Long-range stripe nanodomains in epitaxial (110) BiFeO3 thin films on (100) NdGaO3 substrate

Sharma, Yogesh; Agarwal, Radhe; Phatak, Charudatta; Kim, Bumsoo; Jeon, Seokwoo; Katiyar, Ram S.; Hong, Seungbum

doi:10.1038/s41598-017-05055-z

Title: Long-range stripe nanodomains in epitaxial (110) BiFeO₃ thin films on (100) NdGaO₃ substrate

Abstract

Here, we report the observation of ferroelectric and ferroelastic nanodomains in (110)-oriented BiFeO₃ (BFO) thin films epitaxially grown on low symmetric (100) NdGaO₃ (NGO) substrate. We observed long range ordering of ferroelectric 109° stripe nanodomains separated by periodic vertical domain walls in as-grown 130 nm thick BFO films. The effect of La_0.67Sr_0.33CoO₃ (LSCO) conducting interlayer on domain configurations in BFO/NGO film was also observed with relatively short range-ordering of stripe domains due to the modified electrostatic boundary conditions in BFO/LSCO/NGO film. Additional studies on B-site doping of Nb ions in BFO films showed change in the domain structures due to doping induced change in lattice anisotropy while maintaining the stripe domain morphology with 109° domain wall. Finally, this long-range array of ferroelectric and ferroelastic domains can be useful for optoelectronic devices and ferroelastic templates for strain coupled artificial magnetoelectric heterostructures.

Authors:

Sharma, Yogesh ^[1]; Agarwal, Radhe ^[2];

^[3]; Kim, Bumsoo ^[4]; Jeon, Seokwoo ^[5]; Katiyar, Ram S. ^[2];

^[4]

Argonne National Lab. (ANL), Lemont, IL (United States); Univ. of Puerto Rico, San Juan, PR (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Puerto Rico, San Juan, PR (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States); KAIST, Daejeon (Korea)
KAIST, Daejeon (Korea)

Publication Date:: Fri Jul 07 00:00:00 EDT 2017

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Materials Sciences and Engineering Division

OSTI Identifier:: 1369036

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; ferroelectrics and multiferroics; nanoscale materials

Citation Formats


                    Sharma, Yogesh, Agarwal, Radhe, Phatak, Charudatta, Kim, Bumsoo, Jeon, Seokwoo, Katiyar, Ram S., and Hong, Seungbum. Long-range stripe nanodomains in epitaxial (110) BiFeO3 thin films on (100) NdGaO3 substrate.  United States: N. p., 2017. 
Web.  doi:10.1038/s41598-017-05055-z.

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                    Sharma, Yogesh, Agarwal, Radhe, Phatak, Charudatta, Kim, Bumsoo, Jeon, Seokwoo, Katiyar, Ram S., & Hong, Seungbum. Long-range stripe nanodomains in epitaxial (110) BiFeO3 thin films on (100) NdGaO3 substrate.  United States.  https://doi.org/10.1038/s41598-017-05055-z

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                    Sharma, Yogesh, Agarwal, Radhe, Phatak, Charudatta, Kim, Bumsoo, Jeon, Seokwoo, Katiyar, Ram S., and Hong, Seungbum. Fri .  
"Long-range stripe nanodomains in epitaxial (110) BiFeO3 thin films on (100) NdGaO3 substrate".  United States.  https://doi.org/10.1038/s41598-017-05055-z.  https://www.osti.gov/servlets/purl/1369036.

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@article{osti_1369036,

  title        = {Long-range stripe nanodomains in epitaxial (110) BiFeO3 thin films on (100) NdGaO3 substrate},

  author       = {Sharma, Yogesh and Agarwal, Radhe and Phatak, Charudatta and Kim, Bumsoo and Jeon, Seokwoo and Katiyar, Ram S. and Hong, Seungbum},

  abstractNote = {Here, we report the observation of ferroelectric and ferroelastic nanodomains in (110)-oriented BiFeO3 (BFO) thin films epitaxially grown on low symmetric (100) NdGaO3 (NGO) substrate. We observed long range ordering of ferroelectric 109° stripe nanodomains separated by periodic vertical domain walls in as-grown 130 nm thick BFO films. The effect of La0.67Sr0.33CoO3 (LSCO) conducting interlayer on domain configurations in BFO/NGO film was also observed with relatively short range-ordering of stripe domains due to the modified electrostatic boundary conditions in BFO/LSCO/NGO film. Additional studies on B-site doping of Nb ions in BFO films showed change in the domain structures due to doping induced change in lattice anisotropy while maintaining the stripe domain morphology with 109° domain wall. Finally, this long-range array of ferroelectric and ferroelastic domains can be useful for optoelectronic devices and ferroelastic templates for strain coupled artificial magnetoelectric heterostructures.},

