Highly Efficient and Uniform 1 cm2 Perovskite Solar Cells with an Electrochemically Deposited NiOx Hole-Extraction Layer
Abstract
Here, given that the highest certified conversion efficiency of the organic-inorganic perovskite solar cell (PSC) already exceeds 22%, which is even higher than that of the polycrystalline silicon solar cell, the significance of new scalable processes that can be utilized for preparing large-area devices and their commercialization is rapidly increasing. From this perspective, the electrodeposition method is one of the most suitable processes for preparing large-area devices because it is an already commercialized process with proven controllability and scalability. Here, a highly uniform NiOx layer prepared by electrochemical deposition is reported as an efficient hole-extraction layer of a p-i-n-type planar PSC with a large active area of >1 cm2. It is demonstrated that the increased surface roughness of the NiOx layer, achieved by controlling the deposition current density, facilitates the hole extraction at the interface between perovskite and NiOx, and thus increases the fill factor and the conversion efficiency. The electrochemically deposited NiOx layer also exhibits extremely uniform thickness and morphology, leading to highly efficient and uniform large-area PSCs. As a result, the p-i-n-type planar PSC with an area of 1.084 cm2 exhibits a stable conversion efficiency of 17.0% (19.2% for 0.1 cm2) without showing hysteresis effects.
- Authors:
-
- Seoul National Univ., Seoul (Republic of Korea)
- Pohang Univ. of Science and Technology (POSTECH), Gyeongbuk (Republic of Korea)
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Publication Date:
- Research Org.:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1369122
- Report Number(s):
- NREL/JA-5900-68709
Journal ID: ISSN 1864-5631
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemSusChem
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 12; Journal ID: ISSN 1864-5631
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY; 36 MATERIALS SCIENCE; charge extraction; electrochemical deposition; methylammonium lead halides; nickel oxides; solar cells
Citation Formats
Park, Ik Jae, Kang, Gyeongho, Park, Min Ah, Kim, Ju Seong, Seo, Se Won, Kim, Dong Hoe, Zhu, Kai, Park, Taiho, and Kim, Jin Young. Highly Efficient and Uniform 1 cm2 Perovskite Solar Cells with an Electrochemically Deposited NiOx Hole-Extraction Layer. United States: N. p., 2017.
Web. doi:10.1002/cssc.201700612.
Park, Ik Jae, Kang, Gyeongho, Park, Min Ah, Kim, Ju Seong, Seo, Se Won, Kim, Dong Hoe, Zhu, Kai, Park, Taiho, & Kim, Jin Young. Highly Efficient and Uniform 1 cm2 Perovskite Solar Cells with an Electrochemically Deposited NiOx Hole-Extraction Layer. United States. https://doi.org/10.1002/cssc.201700612
Park, Ik Jae, Kang, Gyeongho, Park, Min Ah, Kim, Ju Seong, Seo, Se Won, Kim, Dong Hoe, Zhu, Kai, Park, Taiho, and Kim, Jin Young. Wed .
"Highly Efficient and Uniform 1 cm2 Perovskite Solar Cells with an Electrochemically Deposited NiOx Hole-Extraction Layer". United States. https://doi.org/10.1002/cssc.201700612. https://www.osti.gov/servlets/purl/1369122.
