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Title: Mesoporous MoS2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na-Ion Charge Storage

Abstract

The ion insertion properties of MoS2 continue to be of widespread interest for energy storage. While much of the current work on MoS2 has been focused on the high capacity four-electron reduction reaction, this process is prone to poor reversibility. Traditional ion intercalation reactions are highlighted and it is demonstrated that ordered mesoporous thin films of MoS2 can be utilized as a pseudocapacitive energy storage material with a specific capacity of 173 mAh g-1 for Li-ions and 118 mAh g-1 for Na-ions at 1 mV s-1. Utilizing synchrotron grazing incidence X-ray diffraction techniques, fast electrochemical kinetics are correlated with the ordered porous structure and with an iso-oriented crystal structure. When Li-ions are utilized, the material can be charged and discharged in 20 seconds while still achieving a specific capacity of 140 mAh g-1. Moreover, the nanoscale architecture of mesoporous MoS2 retains this level of lithium capacity for 10 000 cycles. A detailed electrochemical kinetic analysis indicates that energy storage for both ions in MoS2 is due to a pseudocapacitive mechanism.

Authors:
 [1];  [2];  [1];  [2];  [1];  [3];  [4]
+ Show Author Affiliations
  1. Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry
  2. Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering
  3. Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering; Univ. of California, Los Angeles, CA (United States). The California NanoSystems Inst.
  4. Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry; Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering; Univ. of California, Los Angeles, CA (United States). The California NanoSystems Inst.
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC), Washington D.C. (United States). Molecularly Engineered Energy Materials (MEEM)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1370230
Grant/Contract Number:  
SC0001342; SC0014213
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 6; Journal Issue: 9; Related Information: MEEM partners with University of California, Los Angeles (lead); University of California, Berkeley; Eastern Washington University; University of Kansas; National Renewable Energy Laboratory; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 42 ENGINEERING; electrochemical-energy storage; psuedocapacitance; lithium-ion batteries; MoS2; sodium-ion batteries

Citation Formats

Cook, John B., Kim, Hyung-Seok, Yan, Yan, Ko, Jesse S., Robbennolt, Shauna, Dunn, Bruce, and Tolbert, Sarah H. Mesoporous MoS2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na-Ion Charge Storage. United States: N. p., 2016. Web. doi:10.1002/aenm.201501937.
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Cook, John B., Kim, Hyung-Seok, Yan, Yan, Ko, Jesse S., Robbennolt, Shauna, Dunn, Bruce, & Tolbert, Sarah H. Mesoporous MoS2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na-Ion Charge Storage. United States. https://doi.org/10.1002/aenm.201501937
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Cook, John B., Kim, Hyung-Seok, Yan, Yan, Ko, Jesse S., Robbennolt, Shauna, Dunn, Bruce, and Tolbert, Sarah H. Mon . "Mesoporous MoS2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na-Ion Charge Storage". United States. https://doi.org/10.1002/aenm.201501937. https://www.osti.gov/servlets/purl/1370230.
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@article{osti_1370230,
title = {Mesoporous MoS2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na-Ion Charge Storage},
author = {Cook, John B. and Kim, Hyung-Seok and Yan, Yan and Ko, Jesse S. and Robbennolt, Shauna and Dunn, Bruce and Tolbert, Sarah H.},
abstractNote = {The ion insertion properties of MoS2 continue to be of widespread interest for energy storage. While much of the current work on MoS2 has been focused on the high capacity four-electron reduction reaction, this process is prone to poor reversibility. Traditional ion intercalation reactions are highlighted and it is demonstrated that ordered mesoporous thin films of MoS2 can be utilized as a pseudocapacitive energy storage material with a specific capacity of 173 mAh g-1 for Li-ions and 118 mAh g-1 for Na-ions at 1 mV s-1. Utilizing synchrotron grazing incidence X-ray diffraction techniques, fast electrochemical kinetics are correlated with the ordered porous structure and with an iso-oriented crystal structure. When Li-ions are utilized, the material can be charged and discharged in 20 seconds while still achieving a specific capacity of 140 mAh g-1. Moreover, the nanoscale architecture of mesoporous MoS2 retains this level of lithium capacity for 10 000 cycles. A detailed electrochemical kinetic analysis indicates that energy storage for both ions in MoS2 is due to a pseudocapacitive mechanism.},
doi = {10.1002/aenm.201501937},
journal = {Advanced Energy Materials},
number = 9,
volume = 6,
place = {United States},
year = {Mon Feb 08 00:00:00 EST 2016},
month = {Mon Feb 08 00:00:00 EST 2016}
}
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    Pseudocapacitive Charge Storage in Thick Composite MoS 2 Nanocrystal-Based Electrodes
    journal, October 2016

