The Development of Pseudocapacitive Properties in Nanosized-MoO2
Abstract
Pseudocapacitive charge storage materials offer the opportunity to bridge the gap between high energy density battery materials and high power density electrical double layer capacitor materials through the rational design of transition metal oxide nanoscale architectures. The research reported in this paper describes the origins and development of pseudocapacitance in MoO2. Micron-size particles of MoO2 exhibit a reversible monoclinic to orthorhombic phase transition upon lithium insertion/deinsertion, however, this phase transformation is suppressed when using 15 nm nanocrystals of MoO2. The nanoscale MoO2 exhibits pseudocapacitive behavior and achieves substantially better energy storage kinetics than the corresponding bulk material. Such size-dependent electrochemical behavior is an essential feature of an extrinsic pseudocapacitor material. The high power capability of nanoscale MoO2 is improved further by synthesizing hybrid materials in which MoO2 nanoparticles are grown on reduced graphene oxide (RGO) scaffolds. Electrode architectures containing MoO2-RGO hybrid materials preserve the pseudocapacitance of MoO2 as lithium capacities of nearly 150 mAh g–1 are obtained at a rate of 50 C.
- Authors:
-
- Univ. of California, Los Angeles, CA (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Molecularly Engineered Energy Materials (MEEM)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1370243
- Grant/Contract Number:
- SC0001342; 0840531
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 162; Journal Issue: 5; Related Information: MEEM partners with University of California, Los Angeles (lead); University of California, Berkeley; Eastern Washington University; University of Kansas; National Renewable Energy Laboratory; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Kim, H. -S., Cook, J. B., Tolbert, S. H., and Dunn, B. The Development of Pseudocapacitive Properties in Nanosized-MoO2. United States: N. p., 2015.
Web. doi:10.1149/2.0141505jes.
Kim, H. -S., Cook, J. B., Tolbert, S. H., & Dunn, B. The Development of Pseudocapacitive Properties in Nanosized-MoO2. United States. https://doi.org/10.1149/2.0141505jes
Kim, H. -S., Cook, J. B., Tolbert, S. H., and Dunn, B. Tue .
"The Development of Pseudocapacitive Properties in Nanosized-MoO2". United States. https://doi.org/10.1149/2.0141505jes. https://www.osti.gov/servlets/purl/1370243.
@article{osti_1370243,
title = {The Development of Pseudocapacitive Properties in Nanosized-MoO2},
author = {Kim, H. -S. and Cook, J. B. and Tolbert, S. H. and Dunn, B.},
abstractNote = {Pseudocapacitive charge storage materials offer the opportunity to bridge the gap between high energy density battery materials and high power density electrical double layer capacitor materials through the rational design of transition metal oxide nanoscale architectures. The research reported in this paper describes the origins and development of pseudocapacitance in MoO2. Micron-size particles of MoO2 exhibit a reversible monoclinic to orthorhombic phase transition upon lithium insertion/deinsertion, however, this phase transformation is suppressed when using 15 nm nanocrystals of MoO2. The nanoscale MoO2 exhibits pseudocapacitive behavior and achieves substantially better energy storage kinetics than the corresponding bulk material. Such size-dependent electrochemical behavior is an essential feature of an extrinsic pseudocapacitor material. The high power capability of nanoscale MoO2 is improved further by synthesizing hybrid materials in which MoO2 nanoparticles are grown on reduced graphene oxide (RGO) scaffolds. Electrode architectures containing MoO2-RGO hybrid materials preserve the pseudocapacitance of MoO2 as lithium capacities of nearly 150 mAh g–1 are obtained at a rate of 50 C.},
doi = {10.1149/2.0141505jes},
journal = {Journal of the Electrochemical Society},
number = 5,
volume = 162,
place = {United States},
year = {Tue Feb 03 00:00:00 EST 2015},
month = {Tue Feb 03 00:00:00 EST 2015}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 148 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Kinetics and Mechanism of Molybdenum (VI) Oxide Reduction
journal, August 1995
- Słoczyński, Jerzy
- Journal of Solid State Chemistry, Vol. 118, Issue 1
Hydrothermal Dehydration for the “Green” Reduction of Exfoliated Graphene Oxide to Graphene and Demonstration of Tunable Optical Limiting Properties
journal, July 2009
- Zhou, Yong; Bao, Qiaoliang; Tang, Lena Ai Ling
- Chemistry of Materials, Vol. 21, Issue 13
Synthesis and Lithium Storage Mechanism of Ultrafine MoO 2 Nanorods
journal, December 2011
- Guo, Bingkun; Fang, Xiangpeng; Li, Bin
- Chemistry of Materials, Vol. 24, Issue 3
Thermoelectrochemically Activated MoO[sub 2] Powder Electrode for Lithium Secondary Batteries
journal, January 2009
- Ku, Jun H.; Jung, Yoon S.; Lee, Kyu T.