  doi          = {10.1038/s41598-017-05055-z},

  journal      = {Scientific Reports},

  number       = 1,

  volume       = 7,

  place        = {United States},

  year         = {Fri Jul 07 00:00:00 EDT 2017},

  month        = {Fri Jul 07 00:00:00 EDT 2017}

}

Copy to clipboard

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Title: Long-range stripe nanodomains in epitaxial (110) BiFeO3 thin films on (100) NdGaO3 substrate

Abstract

Citation Formats

MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics journal, July 2005

Spontaneous Vortex Nanodomain Arrays at Ferroelectric Heterointerfaces journal, February 2011

Three-dimensional ferroelectric domain imaging of epitaxial BiFeO3 thin films using angle-resolved piezoresponse force microscopy journal, September 2010

Towards a magnetoelectric memory journal, June 2008

Studies of the switchable photovoltaic effect in co-substituted BiFeO3 thin films journal, October 2014

Reliable polarization switching of BiFeO 3 journal, October 2012

Observation of Nanoscale 180 ° Stripe Domains in Ferroelectric P b T i O 3 Thin Films journal, July 2002

Ferroelastic switching for nanoscale non-volatile magnetoelectric devices journal, February 2010

Switchable photovoltaic and polarization modulated rectification in Si-integrated Pt/(Bi0.9Sm0.1)(Fe0.97Hf0.03)O3/LaNiO3 heterostructures journal, October 2015

Nanoscale Control of Domain Architectures in BiFeO 3 Thin Films journal, April 2009

Imaging Ferroelectric Domains and Domain Walls Using Charge Gradient Microscopy: Role of Screening Charges journal, January 2016

Depolarization corrections to the coercive field in thin-film ferroelectrics journal, June 2003

Effect of lanthanum doping on tetragonal-like BiFe O 3 with mixed-phase domain structures journal, October 2014

The crystal structure of NdGaO3 at 100 K and 293 K based on synchrotron data journal, February 2000

Domain patterns in epitaxial rhombohedral ferroelectric films. I. Geometry and experiments journal, March 1998

Charge gradient microscopy journal, April 2014

Domain Selectivity in BiFeO 3 Thin Films by Modified Substrate Termination journal, March 2016

Epitaxial strain and electric boundary condition effects on the structural and ferroelectric properties of BiFeO 3 films journal, September 2011

Physics and Applications of Bismuth Ferrite journal, June 2009

Interfacial charge and strain effects on the ferroelectric behavior of epitaxial (001) PbTiO 3 films on (110) DyScO 3 substrates journal, March 2014

Domain wall nanoelectronics journal, February 2012

Lattice effects on magnetic and transport properties in La site doping La0.67Sr0.33CoO3 journal, December 2005

Growth of highly resistive BiMnO3 films journal, September 2005

Deterministic switching of ferromagnetism at room temperature using an electric field journal, December 2014

180° Ferroelectric Stripe Nanodomains in BiFeO 3 Thin Films journal, September 2015

Improved ferroelectric properties in multiferroic Bi Fe O 3 thin films through La and Nb codoping journal, March 2008

Equilibrium structure of epitaxial layers journal, September 1976

Multiferroic and magnetoelectric materials journal, August 2006

Screening mechanisms at polar oxide heterointerfaces journal, June 2016

Domain Selectivity in BiFeO 3 Thin Films by Modified Substrate Termination journal, March 2016

Physics and Applications of Bismuth Ferrite journal, June 2009

Lattice effects on magnetic and transport properties in La site doping La0.67Sr0.33CoO3 journal, December 2005

180° Ferroelectric Stripe Nanodomains in BiFeO 3 Thin Films journal, September 2015

Imaging Ferroelectric Domains and Domain Walls Using Charge Gradient Microscopy: Role of Screening Charges journal, January 2016

Nanoscale Control of Domain Architectures in BiFeO 3 Thin Films journal, April 2009

Deterministic switching of ferromagnetism at room temperature using an electric field journal, December 2014

Towards a magnetoelectric memory journal, June 2008

Ferroelastic switching for nanoscale non-volatile magnetoelectric devices journal, February 2010

Growth of highly resistive BiMnO3 films journal, September 2005

Three-dimensional ferroelectric domain imaging of epitaxial BiFeO3 thin films using angle-resolved piezoresponse force microscopy journal, September 2010