    • Cook, John B.; Kim, Hyung-Seok; Lin, Terri C.
    • Advanced Energy Materials, Vol. 7, Issue 2
    • DOI: 10.1002/aenm.201601283

    Nature-Inspired Electrochemical Energy-Storage Materials and Devices
    journal, December 2016

    Ultrafine MoO 2 -Carbon Microstructures Enable Ultralong-Life Power-Type Sodium Ion Storage by Enhanced Pseudocapacitance
    journal, April 2017

    • Zhao, Changtai; Yu, Chang; Zhang, Mengdi
    • Advanced Energy Materials, Vol. 7, Issue 15
    • DOI: 10.1002/aenm.201602880

    Highly Conductive, Lightweight, Low-Tortuosity Carbon Frameworks as Ultrathick 3D Current Collectors
    journal, May 2017

    Revealing Pseudocapacitive Mechanisms of Metal Dichalcogenide SnS 2 /Graphene-CNT Aerogels for High-Energy Na Hybrid Capacitors
    journal, December 2017

    • Cui, Jiang; Yao, Shanshan; Lu, Ziheng
    • Advanced Energy Materials, Vol. 8, Issue 10
    • DOI: 10.1002/aenm.201702488

    Porous MoS 2 /Carbon Spheres Anchored on 3D Interconnected Multiwall Carbon Nanotube Networks for Ultrafast Na Storage
    journal, February 2018

    • Chen, Biao; Lu, Huihui; Zhou, Jingwen
    • Advanced Energy Materials, Vol. 8, Issue 15
    • DOI: 10.1002/aenm.201702909

    Emergent Pseudocapacitance of 2D Nanomaterials
    journal, February 2018

    Vertically Oriented MoS 2 with Spatially Controlled Geometry on Nitrogenous Graphene Sheets for High-Performance Sodium-Ion Batteries
    journal, March 2018

    • Li, Ping; Jeong, Jong Yeob; Jin, Bingjun
    • Advanced Energy Materials, Vol. 8, Issue 19
    • DOI: 10.1002/aenm.201703300

    Metal-Organophosphine Framework-Derived N,P-Codoped Carbon-Confined Cu 3 P Nanopaticles for Superb Na-Ion Storage
    journal, August 2018

    • Kong, Minhong; Song, Huaihe; Zhou, Jisheng
    • Advanced Energy Materials, Vol. 8, Issue 27
    • DOI: 10.1002/aenm.201801489

    Thionine Functionalized 3D Graphene Aerogel: Combining Simplicity and Efficiency in Fabrication of a Metal-Free Redox Supercapacitor
    journal, October 2018

    • Shabangoli, Yasin; Rahmanifar, Mohammad S.; El-Kady, Maher F.
    • Advanced Energy Materials, Vol. 8, Issue 34
    • DOI: 10.1002/aenm.201802869

    Hierarchical Hollow-Microsphere Metal-Selenide@Carbon Composites with Rational Surface Engineering for Advanced Sodium Storage
    journal, November 2018

    Chemical Mass Production of MoS 2 /Graphene van der Waals Heterostructure as a High‐Performance Li‐ion Intercalation Host
    journal, July 2019

    A Pseudolayered MoS 2 as Li-Ion Intercalation Host with Enhanced Rate Capability and Durability
    journal, October 2018

