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Title: Mesoporous MoS2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na-Ion Charge Storage

Abstract

The ion insertion properties of MoS2 continue to be of widespread interest for energy storage. While much of the current work on MoS2 has been focused on the high capacity four-electron reduction reaction, this process is prone to poor reversibility. Traditional ion intercalation reactions are highlighted and it is demonstrated that ordered mesoporous thin films of MoS2 can be utilized as a pseudocapacitive energy storage material with a specific capacity of 173 mAh g-1 for Li-ions and 118 mAh g-1 for Na-ions at 1 mV s-1. Utilizing synchrotron grazing incidence X-ray diffraction techniques, fast electrochemical kinetics are correlated with the ordered porous structure and with an iso-oriented crystal structure. When Li-ions are utilized, the material can be charged and discharged in 20 seconds while still achieving a specific capacity of 140 mAh g-1. Moreover, the nanoscale architecture of mesoporous MoS2 retains this level of lithium capacity for 10 000 cycles. A detailed electrochemical kinetic analysis indicates that energy storage for both ions in MoS2 is due to a pseudocapacitive mechanism.

Authors:
 [1];  [2];  [1];  [2];  [1];  [3];  [4]
  1. Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry
  2. Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering
  3. Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering; Univ. of California, Los Angeles, CA (United States). The California NanoSystems Inst.
  4. Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry; Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering; Univ. of California, Los Angeles, CA (United States). The California NanoSystems Inst.
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC), Washington D.C. (United States). Molecularly Engineered Energy Materials (MEEM)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1370230
Grant/Contract Number:  
SC0001342; SC0014213
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 6; Journal Issue: 9; Related Information: MEEM partners with University of California, Los Angeles (lead); University of California, Berkeley; Eastern Washington University; University of Kansas; National Renewable Energy Laboratory; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 42 ENGINEERING; electrochemical-energy storage; psuedocapacitance; lithium-ion batteries; MoS2; sodium-ion batteries

Citation Formats

Cook, John B., Kim, Hyung-Seok, Yan, Yan, Ko, Jesse S., Robbennolt, Shauna, Dunn, Bruce, and Tolbert, Sarah H. Mesoporous MoS2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na-Ion Charge Storage. United States: N. p., 2016. Web. doi:10.1002/aenm.201501937.
Cook, John B., Kim, Hyung-Seok, Yan, Yan, Ko, Jesse S., Robbennolt, Shauna, Dunn, Bruce, & Tolbert, Sarah H. Mesoporous MoS2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na-Ion Charge Storage. United States. doi:10.1002/aenm.201501937.
Cook, John B., Kim, Hyung-Seok, Yan, Yan, Ko, Jesse S., Robbennolt, Shauna, Dunn, Bruce, and Tolbert, Sarah H. Mon . "Mesoporous MoS2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na-Ion Charge Storage". United States. doi:10.1002/aenm.201501937. https://www.osti.gov/servlets/purl/1370230.
@article{osti_1370230,
title = {Mesoporous MoS2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na-Ion Charge Storage},
author = {Cook, John B. and Kim, Hyung-Seok and Yan, Yan and Ko, Jesse S. and Robbennolt, Shauna and Dunn, Bruce and Tolbert, Sarah H.},
abstractNote = {The ion insertion properties of MoS2 continue to be of widespread interest for energy storage. While much of the current work on MoS2 has been focused on the high capacity four-electron reduction reaction, this process is prone to poor reversibility. Traditional ion intercalation reactions are highlighted and it is demonstrated that ordered mesoporous thin films of MoS2 can be utilized as a pseudocapacitive energy storage material with a specific capacity of 173 mAh g-1 for Li-ions and 118 mAh g-1 for Na-ions at 1 mV s-1. Utilizing synchrotron grazing incidence X-ray diffraction techniques, fast electrochemical kinetics are correlated with the ordered porous structure and with an iso-oriented crystal structure. When Li-ions are utilized, the material can be charged and discharged in 20 seconds while still achieving a specific capacity of 140 mAh g-1. Moreover, the nanoscale architecture of mesoporous MoS2 retains this level of lithium capacity for 10 000 cycles. A detailed electrochemical kinetic analysis indicates that energy storage for both ions in MoS2 is due to a pseudocapacitive mechanism.},
doi = {10.1002/aenm.201501937},
journal = {Advanced Energy Materials},
number = 9,
volume = 6,
place = {United States},
year = {2016},
month = {2}
}

