Thermoelectric power as a probe of density of states in correlated actinide materials: The case of PuCoGa5 superconductor

Gofryk, K.; Griveau, J. -C.; Riseborough, P. S.; Durakiewicz, T.

doi:10.1103/PhysRevB.94.195117

Title: Thermoelectric power as a probe of density of states in correlated actinide materials: The case of PuCoGa₅ superconductor

Abstract

We present measurements of the thermoelectric power of the plutonium-based unconventional superconductor PuCoGa₅. The data is interpreted within a phenomenological model for the quasiparticle density of states of intermediate valence systems and the results are compared with results obtained from photoemission spectroscopy. The results are consistent with intermediate valence nature of 5f-electrons, furthermore, we propose that measurements of the Seebeck coefficient can be used as a probe of density of states in this material, thereby providing a link between transport measurements and photoemission in strongly correlated materials. Here, we discuss these results and their implications for the electronic structure determination of other strongly correlated systems, especially nuclear materials.

Authors:

Gofryk, K. ^[1]; Griveau, J. -C. ^[2]; Riseborough, P. S. ^[3]; Durakiewicz, T. ^[4]

Idaho National Lab. (INL), Idaho Falls, ID (United States)
European Commission, Karlsruhe (Germany). Joint Research Centre, Inst. for Transuranium Elements
Temple Univ., Philadelphia, PA (United States). Dept. of Physics
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Publication Date:: Wed Nov 09 00:00:00 EST 2016

Research Org.:: Idaho National Laboratory (INL), Idaho Falls, ID (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1369437

Alternate Identifier(s):: OSTI ID: 1331407; OSTI ID: 1415374

Report Number(s):: INL/JOU-16-39090; LA-UR-17-22208
Journal ID: ISSN 2469-9950; PRBMDO; TRN: US1702660

Grant/Contract Number:: AC07-05ID14517; FG02-01ER45872; AC52-06NA25396

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 94; Journal Issue: 19; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE; superconductivity; thermoelectric power; Material Science

Citation Formats


                    Gofryk, K., Griveau, J. -C., Riseborough, P. S., and Durakiewicz, T. Thermoelectric power as a probe of density of states in correlated actinide materials: The case of PuCoGa5 superconductor.  United States: N. p., 2016. 
Web.  doi:10.1103/PhysRevB.94.195117.

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                    Gofryk, K., Griveau, J. -C., Riseborough, P. S., & Durakiewicz, T. Thermoelectric power as a probe of density of states in correlated actinide materials: The case of PuCoGa5 superconductor.  United States.  https://doi.org/10.1103/PhysRevB.94.195117

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                    Gofryk, K., Griveau, J. -C., Riseborough, P. S., and Durakiewicz, T. Wed .  
"Thermoelectric power as a probe of density of states in correlated actinide materials: The case of PuCoGa5 superconductor".  United States.  https://doi.org/10.1103/PhysRevB.94.195117.  https://www.osti.gov/servlets/purl/1369437.

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@article{osti_1369437,

  title        = {Thermoelectric power as a probe of density of states in correlated actinide materials: The case of PuCoGa5 superconductor},

  author       = {Gofryk, K. and Griveau, J. -C. and Riseborough, P. S. and Durakiewicz, T.},

  abstractNote = {We present measurements of the thermoelectric power of the plutonium-based unconventional superconductor PuCoGa5. The data is interpreted within a phenomenological model for the quasiparticle density of states of intermediate valence systems and the results are compared with results obtained from photoemission spectroscopy. The results are consistent with intermediate valence nature of 5f-electrons, furthermore, we propose that measurements of the Seebeck coefficient can be used as a probe of density of states in this material, thereby providing a link between transport measurements and photoemission in strongly correlated materials. Here, we discuss these results and their implications for the electronic structure determination of other strongly correlated systems, especially nuclear materials.},

  doi          = {10.1103/PhysRevB.94.195117},

  journal      = {Physical Review B},

  number       = 19,

  volume       = 94,

  place        = {United States},

  year         = {Wed Nov 09 00:00:00 EST 2016},

  month        = {Wed Nov 09 00:00:00 EST 2016}

}

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Works referencing / citing this record:

Crystal electric field contribution to the thermoelectric power of the CeCoAl 4 antiferromagnetic
journal, December 2018

Toliński, Tomasz
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Title: Thermoelectric power as a probe of density of states in correlated actinide materials: The case of PuCoGa5 superconductor

Abstract

Citation Formats

Some comments on Kondo lattices and the Mott transition journal, December 1998

U Be 13 : An Unconventional Actinide Superconductor journal, May 1983

Relationship between the thermopower and entropy of strongly correlated electron systems journal, August 2007

Non-Fermi-liquid behavior in d - and f -electron metals journal, October 2001

Unconventional superconductivity in PuCoGa5 journal, March 2005

Coherence Scale of the Kondo Lattice journal, July 2000

The seebeck coefficient of YbAl2 and YbAl3 journal, September 1974

Exchange Interaction in Alloys with Cerium Impurities journal, September 1969

Thermoelectric power of Ce-based intermediate valent systems journal, May 2006

Thermoelectric power of compounds with cerium: Influence of the crystalline field on the Kondo effect journal, April 1976

Fermi-liquid instabilities at magnetic quantum phase transitions journal, August 2007

Nature of the 5 f states in actinide metals journal, February 2009

Large thermoelectric power in several metallic compounds of cerium and uranium journal, December 2000

