Using Scanning-Probe Block Copolymer Lithography and Electron Microscopy To Track Shape Evolution in Multimetallic Nanoclusters

Liu, Guoliang; Zhang, Chuan; Wu, Jinsong; Mirkin, Chad A.

doi:10.1021/acsnano.5b05191

Title: Using Scanning-Probe Block Copolymer Lithography and Electron Microscopy To Track Shape Evolution in Multimetallic Nanoclusters

Abstract

Here we describe a general method for synthesizing multimetallic core–shell nanoclusters on surfaces. By patterning seeds at predesignated locations using scanning-probe block copolymer lithography, we can track shape evolution in nanoclusters and elucidate their growth pathways using electron microscopy. The growth of core–shell nanostructures on surface-bound seeds is a highly anisotropic process and often results in multimetallic anisotropic nanostructures. Lastly, the shell grows at specific edge and corner sites of the patterned seeds and propagates predominately from the top hemisphere of the seeds.

Authors:

Liu, Guoliang ^[1]; Zhang, Chuan ^[1]; Wu, Jinsong ^[1]; Mirkin, Chad A. ^[1]

Northwestern Univ., Evanston, IL (United States)

Publication Date:: Thu Nov 12 00:00:00 EST 2015

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Center for Bio-Inspired Energy Science (CBES)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1371160

Grant/Contract Number:: SC0000989; FA9550-12-1-0280

Resource Type:: Accepted Manuscript

Journal Name:: ACS Nano

Additional Journal Information:: Journal Volume: 9; Journal Issue: 12; Related Information: CBES partners with Northwestern University (lead); Harvard University; New York University; Pennsylvania State University; University of Michigan; University of Pittsburgh; Journal ID: ISSN 1936-0851

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalysis (homogeneous); solar (photovoltaic); bio-inspired; charge transport; mesostructured materials; materials and chemistry by design; synthesis (novel materials); synthesis (self-assembly); scanning-probe block copolymer lithography; core−shell nanoparticle; shape evolution; multimetallic nanocluster

Citation Formats


                    Liu, Guoliang, Zhang, Chuan, Wu, Jinsong, and Mirkin, Chad A. Using Scanning-Probe Block Copolymer Lithography and Electron Microscopy To Track Shape Evolution in Multimetallic Nanoclusters.  United States: N. p., 2015. 
Web.  doi:10.1021/acsnano.5b05191.

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                    Liu, Guoliang, Zhang, Chuan, Wu, Jinsong, & Mirkin, Chad A. Using Scanning-Probe Block Copolymer Lithography and Electron Microscopy To Track Shape Evolution in Multimetallic Nanoclusters.  United States.  https://doi.org/10.1021/acsnano.5b05191

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                    Liu, Guoliang, Zhang, Chuan, Wu, Jinsong, and Mirkin, Chad A. Thu .  
"Using Scanning-Probe Block Copolymer Lithography and Electron Microscopy To Track Shape Evolution in Multimetallic Nanoclusters".  United States.  https://doi.org/10.1021/acsnano.5b05191.  https://www.osti.gov/servlets/purl/1371160.

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@article{osti_1371160,

  title        = {Using Scanning-Probe Block Copolymer Lithography and Electron Microscopy To Track Shape Evolution in Multimetallic Nanoclusters},

  author       = {Liu, Guoliang and Zhang, Chuan and Wu, Jinsong and Mirkin, Chad A.},

  abstractNote = {Here we describe a general method for synthesizing multimetallic core–shell nanoclusters on surfaces. By patterning seeds at predesignated locations using scanning-probe block copolymer lithography, we can track shape evolution in nanoclusters and elucidate their growth pathways using electron microscopy. The growth of core–shell nanostructures on surface-bound seeds is a highly anisotropic process and often results in multimetallic anisotropic nanostructures. Lastly, the shell grows at specific edge and corner sites of the patterned seeds and propagates predominately from the top hemisphere of the seeds.},

  doi          = {10.1021/acsnano.5b05191},

  journal      = {ACS Nano},

  number       = 12,

  volume       = 9,

  place        = {United States},

  year         = {Thu Nov 12 00:00:00 EST 2015},

  month        = {Thu Nov 12 00:00:00 EST 2015}

}

Copy to clipboard

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Works referencing / citing this record:

