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Title: 3D-Printing of Meso-structurally Ordered Carbon Fiber/Polymer Composites with Unprecedented Orthotropic Physical Properties

Abstract

Here we report the first example of a class of additively manufactured carbon fiber reinforced composite (AMCFRC) materials which have been achieved through the use of a latent thermal cured aromatic thermoset resin system, through an adaptation of direct ink writing (DIW) 3D-printing technology. We have developed a means of printing high performance thermoset carbon fiber composites, which allow the fiber component of a resin and carbon fiber fluid to be aligned in three dimensions via controlled micro-extrusion and subsequently cured into complex geometries. Characterization of our composite systems clearly show that we achieved a high order of fiber alignment within the composite microstructure, which in turn allows these materials to outperform equivalently filled randomly oriented carbon fiber and polymer composites. Moreover, our AM carbon fiber composite systems exhibit highly orthotropic mechanical and electrical responses as a direct result of the alignment of carbon fiber bundles in the microscale which we predict will ultimately lead to the design of truly tailorable carbon fiber/polymer hybrid materials having locally programmable complex electrical, thermal and mechanical response.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
  1. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Publication Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1368030
Report Number(s):
LLNL-JRNL-709557
Journal ID: ISSN 2045-2322
Grant/Contract Number:  
AC52-07NA27344
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 7; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; composites; computational science

Citation Formats

Lewicki, James P., Rodriguez, Jennifer N., Zhu, Cheng, Worsley, Marcus A., Wu, Amanda S., Kanarska, Yuliya, Horn, John D., Duoss, Eric B., Ortega, Jason M., Elmer, William, Hensleigh, Ryan, Fellini, Ryan A., and King, Michael J. 3D-Printing of Meso-structurally Ordered Carbon Fiber/Polymer Composites with Unprecedented Orthotropic Physical Properties. United States: N. p., 2017. Web. doi:10.1038/srep43401.
Lewicki, James P., Rodriguez, Jennifer N., Zhu, Cheng, Worsley, Marcus A., Wu, Amanda S., Kanarska, Yuliya, Horn, John D., Duoss, Eric B., Ortega, Jason M., Elmer, William, Hensleigh, Ryan, Fellini, Ryan A., & King, Michael J. 3D-Printing of Meso-structurally Ordered Carbon Fiber/Polymer Composites with Unprecedented Orthotropic Physical Properties. United States. doi:10.1038/srep43401.
Lewicki, James P., Rodriguez, Jennifer N., Zhu, Cheng, Worsley, Marcus A., Wu, Amanda S., Kanarska, Yuliya, Horn, John D., Duoss, Eric B., Ortega, Jason M., Elmer, William, Hensleigh, Ryan, Fellini, Ryan A., and King, Michael J. Mon . "3D-Printing of Meso-structurally Ordered Carbon Fiber/Polymer Composites with Unprecedented Orthotropic Physical Properties". United States. doi:10.1038/srep43401. https://www.osti.gov/servlets/purl/1368030.
@article{osti_1368030,
title = {3D-Printing of Meso-structurally Ordered Carbon Fiber/Polymer Composites with Unprecedented Orthotropic Physical Properties},
author = {Lewicki, James P. and Rodriguez, Jennifer N. and Zhu, Cheng and Worsley, Marcus A. and Wu, Amanda S. and Kanarska, Yuliya and Horn, John D. and Duoss, Eric B. and Ortega, Jason M. and Elmer, William and Hensleigh, Ryan and Fellini, Ryan A. and King, Michael J.},
abstractNote = {Here we report the first example of a class of additively manufactured carbon fiber reinforced composite (AMCFRC) materials which have been achieved through the use of a latent thermal cured aromatic thermoset resin system, through an adaptation of direct ink writing (DIW) 3D-printing technology. We have developed a means of printing high performance thermoset carbon fiber composites, which allow the fiber component of a resin and carbon fiber fluid to be aligned in three dimensions via controlled micro-extrusion and subsequently cured into complex geometries. Characterization of our composite systems clearly show that we achieved a high order of fiber alignment within the composite microstructure, which in turn allows these materials to outperform equivalently filled randomly oriented carbon fiber and polymer composites. Moreover, our AM carbon fiber composite systems exhibit highly orthotropic mechanical and electrical responses as a direct result of the alignment of carbon fiber bundles in the microscale which we predict will ultimately lead to the design of truly tailorable carbon fiber/polymer hybrid materials having locally programmable complex electrical, thermal and mechanical response.},
doi = {10.1038/srep43401},
journal = {Scientific Reports},
number = ,
volume = 7,
place = {United States},
year = {2017},
month = {3}
}