@article{osti_1369122,
title = {Highly Efficient and Uniform 1 cm2 Perovskite Solar Cells with an Electrochemically Deposited NiOx Hole-Extraction Layer},
author = {Park, Ik Jae and Kang, Gyeongho and Park, Min Ah and Kim, Ju Seong and Seo, Se Won and Kim, Dong Hoe and Zhu, Kai and Park, Taiho and Kim, Jin Young},
abstractNote = {Here, given that the highest certified conversion efficiency of the organic-inorganic perovskite solar cell (PSC) already exceeds 22%, which is even higher than that of the polycrystalline silicon solar cell, the significance of new scalable processes that can be utilized for preparing large-area devices and their commercialization is rapidly increasing. From this perspective, the electrodeposition method is one of the most suitable processes for preparing large-area devices because it is an already commercialized process with proven controllability and scalability. Here, a highly uniform NiOx layer prepared by electrochemical deposition is reported as an efficient hole-extraction layer of a p-i-n-type planar PSC with a large active area of >1 cm2. It is demonstrated that the increased surface roughness of the NiOx layer, achieved by controlling the deposition current density, facilitates the hole extraction at the interface between perovskite and NiOx, and thus increases the fill factor and the conversion efficiency. The electrochemically deposited NiOx layer also exhibits extremely uniform thickness and morphology, leading to highly efficient and uniform large-area PSCs. As a result, the p-i-n-type planar PSC with an area of 1.084 cm2 exhibits a stable conversion efficiency of 17.0% (19.2% for 0.1 cm2) without showing hysteresis effects.},
doi = {10.1002/cssc.201700612},
journal = {ChemSusChem},
number = 12,
volume = 10,
place = {United States},
year = {Wed May 10 00:00:00 EDT 2017},
month = {Wed May 10 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Efficient Semitransparent Perovskite Solar Cells for 23.0%-Efficiency Perovskite/Silicon Four-Terminal Tandem Cells
journal, July 2016
- Chen, Bo; Bai, Yang; Yu, Zhengshan
- Advanced Energy Materials, Vol. 6, Issue 19
Self-formed grain boundary healing layer for highly efficient CH3NH3PbI3 perovskite solar cells
journal, June 2016
- Son, Dae-Yong; Lee, Jin-Wook; Choi, Yung Ji
- Nature Energy, Vol. 1, Issue 7
Synthesis, characterization, and electrochemical properties of ultrafine β-Ni(OH)2 nanoparticles
journal, July 2011
- Aghazadeh, Mustafa; Golikand, Ahmad Nozad; Ghaemi, Mehdi
- International Journal of Hydrogen Energy, Vol. 36, Issue 14
New Hybrid Hole Extraction Layer of Perovskite Solar Cells with a Planar p–i–n Geometry
journal, November 2015
- Park, Ik Jae; Park, Min Ah; Kim, Dong Hoe
- The Journal of Physical Chemistry C, Vol. 119, Issue 49
Perovskite solar cells with 18.21% efficiency and area over 1 cm2 fabricated by heterojunction engineering
journal, September 2016
- Wu, Yongzhen; Yang, Xudong; Chen, Wei
- Nature Energy, Vol. 1, Issue 11
The morphology and nucleation kinetics of copper islands during electrodeposition
journal, May 2006
- Radisic, A.; Vereecken, P. M.; Searson, P. C.
- Surface Science, Vol. 600, Issue 9
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009
- Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
- Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors
journal, May 2013
- Heo, Jin Hyuck; Im, Sang Hyuk; Noh, Jun Hong
- Nature Photonics, Vol. 7, Issue 6, p. 486-491
High-Performance Hole-Extraction Layer of Sol-Gel-Processed NiO Nanocrystals for Inverted Planar Perovskite Solar Cells
journal, July 2014
- Zhu, Zonglong; Bai, Yang; Zhang, Teng
- Angewandte Chemie, Vol. 126, Issue 46
Sequential Deposition of CH 3 NH 3 PbI 3 on Planar NiO Film for Efficient Planar Perovskite Solar Cells
journal, June 2014
- Hu, Long; Peng, Jun; Wang, Weiwei
- ACS Photonics, Vol. 1, Issue 7
Interface engineering of highly efficient perovskite solar cells
journal, July 2014
- Zhou, H.; Chen, Q.; Li, G.
- Science, Vol. 345, Issue 6196
Efficient CH 3 NH 3 PbI 3 Perovskite Solar Cells Employing Nanostructured p-Type NiO Electrode Formed by a Pulsed Laser Deposition
journal, June 2015
- Park, Jong Hoon; Seo, Jangwon; Park, Sangman
- Advanced Materials, Vol. 27, Issue 27
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange
journal, May 2015
- Yang, W. S.; Noh, J. H.; Jeon, N. J.