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Title: Using Scanning-Probe Block Copolymer Lithography and Electron Microscopy To Track Shape Evolution in Multimetallic Nanoclusters

Abstract

Citation Formats

Scanning probe block copolymer lithography journal, November 2010

Delineating the pathways for the site-directed synthesis of individual nanoparticles on surfaces journal, December 2012

"Dip-Pen" Nanolithography journal, January 1999

Applications of dip-pen nanolithography journal, February 2007

Nanotechnology with Soft Materials journal, April 2003

Block Copolymer Lithography: Merging “Bottom-Up” with “Top-Down” Processes journal, December 2005

The role of viscosity on polymer ink transport in dip-pen nanolithography journal, January 2013

Tip-Directed Synthesis of Multimetallic Nanoparticles journal, July 2015

Nanoreactors for Studying Single Nanoparticle Coarsening journal, December 2011

Controlled synthesis of dendritic Au@Pt core–shell nanomaterials for use as an effective fuel cell electrocatalyst journal, December 2008

Epitaxial Growth of Heterogeneous Metal Nanocrystals: From Gold Nano-octahedra to Palladium and Silver Nanocubes journal, June 2008

Plasmon-Driven Synthesis of Triangular Core–Shell Nanoprisms from Gold Seeds journal, November 2007

Stepwise Evolution of Spherical Seeds into 20-Fold Twinned Icosahedra journal, August 2012

Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics? journal, December 2008

Shape-Controlled Synthesis of Gold and Silver Nanoparticles journal, December 2002

Shape Control of Colloidal Metal Nanocrystals journal, March 2008

Shape control in gold nanoparticle synthesis journal, January 2008

Thermodynamics versus Kinetics in Nanosynthesis journal, December 2014

Bimetallic nanoparticles—novel materials for chemical and physical applications journal, January 1998

Hollow Au@Pd and Au@Pt core–shell nanoparticles as electrocatalysts for ethanol oxidation reactions journal, January 2012

Water-dispersable hybrid Au–Pd nanoparticles as catalysts in ethanol oxidation, aqueous phase Suzuki–Miyaura and Heck reactions journal, January 2012

Synthesis and Electrocatalytic Activity of Au−Pd Alloy Nanodendrites for Ethanol Oxidation journal, April 2010

Tailoring Au-core Pd-shell Pt-cluster nanoparticles for enhanced electrocatalytic activity journal, January 2011

Electrode-surface coordination chemistry: ligand substitution and competitive coordination of halides at well-defined Pd(100) and Pd(111) single crystals journal, February 1997

Copper Can Still Be Epitaxially Deposited on Palladium Nanocrystals To Generate Core–Shell Nanocubes Despite Their Large Lattice Mismatch journal, February 2012

In Situ Liquid Cell Electron Microscopy of the Solution Growth of Au–Pd Core–Shell Nanostructures journal, May 2013

Kinetically Controlled Nucleation of Silver on Surfactant-Free Gold Seeds journal, October 2014

Preparation and Characterization of Au Colloid Monolayers journal, February 1995

Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts journal, August 2012

Electron Microscopy of Solid Catalysts—Transforming from a Challenge to a Toolbox journal, March 2015

Synthesis and applications of silver nanoparticles journal, July 2010

Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications journal, December 2011

Approaches to Single-Nanoparticle Catalysis journal, April 2014

Combinatorial Heterogeneous Catalysis—A New Path in an Old Field journal, January 2001

Experimental Strategies for Combinatorial and High-Throughput Materials Development journal, March 2001

Combinatorial Materials Science and Catalysis journal, September 1999

Gold Nanoparticles in Biology: Beyond Toxicity to Cellular Imaging journal, December 2008

Nanostructures in Biodiagnostics journal, April 2005

Integrated Nanoparticle-Biomolecule Hybrid Systems: Synthesis, Properties, and Applications journal, November 2004

Computer Visualization of Three-Dimensional Image Data Using IMOD journal, January 1996

Micropatterning and nanopatterning with polymeric materials for advanced biointerface‐controlled systems journal, February 2019

Arrays of highly complex noble metal nanostructures using nanoimprint lithography in combination with liquid-phase epitaxy journal, January 2018

When lithography meets self-assembly: a review of recent advances in the directed assembly of complex metal nanostructures on planar and textured surfaces journal, June 2017

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Scanning probe block copolymer lithography
journal, November 2010