- Journal of The Electrochemical Society, Vol. 156, Issue 8
Raman Spectra of Graphite Oxide and Functionalized Graphene Sheets
journal, January 2008
- Kudin, Konstantin N.; Ozbas, Bulent; Schniepp, Hannes C.
- Nano Letters, Vol. 8, Issue 1
Pseudocapacitive oxide materials for high-rate electrochemical energy storage
journal, January 2014
- Augustyn, Veronica; Simon, Patrice; Dunn, Bruce
- Energy & Environmental Science, Vol. 7, Issue 5
A facile hydrothermal route to iron(III) oxide with conductive additives as composite anode for lithium ion batteries
journal, August 2014
- Chen, Gen; Rodriguez, Rodrigo; Fei, Ling
- Journal of Power Sources, Vol. 259
A simple reduction process to synthesize MoO2/C composites with cage-like structure for high-performance lithium-ion batteries
journal, January 2013
- Liu, Bing; Zhao, Xinyu; Tian, Yuan
- Physical Chemistry Chemical Physics, Vol. 15, Issue 22
Carbon/MoO 2 Composite Based on Porous Semi-Graphitized Nanorod Assemblies from In Situ Reaction of Tri-Block Polymers
journal, February 2007
- Ji, Xiulei; Herle, P. Subramanya; Rho, Youngho
- Chemistry of Materials, Vol. 19, Issue 3
Size Dependence of a First Order Solid-Solid Phase Transition: The Wurtzite to Rock Salt Transformation in CdSe Nanocrystals
journal, July 1994
- Tolbert, S. H.; Alivisatos, A. P.
- Science, Vol. 265, Issue 5170
Ordered Mesoporous Metallic MoO 2 Materials with Highly Reversible Lithium Storage Capacity
journal, December 2009
- Shi, Yifeng; Guo, Bingkun; Corr, Serena A.
- Nano Letters, Vol. 9, Issue 12
Structure and electrochemistry of LixMoO2
journal, March 1987
- Dahn, J.; Mckinnon, W.
- Solid State Ionics, Vol. 23, Issue 1-2
Enhancement of Redox Cycling Currents at Interdigitated Electrodes with Elevated Fingers
journal, January 2014
- Morita, Masao; Hayashi, Katsuyoshi; Horiuchi, Tsutomu
- Journal of The Electrochemical Society, Vol. 161, Issue 4
Synthesis and applications of molybdenum (IV) oxide
journal, September 2011
- Ellefson, Caleb A.; Marin-Flores, Oscar; Ha, Su
- Journal of Materials Science, Vol. 47, Issue 5
Materials for electrochemical capacitors
journal, November 2008
- Simon, Patrice; Gogotsi, Yury
- Nature Materials, Vol. 7, Issue 11
Behavior of Molybdenum Nitrides as Materials for Electrochemical Capacitors
journal, January 1998
- Liu, T. -C.
