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Title: Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]

Abstract

In situ high energy X-ray diffraction (HEXRD) and in situ X-ray absorption near edge spectroscopy (XANES) were carried out to understand the soild state synthesis of NaxMnO2, with particular interest on the synthesis of P2 type Na2/3MnO2. It was found that there were multi intermediate phases formed before NaMnO2 appeared at about 600 °C. And the final product after cooling process is a combination of O'3 NaMnO2 with P2 Na2/3MnO2. A P2 type Na2/3MnO2 was synthesized at reduced temperature (600 °C). The influence of Na2CO3 impurity on the electrochemical performance of P2 Na2/3MnO2 was thoroughly investigated in our work. It was found that the content of Na2CO3 can be reduced by optimizing Na2CO3/MnCO3 ratio during the solid state reaction or other post treatment such as washing with water. Lastly, we expected our results could provide a good guide for future development of high performance cathode materials for sodium-ion batteries.

Authors:
 [1];  [2];  [2];  [2];  [2];  [2];  [2];  [3];  [2];  [2]
+ Show Author Affiliations
  1. Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Rochester, Rochester, NY (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Univ. of Rochester, Rochester, NY (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
OSTI Identifier:
1369033
Alternate Identifier(s):
OSTI ID: 1397470
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Power Sources
Additional Journal Information:
Journal Volume: 341; Journal Issue: C; Journal ID: ISSN 0378-7753
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE; in situ XANES; P2 type Na2/3MnO2; in situ HEXRD; ion battery; sodium deficiency; solid-state synthesis

Citation Formats

Ma, Tianyuan, Xu, Gui -Liang, Zeng, Xiaoqiao, Li, Yan, Ren, Yang, Sun, Chengjun, Heald, Steve M., Jorne, Jacob, Amine, Khalil, and Chen, Zonghai. Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]. United States: N. p., 2016. Web. doi:10.1016/j.jpowsour.2016.11.022.
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Ma, Tianyuan, Xu, Gui -Liang, Zeng, Xiaoqiao, Li, Yan, Ren, Yang, Sun, Chengjun, Heald, Steve M., Jorne, Jacob, Amine, Khalil, & Chen, Zonghai. Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]. United States. https://doi.org/10.1016/j.jpowsour.2016.11.022
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Ma, Tianyuan, Xu, Gui -Liang, Zeng, Xiaoqiao, Li, Yan, Ren, Yang, Sun, Chengjun, Heald, Steve M., Jorne, Jacob, Amine, Khalil, and Chen, Zonghai. Wed . "Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]". United States. https://doi.org/10.1016/j.jpowsour.2016.11.022. https://www.osti.gov/servlets/purl/1369033.
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@article{osti_1369033,
title = {Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]},
author = {Ma, Tianyuan and Xu, Gui -Liang and Zeng, Xiaoqiao and Li, Yan and Ren, Yang and Sun, Chengjun and Heald, Steve M. and Jorne, Jacob and Amine, Khalil and Chen, Zonghai},
abstractNote = {In situ high energy X-ray diffraction (HEXRD) and in situ X-ray absorption near edge spectroscopy (XANES) were carried out to understand the soild state synthesis of NaxMnO2, with particular interest on the synthesis of P2 type Na2/3MnO2. It was found that there were multi intermediate phases formed before NaMnO2 appeared at about 600 °C. And the final product after cooling process is a combination of O'3 NaMnO2 with P2 Na2/3MnO2. A P2 type Na2/3MnO2 was synthesized at reduced temperature (600 °C). The influence of Na2CO3 impurity on the electrochemical performance of P2 Na2/3MnO2 was thoroughly investigated in our work. It was found that the content of Na2CO3 can be reduced by optimizing Na2CO3/MnCO3 ratio during the solid state reaction or other post treatment such as washing with water. Lastly, we expected our results could provide a good guide for future development of high performance cathode materials for sodium-ion batteries.},
doi = {10.1016/j.jpowsour.2016.11.022},
journal = {Journal of Power Sources},
number = C,
volume = 341,
place = {United States},
year = {Wed Dec 07 00:00:00 EST 2016},
month = {Wed Dec 07 00:00:00 EST 2016}
}
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Works referenced in this record:

Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012

  • Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
  • Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
  • DOI: 10.1002/aenm.201200026

Sodium-Ion Batteries
journal, May 2012

  • Slater, Michael D.; Kim, Donghan; Lee, Eungje
  • Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
  • DOI: 10.1002/adfm.201200691

Structural classification and properties of the layered oxides
journal, January 1980

An advanced cathode for Na-ion batteries with high rate and excellent structural stability
journal, January 2013

  • Lee, Dae Hoe; Xu, Jing; Meng, Ying Shirley
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 9
  • DOI: 10.1039/c2cp44467d

Synthesis and electrochemical behaviors of layered Na0.67[Mn0.65Co0.2Ni0.15]O2 microflakes as a stable cathode material for sodium-ion batteries
journal, January 2013

  • Yuan, Dingding; He, Wei; Pei, Feng
  • Journal of Materials Chemistry A, Vol. 1, Issue 12
  • DOI: 10.1039/c3ta01430d

Layered Na[Ni1/3Fe1/3Mn1/3]O2 cathodes for Na-ion battery application
journal, January 2012

Na 0.67 Mn 1−x Mg x O 2 (0 ≤ x ≤ 0.2): a high capacity cathode for sodium-ion batteries
journal, January 2014