Plutonium-based superconductivity with a transition temperature above 18 K journal, November 2002

Thermoelectric power of cerium and ytterbium intermetallics journal, September 2003

Pressure dependence of the superconductivity in PuCoGa5 journal, May 2004

High-pressure transport properties of CeRu 2 Ge 2 journal, March 2005

Kondo Lattices and the Mott Metal–Insulator Transition journal, January 2005

Superconducting and Magnetic Transitions in the Heavy-Fermion System U Ru 2 Si 2 journal, December 1985

Thermopower of Yb Heavy Fermion Compounds at High Pressure journal, January 1999

Theory of the thermoelectricity of intermetallic compounds with Ce or Yb ions journal, April 2005

The thermoelectric power of Kondo cerium and ytterbium compounds journal, March 2002

Thermoelectric Materials, Phenomena, and Applications: A Bird's Eye View journal, March 2006

Addendum: Non-Fermi-liquid behavior in d - and f -electron metals journal, July 2006

Transport coefficients of intermediate valent CeNix intermetallic compounds journal, February 1985

Electronic structure calculations with dynamical mean-field theory journal, August 2006

Thermoelectrical power of heavy fermion compounds journal, May 2006

Mixed valent metals journal, July 2016

Avoided valence transition in a plutonium superconductor journal, March 2015

Photoemission and the Electronic Structure of P u C o G a 5 journal, October 2003

Electronic structure and correlation effects in PuCoIn 5 as compared to PuCoGa 5 journal, February 2012

Anomalously large thermoelectric cooling figure of merit in the Kondo systems CePd 3 and Celn 3 journal, May 1973

Dependence of the CeNi5 thermoelectric power on strong 4f-electron instability journal, July 2001

On the thermoelectricity of correlated electrons in the zero-temperature limit journal, July 2004

Localization of magnetic moments of cerium in single crystalline Ce Pt 4 In journal, March 2006

Crystal electric field contribution to the thermoelectric power of the CeCoAl 4 antiferromagnetic journal, December 2018

Title: Thermoelectric power as a probe of density of states in correlated actinide materials: The case of PuCoGa₅ superconductor

Some comments on Kondo lattices and the Mott transition
journal, December 1998

U ${Be}_{13}$ : An Unconventional Actinide Superconductor
journal, May 1983

Relationship between the thermopower and entropy of strongly correlated electron systems
journal, August 2007

Non-Fermi-liquid behavior in $d$ - and $f$ -electron metals
journal, October 2001

Unconventional superconductivity in PuCoGa5
journal, March 2005

Coherence Scale of the Kondo Lattice
journal, July 2000

The seebeck coefficient of YbAl2 and YbAl3
journal, September 1974

Exchange Interaction in Alloys with Cerium Impurities
journal, September 1969

Thermoelectric power of Ce-based intermediate valent systems
journal, May 2006

Thermoelectric power of compounds with cerium: Influence of the crystalline field on the Kondo effect
journal, April 1976

Fermi-liquid instabilities at magnetic quantum phase transitions
journal, August 2007

Nature of the $5 f$ states in actinide metals
journal, February 2009

Large thermoelectric power in several metallic compounds of cerium and uranium
journal, December 2000

Plutonium-based superconductivity with a transition temperature above 18 K
journal, November 2002

Thermoelectric power of cerium and ytterbium intermetallics
journal, September 2003

Pressure dependence of the superconductivity in PuCoGa5
journal, May 2004

High-pressure transport properties of CeRu ₂ Ge ₂
journal, March 2005

Kondo Lattices and the Mott Metal–Insulator Transition
journal, January 2005

Superconducting and Magnetic Transitions in the Heavy-Fermion System U ${Ru}_{2}$ ${Si}_{2}$
journal, December 1985

Thermopower of Yb Heavy Fermion Compounds at High Pressure
journal, January 1999

Theory of the thermoelectricity of intermetallic compounds with Ce or Yb ions
journal, April 2005

The thermoelectric power of Kondo cerium and ytterbium compounds
journal, March 2002

Thermoelectric Materials, Phenomena, and Applications: A Bird's Eye View
journal, March 2006

Addendum: Non-Fermi-liquid behavior in $d$ - and $f$ -electron metals
journal, July 2006

Transport coefficients of intermediate valent CeNix intermetallic compounds
journal, February 1985

Electronic structure calculations with dynamical mean-field theory
journal, August 2006

Thermoelectrical power of heavy fermion compounds
journal, May 2006

Mixed valent metals
journal, July 2016

Avoided valence transition in a plutonium superconductor
journal, March 2015

Photoemission and the Electronic Structure of ${P u C o G a}_{5}$
journal, October 2003

Electronic structure and correlation effects in PuCoIn ₅ as compared to PuCoGa ₅
journal, February 2012

Anomalously large thermoelectric cooling figure of merit in the Kondo systems CePd ₃ and Celn ₃
journal, May 1973

Dependence of the CeNi5 thermoelectric power on strong 4f-electron instability
journal, July 2001

On the thermoelectricity of correlated electrons in the zero-temperature limit
journal, July 2004

Localization of magnetic moments of cerium in single crystalline $Ce {Pt}_{4} In$
journal, March 2006

Crystal electric field contribution to the thermoelectric power of the CeCoAl 4 antiferromagnetic
journal, December 2018