- Journal of The Electrochemical Society, Vol. 145, Issue 6
Self-Assembled Hierarchical MoO 2 /Graphene Nanoarchitectures and Their Application as a High-Performance Anode Material for Lithium-Ion Batteries
journal, August 2011
- Sun, Yongming; Hu, Xianluo; Luo, Wei
- ACS Nano, Vol. 5, Issue 9
Nanosize Effect on High-Rate Li-Ion Intercalation in LiCoO 2 Electrode
journal, June 2007
- Okubo, Masashi; Hosono, Eiji; Kim, Jedeok
- Journal of the American Chemical Society, Vol. 129, Issue 23
The Effect of Al Substitution on the Chemical and Electrochemical Phase Stability of Orthorhombic LiMnO 2
journal, November 2012
- Cook, John B.; Kim, Chunjoong; Xu, Linping
- Journal of The Electrochemical Society, Vol. 160, Issue 1
High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance
journal, April 2013
- Augustyn, Veronica; Come, Jérémy; Lowe, Michael A.
- Nature Materials, Vol. 12, Issue 6
Graphene decorated with molybdenum dioxide nanoparticles for use in high energy lithium ion capacitors with an organic electrolyte
journal, January 2013
- Han, Pengxian; Ma, Wen; Pang, Shuping
- Journal of Materials Chemistry A, Vol. 1, Issue 19
Ordered mesoporous α-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors
journal, January 2010
- Brezesinski, Torsten; Wang, John; Tolbert, Sarah H.
- Nature Materials, Vol. 9, Issue 2
Where Do Batteries End and Supercapacitors Begin?
journal, March 2014
- Simon, P.; Gogotsi, Y.; Dunn, B.
- Science, Vol. 343, Issue 6176
Morphosynthesis of a hierarchical MoO2 nanoarchitecture as a binder-free anode for lithium-ion batteries
journal, January 2011
- Sun, Yongming; Hu, Xianluo; Yu, Jimmy C.
- Energy & Environmental Science, Vol. 4, Issue 8
Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005
- Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
- Nature Materials, Vol. 4, Issue 5, p. 366-377
Nanomaterials for Rechargeable Lithium Batteries
journal, April 2008
- Bruce, Peter G.; Scrosati, Bruno; Tarascon, Jean-Marie
- Angewandte Chemie International Edition, Vol. 47, Issue 16, p. 2930-2946
Facile synthesis of reduced graphene oxide in supercritical alcohols and its lithium storage capacity
journal, January 2011
- Budi Nursanto, Eduardus; Nugroho, Agung; Hong, Seung-Ah
- Green Chemistry, Vol. 13, Issue 10
Langmuir−Blodgett Assembly of Graphite Oxide Single Layers
journal, January 2009
- Cote, Laura J.; Kim, Franklin; Huang, Jiaxing
- Journal of the American Chemical Society, Vol. 131, Issue 3
Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO2 (Anatase) Nanoparticles
journal, October 2007
- Wang, John; Polleux, Julien; Lim, James
- The Journal of Physical Chemistry C, Vol. 111, Issue 40, p. 14925-14931
The role and utilization of pseudocapacitance for energy storage by supercapacitors
journal, May 1997
- Conway, B. E.; Birss, V.; Wojtowicz, J.
- Journal of Power Sources, Vol. 66, Issue 1-2
Preparation of Graphitic Oxide
journal, March 1958
- Hummers, William S.; Offeman, Richard E.
- Journal of the American Chemical Society, Vol. 80, Issue 6, p. 1339-1339
Visualization of defect densities in reduced graphene oxide
journal, August 2012
- Eigler, Siegfried; Dotzer, Christoph; Hirsch, Andreas
- Carbon, Vol. 50, Issue 10
Hydrous Ruthenium Oxide as an Electrode Material for Electrochemical Capacitors
journal, January 1995
- Zheng, J. P.