    Rapid synthesis of transition metal dichalcogenide–carbon aerogel composites for supercapacitor electrodes
    journal, July 2017

    • Crane, Matthew J.; Lim, Matthew B.; Zhou, Xuezhe
    • Microsystems & Nanoengineering, Vol. 3, Issue 1
    • DOI: 10.1038/micronano.2017.32

    2D MoS 2 /graphene composites with excellent full Ku band microwave absorption
    journal, January 2016

    • Wang, Xiaoxia; Zhang, Wenling; Ji, Xuqiang
    • RSC Advances, Vol. 6, Issue 108
    • DOI: 10.1039/c6ra22817h

    Methyl-functionalized MoS 2 nanosheets with reduced lattice breathing for enhanced pseudocapacitive sodium storage
    journal, January 2017

    • Huang, Lei; Wei, Qiulong; Xu, Xiaoming
    • Physical Chemistry Chemical Physics, Vol. 19, Issue 21
    • DOI: 10.1039/c7cp00990a

    Recent progresses in high-energy-density all pseudocapacitive-electrode-materials-based asymmetric supercapacitors
    journal, January 2017

    • Sun, Jinfeng; Wu, Chen; Sun, Xiaofei
    • Journal of Materials Chemistry A, Vol. 5, Issue 20
    • DOI: 10.1039/c7ta00932a

    Facile in situ synthesis of crystalline VOOH-coated VS 2 microflowers with superior sodium storage performance
    journal, January 2017

    • Li, Wenbin; Huang, Jianfeng; Feng, Liangliang
    • Journal of Materials Chemistry A, Vol. 5, Issue 38
    • DOI: 10.1039/c7ta05205g

    Towards establishing standard performance metrics for batteries, supercapacitors and beyond
    journal, January 2019

    • Noori, Abolhassan; El-Kady, Maher F.; Rahmanifar, Mohammad S.
    • Chemical Society Reviews, Vol. 48, Issue 5
    • DOI: 10.1039/c8cs00581h

    MoS 2 nanosheets with expanded interlayer spacing for enhanced sodium storage
    journal, January 2018

    • Dong, Huishuang; Xu, Yang; Zhang, Chenglin
    • Inorganic Chemistry Frontiers, Vol. 5, Issue 12
    • DOI: 10.1039/c8qi00969d

    Metallic 1T phase MoS 2 nanosheets decorated hollow cobalt sulfide polyhedra for high-performance lithium storage
    journal, January 2018

    • Lu, Jian; Xia, Guoliang; Gong, Shipeng
    • Journal of Materials Chemistry A, Vol. 6, Issue 26
    • DOI: 10.1039/c8ta02716a

    Ultrafast lithium energy storage enabled by interfacial construction of interlayer-expanded MoS 2 /N-doped carbon nanowires
    journal, January 2018

    • Sun, Huanhuan; Wang, Jian-Gan; Zhang, Yu
    • Journal of Materials Chemistry A, Vol. 6, Issue 27
    • DOI: 10.1039/c8ta04852e

    Adjusting the yolk–shell structure of carbon spheres to boost the capacitive K + storage ability
    journal, January 2018

    • Zhang, Hehe; He, Hanna; Luan, Jingyi
    • Journal of Materials Chemistry A, Vol. 6, Issue 46
    • DOI: 10.1039/c8ta07438k

    Insights into the intrinsic capacity of interlayer-expanded MoS 2 as a Li-ion intercalation host
    journal, January 2019

    • Gong, Shan; Zhao, Guangyu; Lyu, Pengbo
    • Journal of Materials Chemistry A, Vol. 7, Issue 3
    • DOI: 10.1039/c8ta08120d

    Insight into the intercalation mechanism of WSe 2 onions toward metal ion capacitors: sodium rivals lithium
    journal, January 2018

    • Wang, Yichun; Zhang, Xin; Xiong, Peixun
    • Journal of Materials Chemistry A, Vol. 6, Issue 43
    • DOI: 10.1039/c8ta09286a

    A kinetics study on intercalation pseudocapacitance of layered TiS 2 in K-ion batteries
    journal, January 2019

