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Title: Material and device properties of superacid-treated monolayer molybdenum disulfide

Here, we study the effects of chemical treatment with bis(trifluoromethane) sulfonimide superacid on material and device properties of monolayer molybdenum disulfide grown by chemical vapor deposition. Our spatially resolved photoluminescence (PL) measurements and device studies reveal two key findings due to the chemical treatment: (1) noticeable transformation of trions to neutral excitons, and (2) over 7-fold reduction in the density of mid-gap trap states. Specifically, a combination of scanning Auger microscopy and PL mapping reveals that the superacid treatment is effective in passivating the sulfur-deficient regions.
Authors:
 [1] ;  [2] ;  [1]
  1. New York Univ., Brooklyn, NY (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Report Number(s):
BNL-113995-2017-JA
Journal ID: ISSN 0003-6951; APPLAB; R&D Project: 16080; KC0403020
Grant/Contract Number:
SC00112704; SC0012704
Type:
Accepted Manuscript
Journal Name:
Applied Physics Letters
Additional Journal Information:
Journal Volume: 110; Journal Issue: 3; Journal ID: ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)
Research Org:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE
OSTI Identifier:
1368668
Alternate Identifier(s):
OSTI ID: 1361739

Alharbi, Abdullah, Zahl, Percy, and Shahrjerdi, Davood. Material and device properties of superacid-treated monolayer molybdenum disulfide. United States: N. p., Web. doi:10.1063/1.4974046.
Alharbi, Abdullah, Zahl, Percy, & Shahrjerdi, Davood. Material and device properties of superacid-treated monolayer molybdenum disulfide. United States. doi:10.1063/1.4974046.
Alharbi, Abdullah, Zahl, Percy, and Shahrjerdi, Davood. 2017. "Material and device properties of superacid-treated monolayer molybdenum disulfide". United States. doi:10.1063/1.4974046. https://www.osti.gov/servlets/purl/1368668.
@article{osti_1368668,
title = {Material and device properties of superacid-treated monolayer molybdenum disulfide},
author = {Alharbi, Abdullah and Zahl, Percy and Shahrjerdi, Davood},
abstractNote = {Here, we study the effects of chemical treatment with bis(trifluoromethane) sulfonimide superacid on material and device properties of monolayer molybdenum disulfide grown by chemical vapor deposition. Our spatially resolved photoluminescence (PL) measurements and device studies reveal two key findings due to the chemical treatment: (1) noticeable transformation of trions to neutral excitons, and (2) over 7-fold reduction in the density of mid-gap trap states. Specifically, a combination of scanning Auger microscopy and PL mapping reveals that the superacid treatment is effective in passivating the sulfur-deficient regions.},
doi = {10.1063/1.4974046},
journal = {Applied Physics Letters},
number = 3,
volume = 110,
place = {United States},
year = {2017},
month = {1}
}

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