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Works referenced in this record:

Numerical analysis of blood flow in the heart
journal, November 1977


A self-healing carbon fibre reinforced polymer for aerospace applications
journal, June 2007


Polyamide 6?long glass fiber injection moldings
journal, October 1995


Biocompatible Silk Printed Optical Waveguides
journal, June 2009

  • Parker, Sara T.; Domachuk, Peter; Amsden, Jason
  • Advanced Materials, Vol. 21, Issue 23, p. 2411-2415
  • DOI: 10.1002/adma.200801580

Solvent-Cast Three-Dimensional Printing of Multifunctional Microsystems
journal, July 2013

  • Guo, Shuang-Zhuang; Gosselin, Frédérick; Guerin, Nicolas
  • Small, Vol. 9, Issue 24
  • DOI: 10.1002/smll.201300975

The processing, properties, and structure of carbon fibers
journal, February 2005


An adaptive, formally second order accurate version of the immersed boundary method
journal, April 2007

  • Griffith, Boyce E.; Hornung, Richard D.; McQueen, David M.
  • Journal of Computational Physics, Vol. 223, Issue 1
  • DOI: 10.1016/j.jcp.2006.08.019

In vivo bone response to 3D periodic hydroxyapatite scaffolds assembled by direct ink writing
journal, December 2007

  • Simon, Joshua L.; Michna, Sarah; Lewis, Jennifer A.
  • Journal of Biomedical Materials Research Part A, Vol. 83A, Issue 3
  • DOI: 10.1002/jbm.a.31329

Direct Ink Writing of Three-Dimensional Ceramic Structures
journal, December 2006

  • Lewis, Jennifer A.; Smay, James E.; Stuecker, John
  • Journal of the American Ceramic Society, Vol. 89, Issue 12, p. 3599-3609
  • DOI: 10.1111/j.1551-2916.2006.01382.x

Tensile properties of short-glass-fiber- and short-carbon-fiber-reinforced polypropylene composites
journal, October 2000


Evaluation of Commercially Available Carbon Fibers, Fabrics, and Papers for Potential Use in Multifunctional Energy Storage Applications
journal, January 2009

  • Snyder, James F.; Wong, Emma L.; Hubbard, Clifford W.
  • Journal of The Electrochemical Society, Vol. 156, Issue 3
  • DOI: 10.1149/1.3065070

Carbon nanotube/carbon fiber hybrid multiscale composites
journal, May 2002

  • Thostenson, E. T.; Li, W. Z.; Wang, D. Z.
  • Journal of Applied Physics, Vol. 91, Issue 9
  • DOI: 10.1063/1.1466880

Conformal Printing of Electrically Small Antennas on Three-Dimensional Surfaces
journal, January 2011

  • Adams, Jacob J.; Duoss, Eric B.; Malkowski, Thomas F.
  • Advanced Materials, Vol. 23, Issue 11
  • DOI: 10.1002/adma.201003734

3D Printing of Interdigitated Li-Ion Microbattery Architectures
journal, June 2013

  • Sun, Ke; Wei, Teng-Sing; Ahn, Bok Yeop
  • Advanced Materials, Vol. 25, Issue 33, p. 4539-4543
  • DOI: 10.1002/adma.201301036