Delineating the pathways for the site-directed synthesis of individual nanoparticles on surfaces
journal, December 2012

"Dip-Pen" Nanolithography
journal, January 1999

Applications of dip-pen nanolithography
journal, February 2007

Nanotechnology with Soft Materials
journal, April 2003

Block Copolymer Lithography: Merging “Bottom-Up” with “Top-Down” Processes
journal, December 2005

The role of viscosity on polymer ink transport in dip-pen nanolithography
journal, January 2013

Tip-Directed Synthesis of Multimetallic Nanoparticles
journal, July 2015

Nanoreactors for Studying Single Nanoparticle Coarsening
journal, December 2011

Controlled synthesis of dendritic Au@Pt core–shell nanomaterials for use as an effective fuel cell electrocatalyst
journal, December 2008

Epitaxial Growth of Heterogeneous Metal Nanocrystals: From Gold Nano-octahedra to Palladium and Silver Nanocubes
journal, June 2008

Plasmon-Driven Synthesis of Triangular Core–Shell Nanoprisms from Gold Seeds
journal, November 2007

Stepwise Evolution of Spherical Seeds into 20-Fold Twinned Icosahedra
journal, August 2012

Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
journal, December 2008

Shape-Controlled Synthesis of Gold and Silver Nanoparticles
journal, December 2002

Shape Control of Colloidal Metal Nanocrystals
journal, March 2008

Shape control in gold nanoparticle synthesis
journal, January 2008

Thermodynamics versus Kinetics in Nanosynthesis
journal, December 2014

Bimetallic nanoparticles—novel materials for chemical and physical applications
journal, January 1998

Hollow Au@Pd and Au@Pt core–shell nanoparticles as electrocatalysts for ethanol oxidation reactions
journal, January 2012

Water-dispersable hybrid Au–Pd nanoparticles as catalysts in ethanol oxidation, aqueous phase Suzuki–Miyaura and Heck reactions
journal, January 2012

Synthesis and Electrocatalytic Activity of Au−Pd Alloy Nanodendrites for Ethanol Oxidation
journal, April 2010

Tailoring Au-core Pd-shell Pt-cluster nanoparticles for enhanced electrocatalytic activity
journal, January 2011

Electrode-surface coordination chemistry: ligand substitution and competitive coordination of halides at well-defined Pd(100) and Pd(111) single crystals
journal, February 1997

Copper Can Still Be Epitaxially Deposited on Palladium Nanocrystals To Generate Core–Shell Nanocubes Despite Their Large Lattice Mismatch
journal, February 2012

In Situ Liquid Cell Electron Microscopy of the Solution Growth of Au–Pd Core–Shell Nanostructures
journal, May 2013

Kinetically Controlled Nucleation of Silver on Surfactant-Free Gold Seeds
journal, October 2014

Preparation and Characterization of Au Colloid Monolayers
journal, February 1995

Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts
journal, August 2012

Electron Microscopy of Solid Catalysts—Transforming from a Challenge to a Toolbox
journal, March 2015

Synthesis and applications of silver nanoparticles
journal, July 2010

Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications
journal, December 2011

Approaches to Single-Nanoparticle Catalysis
journal, April 2014

Combinatorial Heterogeneous Catalysis—A New Path in an Old Field
journal, January 2001

Experimental Strategies for Combinatorial and High-Throughput Materials Development
journal, March 2001

Combinatorial Materials Science and Catalysis
journal, September 1999

Gold Nanoparticles in Biology: Beyond Toxicity to Cellular Imaging
journal, December 2008

Nanostructures in Biodiagnostics
journal, April 2005

Integrated Nanoparticle-Biomolecule Hybrid Systems: Synthesis, Properties, and Applications
journal, November 2004

Computer Visualization of Three-Dimensional Image Data Using IMOD
journal, January 1996

Micropatterning and nanopatterning with polymeric materials for advanced biointerface‐controlled systems
journal, February 2019

Arrays of highly complex noble metal nanostructures using nanoimprint lithography in combination with liquid-phase epitaxy
journal, January 2018

When lithography meets self-assembly: a review of recent advances in the directed assembly of complex metal nanostructures on planar and textured surfaces
journal, June 2017

Direct Observation of Early Stages of Growth of Multilayered DNA-Templated Au-Pd-Au Core-Shell Nanoparticles in Liquid Phase
journal, February 2019