- Science, Vol. 348, Issue 6240
Monolithic Perovskite-CIGS Tandem Solar Cells via In Situ Band Gap Engineering
journal, September 2015
- Todorov, Teodor; Gershon, Talia; Gunawan, Oki
- Advanced Energy Materials, Vol. 5, Issue 23
An ultra-thin, un-doped NiO hole transporting layer of highly efficient (16.4%) organic–inorganic hybrid perovskite solar cells
journal, January 2016
- Seo, Seongrok; Park, Ik Jae; Kim, Myungjun
- Nanoscale, Vol. 8, Issue 22
Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells
journal, December 2014
- Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng
- Nature Communications, Vol. 5, Issue 1
Nickel Oxide Electrode Interlayer in CH 3 NH 3 PbI 3 Perovskite/PCBM Planar-Heterojunction Hybrid Solar Cells
journal, March 2014
- Jeng, Jun-Yuan; Chen, Kuo-Cheng; Chiang, Tsung-Yu
- Advanced Materials, Vol. 26, Issue 24
A Universal Method to Produce Low-Work Function Electrodes for Organic Electronics
journal, April 2012
- Zhou, Y.; Fuentes-Hernandez, C.; Shim, J.
- Science, Vol. 336, Issue 6079, p. 327-332
Morphology and Microstructure in Electrochemical Deposition of Zinc
journal, March 1986
- Grier, D.; Ben-Jacob, E.; Clarke, Roy
- Physical Review Letters, Vol. 56, Issue 12
Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
journal, January 2016
- Saliba, Michael; Matsui, Taisuke; Seo, Ji-Youn
- Energy & Environmental Science, Vol. 9, Issue 6
Electronic Level Alignment in Inverted Organometal Perovskite Solar Cells
journal, March 2015
- Schulz, Philip; Whittaker-Brooks, Luisa L.; MacLeod, Bradley A.
- Advanced Materials Interfaces, Vol. 2, Issue 7
Hysteresis-less inverted CH 3 NH 3 PbI 3 planar perovskite hybrid solar cells with 18.1% power conversion efficiency
journal, January 2015
- Heo, Jin Hyuck; Han, Hye Ji; Kim, Dasom
- Energy & Environmental Science, Vol. 8, Issue 5
Electrodeposition of copper: the nucleation mechanisms
journal, July 2002
- Grujicic, Darko; Pesic, Batric
- Electrochimica Acta, Vol. 47, Issue 18
A Hierarchically Structured Ni(OH) 2 Monolayer Hollow-Sphere Array and Its Tunable Optical Properties over a Large Region
journal, January 2007
- Duan, G.; Cai, W.; Luo, Y.
- Advanced Functional Materials, Vol. 17, Issue 4
Preparation and characterization of spray pyrolyzed nickel oxide (NiO) thin films
journal, October 2002
- Patil, P. S.; Kadam, L. D.
- Applied Surface Science, Vol. 199, Issue 1-4, p. 211-221
A vacuum flash–assisted solution process for high-efficiency large-area perovskite solar cells
journal, June 2016
- Li, Xiong; Bi, Dongqin; Yi, Chenyi
- Science, Vol. 353, Issue 6294
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012
- Lee, M. M.; Teuscher, J.; Miyasaka, T.
- Science, Vol. 338, Issue 6107, p. 643-647
Nickel hydroxide electrodeposition from nickel nitrate solutions: mechanistic studies
journal, February 2001
- Jayashree, R. S.; Kamath, P. Vishnu
- Journal of Power Sources, Vol. 93, Issue 1-2
Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells
journal, July 2015
- Bi, Cheng; Wang, Qi; Shao, Yuchuan
- Nature Communications, Vol. 6, Issue 1
Perovskite-kesterite monolithic tandem solar cells with high open-circuit voltage
journal, October 2014
- Todorov, Teodor; Gershon, Talia; Gunawan, Oki
- Applied Physics Letters, Vol. 105, Issue 17
Nickel hydroxide powder for NiO·OH/Ni(OH)2 electrodes of the alkaline batteries
journal, February 2001
- Freitas, M. B. J. G.