- Journal of The Electrochemical Society, Vol. 142, Issue 8
Crystalline MnO[sub 2] as Possible Alternatives to Amorphous Compounds in Electrochemical Supercapacitors
journal, January 2006
- Brousse, Thierry; Toupin, Mathieu; Dugas, Romain
- Journal of The Electrochemical Society, Vol. 153, Issue 12
Ammoxidation of toluene over molybdenum oxides
journal, January 1988
- Andersson, Arne; Hansen, Staffan
- Catalysis Letters, Vol. 1, Issue 11
MoO2 synthesized by reduction of MoO3 with ethanol vapor as an anode material with good rate capability for the lithium ion battery
journal, April 2008
- Yang, L. C.; Gao, Q. S.; Tang, Y.
- Journal of Power Sources, Vol. 179, Issue 1
Transition from “Supercapacitor” to “Battery” Behavior in Electrochemical Energy Storage
journal, January 1991
- Conway, B. E.
- Journal of The Electrochemical Society, Vol. 138, Issue 6, p. 1539-1548
Lithium Intercalation Cells Without Metallic Lithium
journal, January 1987
- Auborn, J. J.
- Journal of The Electrochemical Society, Vol. 134, Issue 3
Nanoscale mapping of ion diffusion in a lithium-ion battery cathode
journal, August 2010
- Balke, N.; Jesse, S.; Morozovska, A. N.
- Nature Nanotechnology, Vol. 5, Issue 10
Preparation of Novel Mesoporous Silica Using a Self-Assembled Graphene Oxide Template
journal, April 2020
- Park, Kyeong-Won; Kwon, Oh-Yun
- Scientific Reports, Vol. 10, Issue 1
Transition from 'supercapacitor' to 'battery' behavior in electrochemical energy storage
conference, January 1990
- Conway, B. E.
- Proceedings of the 34th International Power Sources Symposium
The role and utilization of pseudocapacitance for energy storage by supercapacitors
other, January 1997
- Birss, Viola I.; Conway, B. E.; Wojtowicz, J.
- Elsevier
Works referencing / citing this record:
Rapid Pseudocapacitive Sodium-Ion Response Induced by 2D Ultrathin Tin Monoxide Nanoarrays
journal, February 2017
- Chen, Minghua; Chao, Dongliang; Liu, Jilei
- Advanced Functional Materials, Vol. 27, Issue 12
Enhanced Capacity and Rate Capability of Nitrogen/Oxygen Dual-Doped Hard Carbon in Capacitive Potassium-Ion Storage
journal, December 2017
- Yang, Jinlin; Ju, Zhicheng; Jiang, Yong
- Advanced Materials, Vol. 30, Issue 4
Multidimensional Synergistic Nanoarchitecture Exhibiting Highly Stable and Ultrafast Sodium-Ion Storage
journal, March 2018
- Tan, Shuangshuang; Jiang, Yalong; Wei, Qiulong
- Advanced Materials, Vol. 30, Issue 18
Large Intercalation Pseudocapacitance in 2D VO 2 (B): Breaking through the Kinetic Barrier
journal, August 2018
- Xia, Chuan; Lin, Zifeng; Zhou, Yungang
- Advanced Materials, Vol. 30, Issue 40
Flexible WS 2 @CNFs Membrane Electrode with Outstanding Lithium Storage Performance Derived from Capacitive Behavior
journal, December 2017
- Wu, Chen; Zeng, Xiaohui; He, Pingge
- Advanced Materials Interfaces, Vol. 5, Issue 3
Mesoporous MoS 2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na-Ion Charge Storage
journal, February 2016
- Cook, John B.; Kim, Hyung-Seok; Yan, Yan
- Advanced Energy Materials, Vol. 6, Issue 9
Pseudocapacitive Charge Storage in Thick Composite MoS 2 Nanocrystal-Based Electrodes
journal, October 2016
- Cook, John B.; Kim, Hyung-Seok; Lin, Terri C.