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    • Advanced Energy Materials, Vol. 8, Issue 10
    • DOI: 10.1002/aenm.201702488

    Porous MoS 2 /Carbon Spheres Anchored on 3D Interconnected Multiwall Carbon Nanotube Networks for Ultrafast Na Storage
    journal, February 2018

    • Chen, Biao; Lu, Huihui; Zhou, Jingwen
    • Advanced Energy Materials, Vol. 8, Issue 15
    • DOI: 10.1002/aenm.201702909

    Emergent Pseudocapacitance of 2D Nanomaterials
    journal, February 2018


    Vertically Oriented MoS 2 with Spatially Controlled Geometry on Nitrogenous Graphene Sheets for High-Performance Sodium-Ion Batteries
    journal, March 2018

    • Li, Ping; Jeong, Jong Yeob; Jin, Bingjun
    • Advanced Energy Materials, Vol. 8, Issue 19
    • DOI: 10.1002/aenm.201703300

    Metal-Organophosphine Framework-Derived N,P-Codoped Carbon-Confined Cu 3 P Nanopaticles for Superb Na-Ion Storage
    journal, August 2018

    • Kong, Minhong; Song, Huaihe; Zhou, Jisheng
    • Advanced Energy Materials, Vol. 8, Issue 27
    • DOI: 10.1002/aenm.201801489

    Thionine Functionalized 3D Graphene Aerogel: Combining Simplicity and Efficiency in Fabrication of a Metal-Free Redox Supercapacitor
    journal, October 2018

    • Shabangoli, Yasin; Rahmanifar, Mohammad S.; El-Kady, Maher F.
    • Advanced Energy Materials, Vol. 8, Issue 34
    • DOI: 10.1002/aenm.201802869

    Hierarchical Hollow-Microsphere Metal-Selenide@Carbon Composites with Rational Surface Engineering for Advanced Sodium Storage
    journal, November 2018


    A Pseudolayered MoS 2 as Li-Ion Intercalation Host with Enhanced Rate Capability and Durability
    journal, October 2018


    Rapid synthesis of transition metal dichalcogenide–carbon aerogel composites for supercapacitor electrodes
    journal, July 2017

    • Crane, Matthew J.; Lim, Matthew B.; Zhou, Xuezhe
    • Microsystems & Nanoengineering, Vol. 3, Issue 1
    • DOI: 10.1038/micronano.2017.32

    Hybrid two-dimensional materials in rechargeable battery applications and their microscopic mechanisms
    journal, January 2016

    • Wang, Xi; Weng, Qunhong; Yang, Yijun
    • Chemical Society Reviews, Vol. 45, Issue 15
    • DOI: 10.1039/c5cs00937e

    2D MoS 2 /graphene composites with excellent full Ku band microwave absorption
    journal, January 2016

    • Wang, Xiaoxia; Zhang, Wenling; Ji, Xuqiang
    • RSC Advances, Vol. 6, Issue 108
    • DOI: 10.1039/c6ra22817h

    Recent progresses in high-energy-density all pseudocapacitive-electrode-materials-based asymmetric supercapacitors
    journal, January 2017

    • Sun, Jinfeng; Wu, Chen; Sun, Xiaofei
    • Journal of Materials Chemistry A, Vol. 5, Issue 20
    • DOI: 10.1039/c7ta00932a

    Facile in situ synthesis of crystalline VOOH-coated VS 2 microflowers with superior sodium storage performance
    journal, January 2017

    • Li, Wenbin; Huang, Jianfeng; Feng, Liangliang
    • Journal of Materials Chemistry A, Vol. 5, Issue 38
    • DOI: 10.1039/c7ta05205g

    Towards establishing standard performance metrics for batteries, supercapacitors and beyond
    journal, January 2019

    • Noori, Abolhassan; El-Kady, Maher F.; Rahmanifar, Mohammad S.
    • Chemical Society Reviews, Vol. 48, Issue 5
    • DOI: 10.1039/c8cs00581h

    MoS 2 nanosheets with expanded interlayer spacing for enhanced sodium storage
    journal, January 2018