  • Billaud, Juliette; Singh, Gurpreet; Armstrong, A. Robert
  • Energy Environ. Sci., Vol. 7, Issue 4
  • DOI: 10.1039/C4EE00465E

P2-type Na 0.66 Ni 0.33–x Zn x Mn 0.67 O 2 as new high-voltage cathode materials for sodium-ion batteries
journal, May 2015

High-Performance P2-Type Na 2/3 (Mn 1/2 Fe 1/4 Co 1/4 )O 2 Cathode Material with Superior Rate Capability for Na-Ion Batteries
journal, September 2015

Sur quelques nouvelles phases de formule NaxMnO2 (x ⩽ 1)
journal, February 1971

  • Parant, Jean-Paul; Olazcuaga, Roger; Devalette, Michel
  • Journal of Solid State Chemistry, Vol. 3, Issue 1
  • DOI: 10.1016/0022-4596(71)90001-6

Sodium and Manganese Stoichiometry of P2-Type Na 2/3 MnO 2
journal, September 2016

  • Kumakura, Shinichi; Tahara, Yoshiyuki; Kubota, Kei
  • Angewandte Chemie International Edition, Vol. 55, Issue 41
  • DOI: 10.1002/anie.201606415

Solid state synthesis of LiFePO4 studied by in situ high energy X-ray diffraction
journal, January 2011

  • Chen, Zonghai; Ren, Yang; Qin, Yan
  • Journal of Materials Chemistry, Vol. 21, Issue 15
  • DOI: 10.1039/c0jm04049e

Formation of Li2MnO3 investigated by in situ synchrotron probes
journal, November 2014

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

Synthesis of full concentration gradient cathode studied by high energy X-ray diffraction
journal, January 2016

Structure and reversible lithium intercalation in a new P′3-phase: Na2/3Mn1−yFeyO2 (y = 0, 1/3, 2/3)
journal, January 2012

  • Yoncheva, M.; Stoyanova, R.; Zhecheva, E.
  • Journal of Materials Chemistry, Vol. 22, Issue 44
  • DOI: 10.1039/c2jm35203f

β-NaMnO 2 : A High-Performance Cathode for Sodium-Ion Batteries
journal, November 2014

  • Billaud, Juliette; Clément, Raphaële J.; Armstrong, A. Robert
  • Journal of the American Chemical Society, Vol. 136, Issue 49
  • DOI: 10.1021/ja509704t

Local Atomic Arrangement and Electronic Structure of Nanocrystalline Transition Metal Oxides Determined by X-ray Absorption Spectroscopy
journal, June 2003

  • Hwang, Seong-Ju; Choy, Jin-Ho
  • The Journal of Physical Chemistry B, Vol. 107, Issue 24
  • DOI: 10.1021/jp034049d

In Situ Mn K-edge X-ray Absorption Spectroscopy Studies of Electrodeposited Manganese Oxide Films for Electrochemical Capacitors
journal, January 2007

  • Nam, Kyung-Wan; Kim, Min Gyu; Kim, Kwang-Bum
  • The Journal of Physical Chemistry C, Vol. 111, Issue 2
  • DOI: 10.1021/jp063130o

Review—Manganese-Based P2-Type Transition Metal Oxides as Sodium-Ion Battery Cathode Materials
journal, January 2015

  • Clément, Raphaële J.; Bruce, Peter G.; Grey, Clare P.
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0201514jes

A Comparative Study of Layered Transition Metal Oxide Cathodes for Application in Sodium-Ion Battery
journal, February 2015

  • Hasa, Ivana; Buchholz, Daniel; Passerini, Stefano
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 9
  • DOI: 10.1021/am5080437

Water sensitivity of layered P2/P3-Na x Ni 0.22 Co 0.11 Mn 0.66 O 2 cathode material
journal, January 2014

  • Buchholz, Daniel; Chagas, Luciana Gomes; Vaalma, Christoph
  • J. Mater. Chem. A, Vol. 2, Issue 33
  • DOI: 10.1039/C4TA02627F

Thermal and carbothermic decomposition of Na2CO3 and Li2CO3
journal, February 2001

Electrochemical investigation of the P2–NaxCoO2 phase diagram
journal, December 2010

  • Berthelot, R.; Carlier, D.; Delmas, C.
  • Nature Materials, Vol. 10, Issue 1
  • DOI: 10.1038/nmat2920
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    Works referencing / citing this record:

    Challenges in Developing Electrodes, Electrolytes, and Diagnostics Tools to Understand and Advance Sodium-Ion Batteries
    journal, February 2018

    • Xu, Gui-Liang; Amine, Rachid; Abouimrane, Ali
    • Advanced Energy Materials, Vol. 8, Issue 14
    • DOI: 10.1002/aenm.201702403

    Excellent cyclability of P2-type Na–Co–Mn–Si–O cathode material for high-rate sodium-ion batteries
    journal, July 2019

    A Novel Graphene Oxide Wrapped Na 2 Fe 2 (SO 4 ) 3 /C Cathode Composite for Long Life and High Energy Density Sodium-Ion Batteries
    journal, August 2018

    • Chen, Mingzhe; Cortie, David; Hu, Zhe
    • Advanced Energy Materials, Vol. 8, Issue 27
    • DOI: 10.1002/aenm.201800944

    Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: status, challenges and countermeasures
    journal, January 2019

    • Wang, Shenghan; Sun, Chenglin; Wang, Ning
    • Journal of Materials Chemistry A, Vol. 7, Issue 17
    • DOI: 10.1039/c8ta12441h
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