- Advanced Energy Materials, Vol. 7, Issue 2
Ultrafine MoO 2 -Carbon Microstructures Enable Ultralong-Life Power-Type Sodium Ion Storage by Enhanced Pseudocapacitance
journal, April 2017
- Zhao, Changtai; Yu, Chang; Zhang, Mengdi
- Advanced Energy Materials, Vol. 7, Issue 15
Emergent Pseudocapacitance of 2D Nanomaterials
journal, February 2018
- Yu, Xu; Yun, Sol; Yeon, Jeong Seok
- Advanced Energy Materials, Vol. 8, Issue 13
Electrochemical and Structural Investigation of Calcium Substituted Monoclinic Li 3 V 2 (PO 4 ) 3 Anode Materials for Li‐Ion Batteries
journal, July 2019
- Fu, Qiang; Liu, Shuoqi; Sarapulova, Angelina
- Advanced Energy Materials, Vol. 9, Issue 33
Design of Carbon/Metal Oxide Hybrids for Electrochemical Energy Storage
journal, June 2018
- Fleischmann, Simon; Tolosa, Aura; Presser, Volker
- Chemistry - A European Journal, Vol. 24, Issue 47
Phosphorus Particles Embedded in Reduced Graphene Oxide Matrix to Enhance Capacity and Rate Capability for Capacitive Potassium-Ion Storage
journal, August 2018
- Wang, Hong; Wang, Lifeng; Wang, Liancheng
- Chemistry - A European Journal, Vol. 24, Issue 52
MoS 2 /MoO x -Nanostructure-Decorated Activated Carbon Cloth for Enhanced Supercapacitor Performance
journal, February 2018
- Sari, Fitri Nur Indah; Ting, Jyh-Ming
- ChemSusChem, Vol. 11, Issue 5
Co–Sn Nanocrystalline Solid Solutions as Anode Materials in Lithium‐Ion Batteries with High Pseudocapacitive Contribution
journal, April 2019
- Li, Junshan; Xu, Xijun; Luo, Zhishan
- ChemSusChem, Vol. 12, Issue 7
In Operando Calorimetric Measurements for Activated Carbon Electrodes in Ionic Liquid Electrolytes under Large Potential Windows
journal, January 2020
- Munteshari, Obaidallah; Borenstein, Arie; DeBlock, Ryan H.
- ChemSusChem, Vol. 13, Issue 5
Enhanced pseudocapacitive energy storage properties of Nb 2 O 5 /C core‐shell structures with the surface modification
journal, May 2019
- Kim, Jong Woung; Kim, Sang‐Ok; Kim, Hyung‐Seok
- International Journal of Energy Research, Vol. 43, Issue 9
A 1D Honeycomb‐Like Amorphous Zincic Vanadate for Stable and Fast Sodium‐Ion Storage
journal, January 2020
- Qin, Zhongzheng; Lv, Chade; Pei, Jian
- Small, Vol. 16, Issue 5
Interface-modulated fabrication of hierarchical yolk–shell Co3O4/C dodecahedrons as stable anodes for lithium and sodium storage
journal, April 2017
- Wu, Yuzhu; Meng, Jiashen; Li, Qi
- Nano Research, Vol. 10, Issue 7
Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance
journal, June 2016
- Chao, Dongliang; Zhu, Changrong; Yang, Peihua
- Nature Communications, Vol. 7, Issue 1
Efficient storage mechanisms for building better supercapacitors
journal, May 2016
- Salanne, M.; Rotenberg, B.; Naoi, K.
- Nature Energy, Vol. 1, Issue 6
Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x
journal, December 2016
- Kim, Hyung-Seok; Cook, John B.; Lin, Hao
- Nature Materials, Vol. 16, Issue 4
Achieving high energy density and high power density with pseudocapacitive materials
journal, October 2019
- Choi, Christopher; Ashby, David S.; Butts, Danielle M.