- Journal of Power Sources, Vol. 93, Issue 1-2
Highly Efficient Flexible Perovskite Solar Cells Using Solution-Derived NiO x Hole Contacts
journal, February 2016
- Yin, Xingtian; Chen, Peng; Que, Meidan
- ACS Nano, Vol. 10, Issue 3
Nanostructured mesoporous nickel oxide thin films
journal, February 2007
- Sasi, B.; Gopchandran, K. G.
- Nanotechnology, Vol. 18, Issue 11
Compositional engineering of perovskite materials for high-performance solar cells
journal, January 2015
- Jeon, Nam Joong; Noh, Jun Hong; Yang, Woon Seok
- Nature, Vol. 517, Issue 7535
Low-Temperature Sputtered Nickel Oxide Compact Thin Film as Effective Electron Blocking Layer for Mesoscopic NiO/CH 3 NH 3 PbI 3 Perovskite Heterojunction Solar Cells
journal, July 2014
- Wang, Kuo-Chin; Shen, Po-Shen; Li, Ming-Hsien
- ACS Applied Materials & Interfaces, Vol. 6, Issue 15
High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015
- Nie, W.; Tsai, H.; Asadpour, R.
- Science, Vol. 347, Issue 6221, p. 522-525
Solution-Processible Crystalline NiO Nanoparticles for High-Performance Planar Perovskite Photovoltaic Cells
journal, July 2016
- Kwon, Uisik; Kim, Bong-Gi; Nguyen, Duc Cuong
- Scientific Reports, Vol. 6, Issue 1
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%
journal, August 2012
- Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok
- Scientific Reports, Vol. 2, Issue 1
Works referencing / citing this record:
A Review of Perovskites Solar Cell Stability
journal, February 2019
- Wang, Rui; Mujahid, Muhammad; Duan, Yu
- Advanced Functional Materials, Vol. 29, Issue 47
Improving the Performance and Stability of Inverted Planar Flexible Perovskite Solar Cells Employing a Novel NDI-Based Polymer as the Electron Transport Layer
journal, February 2018
- Kim, Hong Il; Kim, Myeong-Jong; Choi, Kyoungwon
- Advanced Energy Materials, Vol. 8, Issue 16
Nickel Oxide as Efficient Hole Transport Materials for Perovskite Solar Cells
journal, March 2019
- Yin, Xingtian; Guo, Yuxiao; Xie, Haixia
- Solar RRL, Vol. 3, Issue 5
Efficient Inverted Planar Perovskite Solar Cells Using Ultraviolet/Ozone‐Treated NiO x as the Hole Transport Layer
journal, March 2019
- Wang, Tun; Ding, Dong; Zheng, Hao
- Solar RRL, Vol. 3, Issue 6
Scalable fabrication of perovskite solar cells
journal, March 2018
- Li, Zhen; Klein, Talysa R.; Kim, Dong Hoe
- Nature Reviews Materials, Vol. 3, Issue 4
Large-area, green solvent spray deposited nickel oxide films for scalable fabrication of triple-cation perovskite solar cells
journal, January 2020
- Kumar, Neetesh; Lee, Hock Beng; Hwang, Sunbin
- Journal of Materials Chemistry A, Vol. 8, Issue 6
A facile and controllable electrochemically fabricated nonstoichiometric MoO x film for novel opto-electronic devices
journal, May 2019
- Zeng, Ranran; Liu, Hong; Shen, Wenzhong
- Journal of Micromechanics and Microengineering, Vol. 29, Issue 6
Analysing the Prospects of Perovskite Solar Cells within the Purview of Recent Scientific Advancements
journal, June 2018
- Bhat, Aakash; Dhamaniya, Bhanu; Chhillar, Priyanka
- Crystals, Vol. 8, Issue 6
Electrochemically Deposited NiO Films as a Blocking Layer in p-Type Dye-Sensitized Solar Cells with an Impressive 45% Fill Factor
journal, January 2020
- Bonomo, Matteo; Di Girolamo, Diego; Piccinni, Marco
- Nanomaterials, Vol. 10, Issue 1