Additive manufacturing of carbon fiber reinforced thermoplastic composites using fused deposition modeling
journal, October 2015


3D-Printing of Lightweight Cellular Composites
journal, June 2014

  • Compton, Brett G.; Lewis, Jennifer A.
  • Advanced Materials, Vol. 26, Issue 34, p. 5930-5935
  • DOI: 10.1002/adma.201401804

Managing application complexity in the SAMRAI object-oriented framework
journal, January 2002

  • Hornung, Richard D.; Kohn, Scott R.
  • Concurrency and Computation: Practice and Experience, Vol. 14, Issue 5
  • DOI: 10.1002/cpe.652

Carbon Fibers: Precursors, Manufacturing, and Properties
journal, May 2012

  • Frank, Erik; Hermanutz, Frank; Buchmeiser, Michael R.
  • Macromolecular Materials and Engineering, Vol. 297, Issue 6
  • DOI: 10.1002/mame.201100406

Colloidal Inks for Directed Assembly of 3-D Periodic Structures
journal, July 2002

  • Smay, James E.; Cesarano, Joseph; Lewis, Jennifer A.
  • Langmuir, Vol. 18, Issue 14, p. 5429-5437
  • DOI: 10.1021/la0257135

Highly oriented carbon fiber–polymer composites via additive manufacturing
journal, December 2014


Short fiber reinforced composites for fused deposition modeling
journal, March 2001


Direct‐Write Assembly of Microperiodic Silk Fibroin Scaffolds for Tissue Engineering Applications
journal, July 2008

  • Ghosh, Sourabh; Parker, Sara T.; Wang, Xianyan
  • Advanced Functional Materials, Vol. 18, Issue 13
  • DOI: 10.1002/adfm.200800040

Measuring the fibre orientation and modelling the elastic properties of injection-moulded long-glass-fibre-reinforced nylon
journal, January 1995


Direct-write fabrication of freestanding nanocomposite strain sensors
journal, February 2012


Three-Dimensional Printing of Elastomeric, Cellular Architectures with Negative Stiffness
journal, May 2014

  • Duoss, Eric B.; Weisgraber, Todd H.; Hearon, Keith
  • Advanced Functional Materials, Vol. 24, Issue 31
  • DOI: 10.1002/adfm.201400451

Nanofiber-reinforced polymers prepared by fused deposition modeling: Nanofiber-Reinforced Polymers
journal, June 2003

  • Shofner, M. L.; Lozano, K.; Rodríguez-Macías, F. J.
  • Journal of Applied Polymer Science, Vol. 89, Issue 11
  • DOI: 10.1002/app.12496

The carbon fibre/epoxy interface—A review
journal, January 1991


Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique
journal, September 2011


A comparison of rapid prototyping technologies
journal, October 1998


Carbon fiber reinforced plastics in aircraft construction
journal, December 2005


Fiber-Reinforced Polymer Composites for Construction—State-of-the-Art Review
journal, May 2002


The influence of fibre diameter on the tensile behaviour of short-glass-fibre reinforced polymers
journal, January 1985


The importance of carbon fiber to polymer additive manufacturing
journal, September 2014

  • Love, Lonnie J.; Kunc, Vlastamil; Rios, Orlando
  • Journal of Materials Research, Vol. 29, Issue 17
  • DOI: 10.1557/jmr.2014.212

On the mechanical response of short fibre reinforced polymer composites
journal, May 1994

  • Biolzi, L.; Castellani, L.; Pitacco, I.
  • Journal of Materials Science, Vol. 29, Issue 9
  • DOI: 10.1007/BF00363447

Carbon Fiber Reinforced Shape Memory Polymer Composites
journal, November 2000

  • Gall, Ken; Mikulas, Martin; Munshi, Naseem A.
  • Journal of Intelligent Material Systems and Structures, Vol. 11, Issue 11
  • DOI: 10.1106/EJGR-EWNM-6CLX-3X2M

