skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework

Abstract

A Keggin-type polyoxometalate (H3PW12O40) was incorporated into a mesoporous Zr-based MOF (NU-1000) via an impregnation method in aqueous media, resulting in the hybrid material, PW12@NU-1000. The POM@MOF composite was characterized by a suite of physical methods, indicating the retention of crystallinity and high porosity of the parent MOF. The hybrid material was also stable to leaching in aqueous media at varying pH. Lastly, the material was tested as a heterogeneous catalyst for the oxidation of 2-chloroethyl ethyl sulfide using hydrogen peroxide as the oxidant. PW12@NU-1000 was shown to have a higher catalytic activity than either of the individual constituents alone.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [2];  [2]; ORCiD logo [3];  [4];  [3]; ORCiD logo [1]; ORCiD logo [5]
  1. Northwestern Univ., Evanston, IL (United States)
  2. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
  4. Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Univ. of Washington, Seattle, WA (United States)
  5. Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
US Army Research Office (ARO); National Science Foundation (NSF); W.M. Keck Foundation; Inorganometallic Catalyst Design Center (ICDC); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Scientific User Facilities Division; Energy Frontier Research Center
OSTI Identifier:
1372079
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 29; Journal Issue: 12; Journal ID: ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; NU-1000; POM@MOF; catalysis; metal–organic frameworks; phosphotungstic acid; polyoxometalate; sulfide oxidation

Citation Formats

Buru, Cassandra T., Li, Peng, Mehdi, B. Layla, Dohnalkova, Alice, Platero-Prats, Ana E., Browning, Nigel D., Chapman, Karena W., Hupp, Joseph T., and Farha, Omar K. Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework. United States: N. p., 2017. Web. doi:10.1021/acs.chemmater.7b00750.
Buru, Cassandra T., Li, Peng, Mehdi, B. Layla, Dohnalkova, Alice, Platero-Prats, Ana E., Browning, Nigel D., Chapman, Karena W., Hupp, Joseph T., & Farha, Omar K. Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework. United States. doi:10.1021/acs.chemmater.7b00750.
Buru, Cassandra T., Li, Peng, Mehdi, B. Layla, Dohnalkova, Alice, Platero-Prats, Ana E., Browning, Nigel D., Chapman, Karena W., Hupp, Joseph T., and Farha, Omar K. Wed . "Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework". United States. doi:10.1021/acs.chemmater.7b00750. https://www.osti.gov/servlets/purl/1372079.
@article{osti_1372079,
title = {Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework},
author = {Buru, Cassandra T. and Li, Peng and Mehdi, B. Layla and Dohnalkova, Alice and Platero-Prats, Ana E. and Browning, Nigel D. and Chapman, Karena W. and Hupp, Joseph T. and Farha, Omar K.},
abstractNote = {A Keggin-type polyoxometalate (H3PW12O40) was incorporated into a mesoporous Zr-based MOF (NU-1000) via an impregnation method in aqueous media, resulting in the hybrid material, PW12@NU-1000. The POM@MOF composite was characterized by a suite of physical methods, indicating the retention of crystallinity and high porosity of the parent MOF. The hybrid material was also stable to leaching in aqueous media at varying pH. Lastly, the material was tested as a heterogeneous catalyst for the oxidation of 2-chloroethyl ethyl sulfide using hydrogen peroxide as the oxidant. PW12@NU-1000 was shown to have a higher catalytic activity than either of the individual constituents alone.},
doi = {10.1021/acs.chemmater.7b00750},
journal = {Chemistry of Materials},
number = 12,
volume = 29,
place = {United States},
year = {2017},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 23 works
Citation information provided by
Web of Science

Save / Share:

Works referencing / citing this record:

Construction of unprecedented pillar-layered metal organic frameworks via a dual-ligand strategy for dye degradation
journal, January 2018

  • Tang, Yu-Huan; Wang, Fei; Zhang, Jian
  • Dalton Transactions, Vol. 47, Issue 12
  • DOI: 10.1039/c7dt04484d

Revisiting the structural homogeneity of NU-1000, a Zr-based metal–organic framework
journal, January 2018

  • Islamoglu, Timur; Otake, Ken-ichi; Li, Peng
  • CrystEngComm, Vol. 20, Issue 39
  • DOI: 10.1039/c8ce00455b

Heptamolybdate: a highly active sulfide oxygenation catalyst
journal, January 2018

  • Porter, Ashlin G.; Hu, Hanfeng; Liu, Xuemei
  • Dalton Transactions, Vol. 47, Issue 34
  • DOI: 10.1039/c8dt00583d

Versatile catalysts constructed from hybrid polyoxomolybdates for simultaneously detoxifying sulfur mustard and organophosphate simulants
journal, January 2019

  • Hou, Yujiao; An, Haiyan; Chang, Shenzhen
  • Catalysis Science & Technology, Vol. 9, Issue 10
  • DOI: 10.1039/c9cy00094a

Synthesis, Crystal Structure, and Electrochemical Properties of One Polyoxometalate-Based Silver(I) Compound with Keggin-Type [PW12O40]3− Anions
journal, June 2018

  • Yang, H. X.; Zhu, W. J.; Jin, L. Y.
  • Russian Journal of Coordination Chemistry, Vol. 44, Issue 7
  • DOI: 10.1134/s1070328418070035

Construction of unprecedented pillar-layered metal organic frameworks via a dual-ligand strategy for dye degradation
journal, January 2018

  • Tang, Yu-Huan; Wang, Fei; Zhang, Jian
  • Dalton Transactions, Vol. 47, Issue 12
  • DOI: 10.1039/c7dt04484d

Revisiting the structural homogeneity of NU-1000, a Zr-based metal–organic framework
journal, January 2018

  • Islamoglu, Timur; Otake, Ken-ichi; Li, Peng
  • CrystEngComm, Vol. 20, Issue 39
  • DOI: 10.1039/c8ce00455b

Heptamolybdate: a highly active sulfide oxygenation catalyst
journal, January 2018

  • Porter, Ashlin G.; Hu, Hanfeng; Liu, Xuemei
  • Dalton Transactions, Vol. 47, Issue 34
  • DOI: 10.1039/c8dt00583d

Versatile catalysts constructed from hybrid polyoxomolybdates for simultaneously detoxifying sulfur mustard and organophosphate simulants
journal, January 2019

  • Hou, Yujiao; An, Haiyan; Chang, Shenzhen
  • Catalysis Science & Technology, Vol. 9, Issue 10
  • DOI: 10.1039/c9cy00094a

Synthesis, Crystal Structure, and Electrochemical Properties of One Polyoxometalate-Based Silver(I) Compound with Keggin-Type [PW12O40]3− Anions
journal, June 2018

  • Yang, H. X.; Zhu, W. J.; Jin, L. Y.
  • Russian Journal of Coordination Chemistry, Vol. 44, Issue 7
  • DOI: 10.1134/s1070328418070035