Domain patterns in epitaxial rhombohedral ferroelectric films. I. Geometry and experiments journal, March 1998

Interfacial charge and strain effects on the ferroelectric behavior of epitaxial (001) PbTiO 3 films on (110) DyScO 3 substrates journal, March 2014

Studies of the switchable photovoltaic effect in co-substituted BiFeO3 thin films journal, October 2014

Switchable photovoltaic and polarization modulated rectification in Si-integrated Pt/(Bi0.9Sm0.1)(Fe0.97Hf0.03)O3/LaNiO3 heterostructures journal, October 2015

Screening mechanisms at polar oxide heterointerfaces journal, June 2016

Depolarization corrections to the coercive field in thin-film ferroelectrics journal, June 2003

Reliable polarization switching of BiFeO 3 journal, October 2012

Raman spectroscopy of single-domain multiferroic BiFeO 3 journal, February 2010

MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics journal, July 2005

Converse flexoelectricity around ferroelastic domain walls preprint, January 2019

Revealing the Interplay of Structural Phase Transitions and Ferroelectric Switching in Mixed Phase BiFeO 3 journal, October 2018

Ionic Gating of Ultrathin and Leaky Ferroelectrics journal, January 2019

Tuning Effective Spin Hall Angles via Oxygen Vacancies in Multiferroic BiFeO 3 ‐Based Heterostructures journal, August 2019

Thermooptical evidence of carrier-stabilized ferroelectricity in ultrathin electrodeless films journal, May 2018

Structural, magnetic, and ferroelectric properties of T-like cobalt-doped BiFeO 3 thin films journal, February 2018

Large modulation of perpendicular magnetic anisotropy in a BiFeO 3 /Al 2 O 3 /Pt/Co/Pt multiferroic heterostructure via spontaneous polarizations journal, August 2018

Self-assembly and properties of domain walls in BiFeO 3 layers grown via molecular-beam epitaxy journal, July 2019

Cobalt doping of bismuth ferrite for matched dielectric and magnetic loss journal, November 2019

High-temperature Magnetodielectric Bi ( Fe 0.5 Mn 0.5 ) O 3 Thin Films with Checkerboard-Ordered Oxygen Vacancies and Low Magnetic Damping journal, November 2018

Thermooptical evidence of carrier-stabilized ferroelectricity in ultrathin electrodeless films journal, May 2018

Title: Long-range stripe nanodomains in epitaxial (110) BiFeO₃ thin films on (100) NdGaO₃ substrate

MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics
journal, July 2005

Spontaneous Vortex Nanodomain Arrays at Ferroelectric Heterointerfaces
journal, February 2011

Three-dimensional ferroelectric domain imaging of epitaxial BiFeO3 thin films using angle-resolved piezoresponse force microscopy
journal, September 2010

Towards a magnetoelectric memory
journal, June 2008

Studies of the switchable photovoltaic effect in co-substituted BiFeO3 thin films
journal, October 2014

Reliable polarization switching of BiFeO ₃
journal, October 2012

Observation of Nanoscale $180 °$ Stripe Domains in Ferroelectric ${P b T i O}_{3}$ Thin Films
journal, July 2002

Ferroelastic switching for nanoscale non-volatile magnetoelectric devices
journal, February 2010

Switchable photovoltaic and polarization modulated rectification in Si-integrated Pt/(Bi0.9Sm0.1)(Fe0.97Hf0.03)O3/LaNiO3 heterostructures
journal, October 2015

Nanoscale Control of Domain Architectures in BiFeO ₃ Thin Films
journal, April 2009

Imaging Ferroelectric Domains and Domain Walls Using Charge Gradient Microscopy: Role of Screening Charges
journal, January 2016

Depolarization corrections to the coercive field in thin-film ferroelectrics
journal, June 2003

Effect of lanthanum doping on tetragonal-like $BiFe O_{3}$ with mixed-phase domain structures
journal, October 2014

The crystal structure of NdGaO3 at 100 K and 293 K based on synchrotron data
journal, February 2000

Domain patterns in epitaxial rhombohedral ferroelectric films. I. Geometry and experiments
journal, March 1998

Charge gradient microscopy
journal, April 2014

Domain Selectivity in BiFeO ₃ Thin Films by Modified Substrate Termination
journal, March 2016

Epitaxial strain and electric boundary condition effects on the structural and ferroelectric properties of BiFeO $_{3}$ films
journal, September 2011

