Phase transformations in Ln2O3 materials irradiated with swift heavy ions

Tracy, Cameron L.; Lang, Maik; Zhang, Fuxiang; Trautmann, Christina; Ewing, Rodney C.

doi:10.1103/PhysRevB.92.174101

Title: Phase transformations in ${Ln}_{2} O_{3}$ materials irradiated with swift heavy ions

Journal Article · 02 November 2015 · Physical Review. B, Condensed Matter and Materials Physics

DOI: https://doi.org/10.1103/PhysRevB.92.174101 · OSTI ID:1370871

Tracy, Cameron L. ^[1]; Lang, Maik ^[2]; Zhang, Fuxiang ^[3]; Trautmann, Christina ^[4]; Ewing, Rodney C. ^[5]

Univ. of Michigan, Ann Arbor, MI (United States); Stanford Univ., CA (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Michigan, Ann Arbor, MI (United States); Yanshan Univ., Hebei (China)
GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany); Technische Univ. Darmstadt (Germany)
Stanford Univ., CA (United States)

Phase transformations induced in the cubic C-type lanthanide sesquioxides, Ln₂O₃ (Ln = Sm, Gd, Ho, Tm, and Lu), by dense electronic excitation are investigated. The structural modifications resulting from exposure to beams of 185 MeV Xe and 2246 MeV Au ions are characterized using synchrotron x-ray diffraction and Raman spectroscopy. The formation of a B-type polymorph, an X-type nonequilibrium phase, and an amorphous phase are observed. The specific phase formed and the transformation rate show dependence on the material composition, as well as the ion beam mass and energy. Atomistic mechanisms for these transformations are determined, indicating that formation of the B-type phase results from the production of anti-Frenkel defects and the aggregation of anion vacancies into planar clusters, whereas formation of the X-type and amorphous phases requires extensive displacement of both anions and cations. Here, the observed variations in phase behavior with changing lanthanide ionic radius and deposited electronic energy density are related to the energetics of these transformation mechanisms.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0001089

OSTI ID:: 1370871

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Journal Name: Physical Review. B, Condensed Matter and Materials Physics Journal Issue: 17 Vol. 92; ISSN 1098-0121; ISSN PRBMDO

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Journal Article · 2021 · Journal of Applied Physics · OSTI ID:1846449

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Comparison of the high-pressure behavior of the cerium oxides

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36 MATERIALS SCIENCE
materials and chemistry by design
nuclear (including radiation effects)
synthesis (novel materials)
synthesis (self-assembly)

Title: Phase transformations in Ln2O3 materials irradiated with swift heavy ions

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Title: Phase transformations in ${Ln}_{2} O_{3}$ materials irradiated with swift heavy ions