Paper-Based Energy-Storage Devices Comprising Carbon Fiber-Reinforced Polypyrrole-Cladophora Nanocellulose Composite Electrodes
journal, February 2012

  • Razaq, Aamir; Nyholm, Leif; Sjödin, Martin
  • Advanced Energy Materials, Vol. 2, Issue 4
  • DOI: 10.1002/aenm.201100713

Thixotropic rheology of concentrated alumina colloidal gels for solid freeform fabrication
journal, May 2011

  • Zhu, Cheng; Smay, James E.
  • Journal of Rheology, Vol. 55, Issue 3
  • DOI: 10.1122/1.3573828

The immersed boundary method for advection–electrodiffusion with implicit timestepping and local mesh refinement
journal, July 2010

  • Lee, Pilhwa; Griffith, Boyce E.; Peskin, Charles S.
  • Journal of Computational Physics, Vol. 229, Issue 13
  • DOI: 10.1016/j.jcp.2010.03.036

Effect of glass-fibre reinforcement and annealing on microstructure and mechanical behaviour of nylon 6,6: Part II Mechanical behaviour
journal, April 1994

  • Shiao, M. L.; Nair, S. V.; Garrett, P. D.
  • Journal of Materials Science, Vol. 29, Issue 7
  • DOI: 10.1007/BF00351291

Mechanically robust and electrically conductive carbon nanotube foams
journal, February 2009

  • Worsley, Marcus A.; Kucheyev, Sergei O.; Satcher, Joe H.
  • Applied Physics Letters, Vol. 94, Issue 7, Article No. 073115
  • DOI: 10.1063/1.3086293

Microfailure behaviour of randomly dispersed short fibre reinforced thermoplastic composites obtained by direct SEM observation
journal, July 1991

  • Sato, N.; Kurauchi, T.; Sato, S.
  • Journal of Materials Science, Vol. 26, Issue 14
  • DOI: 10.1007/BF01184987

A benchmark study on rapid prototyping processes and machines: Quantitative comparisons of mechanical properties, accuracy, roughness, speed, and material cost
journal, February 2008

  • Kim, G. D.; Oh, Y. T.
  • Proceedings of the Institution of Mechanical Engineers, Part B: Journal of Engineering Manufacture, Vol. 222, Issue 2
  • DOI: 10.1243/09544054JEM724

Natural-fiber-reinforced polymer composites in automotive applications
journal, November 2006


Characterization of fiber/matrix interface strength: applicability of different tests, approaches and parameters
journal, January 2005


Low-frequency dielectric measurements (10 -4 to 6 × 10 4 Hz): a new computer-controlled method
journal, August 1984

  • Hayward, D.; Gawayne, M.; Mahboubian-Jones, B.
  • Journal of Physics E: Scientific Instruments, Vol. 17, Issue 8
  • DOI: 10.1088/0022-3735/17/8/014

Processing and characterization of aligned vapor grown carbon fiber reinforced polypropylene
journal, January 2002

  • Kuriger, Rex J.; Alam, M. Khairul; Anderson, David P.
  • Composites Part A: Applied Science and Manufacturing, Vol. 33, Issue 1
  • DOI: 10.1016/S1359-835X(01)00070-7

Catenary shape evolution of spanning structures in direct-write assembly of colloidal gels
journal, March 2012


Fabrication and Properties of Carbon Fibers
journal, December 2009


Direct Ink Writing of 3D Functional Materials
journal, November 2006


A discrete numerical model for granular assemblies
journal, March 1979


Highly compressible 3D periodic graphene aerogel microlattices
journal, April 2015

  • Zhu, Cheng; Han, T. Yong-Jin; Duoss, Eric B.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7962

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    Compressive Response of Non-slender Octet Carbon Microlattices
    journal, July 2019


    Compressive Response of Non-slender Octet Carbon Microlattices
    journal, July 2019