    • Dong, Huishuang; Xu, Yang; Zhang, Chenglin
    • Inorganic Chemistry Frontiers, Vol. 5, Issue 12
    • DOI: 10.1039/c8qi00969d

    Metallic 1T phase MoS 2 nanosheets decorated hollow cobalt sulfide polyhedra for high-performance lithium storage
    journal, January 2018

    • Lu, Jian; Xia, Guoliang; Gong, Shipeng
    • Journal of Materials Chemistry A, Vol. 6, Issue 26
    • DOI: 10.1039/c8ta02716a

    Ultrafast lithium energy storage enabled by interfacial construction of interlayer-expanded MoS 2 /N-doped carbon nanowires
    journal, January 2018

    • Sun, Huanhuan; Wang, Jian-Gan; Zhang, Yu
    • Journal of Materials Chemistry A, Vol. 6, Issue 27
    • DOI: 10.1039/c8ta04852e

    Adjusting the yolk–shell structure of carbon spheres to boost the capacitive K + storage ability
    journal, January 2018

    • Zhang, Hehe; He, Hanna; Luan, Jingyi
    • Journal of Materials Chemistry A, Vol. 6, Issue 46
    • DOI: 10.1039/c8ta07438k

    Insights into the intrinsic capacity of interlayer-expanded MoS 2 as a Li-ion intercalation host
    journal, January 2019

    • Gong, Shan; Zhao, Guangyu; Lyu, Pengbo
    • Journal of Materials Chemistry A, Vol. 7, Issue 3
    • DOI: 10.1039/c8ta08120d

    Insight into the intercalation mechanism of WSe 2 onions toward metal ion capacitors: sodium rivals lithium
    journal, January 2018

    • Wang, Yichun; Zhang, Xin; Xiong, Peixun
    • Journal of Materials Chemistry A, Vol. 6, Issue 43
    • DOI: 10.1039/c8ta09286a

    A kinetics study on intercalation pseudocapacitance of layered TiS 2 in K-ion batteries
    journal, January 2019

    • Zhang, Rongyu; Yang, Xu; Xu, Shifeng
    • Physical Chemistry Chemical Physics, Vol. 21, Issue 47
    • DOI: 10.1039/c9cp04254g

    A cellulose substance derived nanofibrous CoS–nanoparticle/carbon composite as a high-performance anodic material for lithium-ion batteries
    journal, January 2020

    • Yuan, Hang; Wang, Fan; Li, Shun
    • New Journal of Chemistry, Vol. 44, Issue 5
    • DOI: 10.1039/c9nj05587h

    A layered Bi 2 Te 3 nanoplates/graphene composite with high gravimetric and volumetric performance for Na-ion storage
    journal, January 2019

    • Sun, Dianding; Zhang, Guanjun; Li, Dan
    • Sustainable Energy & Fuels, Vol. 3, Issue 11
    • DOI: 10.1039/c9se00544g

    Binding low crystalline MoS 2 nanoflakes on nitrogen-doped carbon nanotube: towards high-rate lithium and sodium storage
    journal, January 2019

    • Wu, Tianjing; Jing, Mingjun; Liu, Yong
    • Journal of Materials Chemistry A, Vol. 7, Issue 11
    • DOI: 10.1039/c9ta00123a

    Multivalent metal ion hybrid capacitors: a review with a focus on zinc-ion hybrid capacitors
    journal, January 2019

    • Dong, Liubing; Yang, Wang; Yang, Wu
    • Journal of Materials Chemistry A, Vol. 7, Issue 23
    • DOI: 10.1039/c9ta02678a

    Nitrogen-doped hollow carbon nanospheres towards the application of potassium ion storage
    journal, January 2019

    • Ruan, Jiafeng; Wu, Xi; Wang, Yan
    • Journal of Materials Chemistry A, Vol. 7, Issue 33
    • DOI: 10.1039/c9ta05205d

    α-MnO 2 @In 2 O 3  Nanotubes as Cathode Material for Aqueous Rechargeable Zn-Ion Battery with High Electrochemical Performance
    journal, January 2019

    • Gou, Lei; Xue, Dong; Mou, Ke-Liang
    • Journal of The Electrochemical Society, Vol. 166, Issue 14
    • DOI: 10.1149/2.0801914jes