- Nature Reviews Materials, Vol. 5, Issue 1
Li 4 Ti 5 O 12 –TiO 2 /MoO 2 nanoclusters-embedded into carbon nanosheets core/shell porous superstructures boost lithium ion storage
journal, January 2017
- Yang, Yong; Wang, Shitong; Luo, Mingchuan
- Journal of Materials Chemistry A, Vol. 5, Issue 24
Fresh MoO 2 as a better electrode for pseudocapacitive sodium-ion storage
journal, January 2018
- Zhao, Xu; Zhao, Yundong; Yang, Ying
- New Journal of Chemistry, Vol. 42, Issue 18
Pseudocapacitive layered birnessite sodium manganese dioxide for high-rate non-aqueous sodium ion capacitors
journal, January 2018
- Jiang, Yalong; Tan, Shuangshuang; Wei, Qiulong
- Journal of Materials Chemistry A, Vol. 6, Issue 26
Self-stacked multilayer FeOCl supported on a cellulose-derived carbon aerogel: a new and high-performance anode material for supercapacitors
journal, January 2019
- Wan, Caichao; Jiao, Yue; Bao, Wenhui
- Journal of Materials Chemistry A, Vol. 7, Issue 16
Targeted synthesis of ionic liquid-polyoxometalate derived Mo-based electrodes for advanced electrochemical performance
journal, January 2019
- Chen, Guojian; Zhang, Lei; Zhang, Yadong
- Journal of Materials Chemistry A, Vol. 7, Issue 12
NiS 2 nanoparticles anchored on open carbon nanohelmets as an advanced anode for lithium-ion batteries
journal, January 2020
- Yang, D. D.; Zhao, M.; Zhang, R. D.
- Nanoscale Advances, Vol. 2, Issue 1
Molybdenum oxide nano-dumplings with excellent stability for photothermal cancer therapy and as a controlled release hydrogel
journal, January 2019
- Yang, Haiyao; Guo, Yanxian; Zhuang, Zhengfei
- New Journal of Chemistry, Vol. 43, Issue 36
Towards fast-charging technologies in Li + /Na + storage: from the perspectives of pseudocapacitive materials and non-aqueous hybrid capacitors
journal, January 2019
- Huang, Haijian; Niederberger, Markus
- Nanoscale, Vol. 11, Issue 41
Electrochemically modified graphite paper as an advanced electrode substrate for supercapacitor application
journal, January 2019
- Mandal, Debasish; Routh, Parimal; Mahato, Ashok K.
- Journal of Materials Chemistry A, Vol. 7, Issue 29
Carbon Coated SnO 2 as a Negative Electrode Additive for High Performance Lead Acid Batteries and Supercapacitors
journal, January 2019
- Naresh, Vangapally; Martha, Surendra K.
- Journal of The Electrochemical Society, Vol. 166, Issue 4
MnO 2 -Carbon Nanotube Electrodes for Supercapacitors with High Active Mass Loadings
journal, January 2017
- Chen, Ri; Poon, Ryan; Sahu, Rakesh P.
- Journal of The Electrochemical Society, Vol. 164, Issue 7
Electrochemical and Structural Investigation of Calcium Substituted Monoclinic Li3V2(PO4)3 Anode Materials for Li‐Ion Batteries
text, January 2019
- Fu, Qiang; Liu, Shuoqi; Sarapulova, Angelina
- Karlsruhe
Towards fast-charging technologies in Li+/Na+ storage: from the perspectives of pseudocapacitive materials and non-aqueous hybrid capacitors
text, January 2019
- Huang, Haijian; Niederberger, Markus
- ETH Zurich
Design of Carbon/Metal Oxide Hybrids for Electrochemical Energy Storage
collection, January 2018
- Fleischmann, Simon; Tolosa, Aura; Presser, Volker
- Universität des Saarlandes