Physics and Applications of Bismuth Ferrite
journal, June 2009

Interfacial charge and strain effects on the ferroelectric behavior of epitaxial (001) PbTiO ₃ films on (110) DyScO ₃ substrates
journal, March 2014

Domain wall nanoelectronics
journal, February 2012

Lattice effects on magnetic and transport properties in La site doping La0.67Sr0.33CoO3
journal, December 2005

Growth of highly resistive BiMnO3 films
journal, September 2005

Deterministic switching of ferromagnetism at room temperature using an electric field
journal, December 2014

180° Ferroelectric Stripe Nanodomains in BiFeO ₃ Thin Films
journal, September 2015

Improved ferroelectric properties in multiferroic $Bi Fe O_{3}$ thin films through La and Nb codoping
journal, March 2008

Equilibrium structure of epitaxial layers
journal, September 1976

Multiferroic and magnetoelectric materials
journal, August 2006

Screening mechanisms at polar oxide heterointerfaces
journal, June 2016

Domain Selectivity in BiFeO ₃ Thin Films by Modified Substrate Termination
journal, March 2016

Physics and Applications of Bismuth Ferrite
journal, June 2009

Lattice effects on magnetic and transport properties in La site doping La0.67Sr0.33CoO3
journal, December 2005

180° Ferroelectric Stripe Nanodomains in BiFeO ₃ Thin Films
journal, September 2015

Imaging Ferroelectric Domains and Domain Walls Using Charge Gradient Microscopy: Role of Screening Charges
journal, January 2016

Nanoscale Control of Domain Architectures in BiFeO ₃ Thin Films
journal, April 2009

Deterministic switching of ferromagnetism at room temperature using an electric field
journal, December 2014

Towards a magnetoelectric memory
journal, June 2008

Ferroelastic switching for nanoscale non-volatile magnetoelectric devices
journal, February 2010

Growth of highly resistive BiMnO3 films
journal, September 2005

Three-dimensional ferroelectric domain imaging of epitaxial BiFeO3 thin films using angle-resolved piezoresponse force microscopy
journal, September 2010

Domain patterns in epitaxial rhombohedral ferroelectric films. I. Geometry and experiments
journal, March 1998

Interfacial charge and strain effects on the ferroelectric behavior of epitaxial (001) PbTiO ₃ films on (110) DyScO ₃ substrates
journal, March 2014

Studies of the switchable photovoltaic effect in co-substituted BiFeO3 thin films
journal, October 2014

Switchable photovoltaic and polarization modulated rectification in Si-integrated Pt/(Bi0.9Sm0.1)(Fe0.97Hf0.03)O3/LaNiO3 heterostructures
journal, October 2015

Screening mechanisms at polar oxide heterointerfaces
journal, June 2016

Depolarization corrections to the coercive field in thin-film ferroelectrics
journal, June 2003

Reliable polarization switching of BiFeO ₃
journal, October 2012

Raman spectroscopy of single-domain multiferroic ${BiFeO}_{3}$
journal, February 2010

MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics
journal, July 2005

Converse flexoelectricity around ferroelastic domain walls
preprint, January 2019

Revealing the Interplay of Structural Phase Transitions and Ferroelectric Switching in Mixed Phase BiFeO ₃
journal, October 2018

Ionic Gating of Ultrathin and Leaky Ferroelectrics
journal, January 2019

Tuning Effective Spin Hall Angles via Oxygen Vacancies in Multiferroic BiFeO ₃ ‐Based Heterostructures
journal, August 2019

Thermooptical evidence of carrier-stabilized ferroelectricity in ultrathin electrodeless films
journal, May 2018

Structural, magnetic, and ferroelectric properties of T-like cobalt-doped BiFeO ₃ thin films
journal, February 2018

Large modulation of perpendicular magnetic anisotropy in a BiFeO ₃ /Al ₂ O ₃ /Pt/Co/Pt multiferroic heterostructure via spontaneous polarizations
journal, August 2018

Self-assembly and properties of domain walls in BiFeO ₃ layers grown via molecular-beam epitaxy
journal, July 2019

Cobalt doping of bismuth ferrite for matched dielectric and magnetic loss
journal, November 2019

High-temperature Magnetodielectric $Bi ({Fe}_{0.5} {Mn}_{0.5}) O_{3}$ Thin Films with Checkerboard-Ordered Oxygen Vacancies and Low Magnetic Damping
journal, November 2018

Thermooptical evidence of carrier-stabilized ferroelectricity in ultrathin electrodeless films
journal, May 2018