    • Zhang, Rongyu; Yang, Xu; Xu, Shifeng
    • Physical Chemistry Chemical Physics, Vol. 21, Issue 47
    • DOI: 10.1039/c9cp04254g

    A cellulose substance derived nanofibrous CoS–nanoparticle/carbon composite as a high-performance anodic material for lithium-ion batteries
    journal, January 2020

    • Yuan, Hang; Wang, Fan; Li, Shun
    • New Journal of Chemistry, Vol. 44, Issue 5
    • DOI: 10.1039/c9nj05587h

    A layered Bi 2 Te 3 nanoplates/graphene composite with high gravimetric and volumetric performance for Na-ion storage
    journal, January 2019

    • Sun, Dianding; Zhang, Guanjun; Li, Dan
    • Sustainable Energy & Fuels, Vol. 3, Issue 11
    • DOI: 10.1039/c9se00544g

    Binding low crystalline MoS 2 nanoflakes on nitrogen-doped carbon nanotube: towards high-rate lithium and sodium storage
    journal, January 2019

    • Wu, Tianjing; Jing, Mingjun; Liu, Yong
    • Journal of Materials Chemistry A, Vol. 7, Issue 11
    • DOI: 10.1039/c9ta00123a

    Multivalent metal ion hybrid capacitors: a review with a focus on zinc-ion hybrid capacitors
    journal, January 2019

    • Dong, Liubing; Yang, Wang; Yang, Wu
    • Journal of Materials Chemistry A, Vol. 7, Issue 23
    • DOI: 10.1039/c9ta02678a

    Nitrogen-doped hollow carbon nanospheres towards the application of potassium ion storage
    journal, January 2019

    • Ruan, Jiafeng; Wu, Xi; Wang, Yan
    • Journal of Materials Chemistry A, Vol. 7, Issue 33
    • DOI: 10.1039/c9ta05205d

    α-MnO 2 @In 2 O 3  Nanotubes as Cathode Material for Aqueous Rechargeable Zn-Ion Battery with High Electrochemical Performance
    journal, January 2019

    • Gou, Lei; Xue, Dong; Mou, Ke-Liang
    • Journal of The Electrochemical Society, Vol. 166, Issue 14
    • DOI: 10.1149/2.0801914jes

    Facile Fabrication of Nitrogen-Doped Porous Carbon as Superior Anode Material for Potassium-Ion Batteries
    journal, October 2018

    Approaching the Lithiation Limit of MoS 2 While Maintaining Its Layered Crystalline Structure to Improve Lithium Storage
    journal, February 2019

    • Zhu, Zhiqiang; Tang, Yuxin; Leow, Wan Ru
    • Angewandte Chemie International Edition, Vol. 58, Issue 11
    • DOI: 10.1002/anie.201813698

    Fabrication of Porous Carbon with Controllable Nitrogen Doping as Anode for High‐Performance Potassium‐Ion Batteries
    journal, July 2019

    VS 4 ‐Decorated Carbon Nanotubes for Lithium Storage with Pseudocapacitance Contribution
    journal, March 2020

    Hollow MoS2/rGO composites as high-performance anode materials for lithium-ion batteries
    journal, May 2019

    Pseudocapacitance-tuned high-rate and long-term cyclability of NiCo 2 S 4 hexagonal nanosheets prepared by vapor transformation for lithium storage
    journal, January 2017

    • Song, Yun; Chen, Ziliang; Li, Yanmei
    • Journal of Materials Chemistry A, Vol. 5, Issue 19
    • DOI: 10.1039/c7ta01758h

    Graphene-coupled Ti 3 C 2 MXenes-derived TiO 2 mesostructure: promising sodium-ion capacitor anode with fast ion storage and long-term cycling
    journal, January 2018

    • Wang, Rutao; Wang, Shijie; Zhang, Yabin
    • Journal of Materials Chemistry A, Vol. 6, Issue 3
    • DOI: 10.1039/c7ta09153b

