, Vicky V. T., Balasubramanian, Mahalingam, Lynn, Jeffrey W., Grey, Clare P., and Wilson, Stephen D. Sat .
"Floating zone growth of α-Na0.90MnO2 single crystals". United States. https://doi.org/10.1016/j.jcrysgro.2016.12.010. https://www.osti.gov/servlets/purl/1372403.
@article{osti_1372403,
title = {Floating zone growth of α-Na0.90MnO2 single crystals},
author = {Dally, Rebecca and Clement, Raphaele J. and Chisnell, Robin and Taylor, Stephanie and Butala, Megan M. and Doan-Nguyen, Vicky V. T. and Balasubramanian, Mahalingam and Lynn, Jeffrey W. and Grey, Clare P. and Wilson, Stephen D.},
abstractNote = {Here, single crystal growth of α-NaxMnO2 (x=0.90) is reported via the floating zone technique. The conditions required for stable growth and intergrowth-free crystals are described along with the results of trials under alternate growth atmospheres. Chemical and structural characterizations of the resulting α-Na0.90MnO2 crystals are performed using ICP-AES NMR, XANES, XPS, and neutron diffraction measurements. As a layered transition metal oxide with large ionic mobility and strong correlation effects, α-NaxMnO2 is of interest to many communities, and the implications of large volume, high purity, single crystal growth are discussed.},
doi = {10.1016/j.jcrysgro.2016.12.010},
journal = {Journal of Crystal Growth},
number = C,
volume = 459,
place = {United States},
year = {Sat Dec 03 00:00:00 EST 2016},
month = {Sat Dec 03 00:00:00 EST 2016}
}
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Works referencing / citing this record:
Amplitude mode in the planar triangular antiferromagnet Na0.9MnO2
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