    Hierarchical MoS 2 /Carbon microspheres as long-life and high-rate anodes for sodium-ion batteries
    journal, January 2018

    • Wu, Junxiong; Lu, Ziheng; Li, Kaikai
    • Journal of Materials Chemistry A, Vol. 6, Issue 14
    • DOI: 10.1039/c7ta11119c

    Oxygen-deficient anatase TiO 2 @C nanospindles with pseudocapacitive contribution for enhancing lithium storage
    journal, January 2018

    • Deng, Xiaolan; Wei, Zengxi; Cui, Chunyu
    • Journal of Materials Chemistry A, Vol. 6, Issue 9
    • DOI: 10.1039/c7ta11301c

    Identifying the origin and contribution of pseudocapacitive sodium ion storage in tungsten disulphide nanosheets for application in sodium-ion capacitors
    journal, January 2018

    • Ding, Chunxia; Huang, Ting; Tao, Yaping
    • Journal of Materials Chemistry A, Vol. 6, Issue 42
    • DOI: 10.1039/c8ta07677d

    An Ångström-level d -spacing controlling synthetic route for MoS 2 towards stable intercalation of sodium ions
    journal, January 2018

    • Zhang, Kan; Li, Ping; Guo, Shiying
    • Journal of Materials Chemistry A, Vol. 6, Issue 45
    • DOI: 10.1039/c8ta09066a

    Embedding heterostructured MnS/Co 1−x S nanoparticles in porous carbon/graphene for superior lithium storage
    journal, January 2019

    • Li, Baosheng; Wang, Ruirui; Chen, Ziliang
    • Journal of Materials Chemistry A, Vol. 7, Issue 3
    • DOI: 10.1039/c8ta09740b

    Recent advances in amphiphilic block copolymer templated mesoporous metal-based materials: assembly engineering and applications
    journal, January 2020

    • Zou, Yidong; Zhou, Xinran; Ma, Junhao
    • Chemical Society Reviews, Vol. 49, Issue 4
    • DOI: 10.1039/c9cs00334g

    Highly dispersed ultrasmall NiS 2 nanoparticles in porous carbon nanofiber anodes for sodium ion batteries
    journal, January 2019

    • Zhao, Wenxiang; Ci, Suqin; Hu, Xiang
    • Nanoscale, Vol. 11, Issue 11
    • DOI: 10.1039/c9nr00160c

    Laser-induced fabrication of nanoporous monolayer WS 2 membranes
    journal, April 2018

    A Facile Synthesis of MoS2/g-C3N4 Composite as an Anode Material with Improved Lithium Storage Capacity
    journal, May 2019

    • Tran Huu, Ha; Nguyen Thi, Xuan Dieu; Nguyen Van, Kim
    • Materials, Vol. 12, Issue 11
    • DOI: 10.3390/ma12111730

    Mesoporous NiS 2 Nanospheres Anode with Pseudocapacitance for High-Rate and Long-Life Sodium-Ion Battery
    journal, August 2017

    One step in situ synthesis of ZnS/N and S co-doped carbon composites via salt templating for lithium-ion battery applications
    journal, January 2019

    • Ikram, Sadaf; Müller, Marcus; Dsoke, Sonia
    • New Journal of Chemistry, Vol. 43, Issue 33
    • DOI: 10.1039/c9nj02488c

    Enhancing potassium-ion battery performance by defect and interlayer engineering
    journal, January 2019

    • Xu, Yang; Bahmani, Farzaneh; Zhou, Min
    • Nanoscale Horizons, Vol. 4, Issue 1
    • DOI: 10.1039/c8nh00305j

    Growth of MoS 2 Nanoflowers with Expanded Interlayer Distance onto N-Doped Graphene for Reversible Lithium Storage
    journal, June 2018

    Hierarchical MoS 2 @N‐Doped Carbon Hollow Spheres with Enhanced Performance in Sodium Dual‐Ion Batteries
    journal, September 2018

    Three-Dimensional PrGO-Based Sandwich Composites With MoS2 Flowers as Stuffings for Superior Lithium Storage
    journal, February 2020

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