skip to main content

DOE PAGESDOE PAGES

Title: Laser ablation of sub-10 nm silver nanoparticles

Laser ablation of silver nanoparticles (NPs) was studied with laser post-ionization (LPI) time-of-flight mass spectrometry (TOF MS). Silver NPs containing ~15 000 Ag atoms (4 nm radius) were deposited by soft landing (energy 3 eV/atom) onto indium tin oxide (ITO)/glass substrates. Laser ablation was performed using frequency-doubled Ti:sapphire nanosecond pulsed laser irradiation at three different wavelengths (371, 401, and 421 nm), whereas for post-ionization, pulses from an F 2 laser were used. Laser fluences and time delay dependencies of Ag and In signals were obtained. Using these data, the temperature of the desorption source as well as its time duration were calculated. It was found that the peak temperature of NPs was above their melting point and they cooled down slowly, with temperature decay time of several hundreds of nanoseconds. This anomalous behavior was explained based on a model where the semiconducting ITO substrate is initially transparent to the desorption laser radiation but starts to adsorb it due to the temperature increase arising from heat exchange with NPs. Poor heat conduction in the ITO film creates conditions for long-lived hot spots on the surface and initiates further optical damage of the substrate. No difference in the ablation process due tomore » plasmon resonance was detected, likely due to thermal expansion and melting of NPs during laser irradiation, which then broadens the plasmon absorption band enough to cover all wavelengths used. Here, these results clearly demonstrate that the process of NP interaction with laser radiation is governed not only by initial optical and thermophysical parameters of NPs and the surrounding media, but also by their alteration due to temperature increases during the irradiation process.« less
Authors:
ORCiD logo [1] ;  [2] ;  [3] ;  [4] ;  [5] ;  [6] ;  [4] ;  [1]
  1. Argonne National Lab. (ANL), Lemont, IL (United States)
  2. Robot Nose Corp., Lemont, IL (United States)
  3. Euclid TechLabs, Bolingbrook, IL (United States)
  4. Ionwerks Inc., Houston, TX (United States)
  5. Ionwerks Inc., Houston, TX (United States); Rice Univ., Houston, TX (United States)
  6. Rice Univ., Houston, TX (United States)
Publication Date:
Grant/Contract Number:
AC02-06CH11357
Type:
Accepted Manuscript
Journal Name:
Journal of Physical Chemistry. C
Additional Journal Information:
Journal Volume: 121; Journal Issue: 17; Journal ID: ISSN 1932-7447
Publisher:
American Chemical Society
Research Org:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Materials Sciences and Engineering Division
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; ablation; laser; nanoparticles; mass spectrometry; silver
OSTI Identifier:
1366732
Alternate Identifier(s):
OSTI ID: 1427535

Zinovev, Alexander, Moore, Jerome F., Baryshev, Sergey V., Schultz, J. Albert, Lewis, Ernest, Brinson, Bruce, McCully, Michael, and Pellin, Michael. Laser ablation of sub-10 nm silver nanoparticles. United States: N. p., Web. doi:10.1021/acs.jpcc.7b01061.
Zinovev, Alexander, Moore, Jerome F., Baryshev, Sergey V., Schultz, J. Albert, Lewis, Ernest, Brinson, Bruce, McCully, Michael, & Pellin, Michael. Laser ablation of sub-10 nm silver nanoparticles. United States. doi:10.1021/acs.jpcc.7b01061.
Zinovev, Alexander, Moore, Jerome F., Baryshev, Sergey V., Schultz, J. Albert, Lewis, Ernest, Brinson, Bruce, McCully, Michael, and Pellin, Michael. 2017. "Laser ablation of sub-10 nm silver nanoparticles". United States. doi:10.1021/acs.jpcc.7b01061. https://www.osti.gov/servlets/purl/1366732.
@article{osti_1366732,
title = {Laser ablation of sub-10 nm silver nanoparticles},
author = {Zinovev, Alexander and Moore, Jerome F. and Baryshev, Sergey V. and Schultz, J. Albert and Lewis, Ernest and Brinson, Bruce and McCully, Michael and Pellin, Michael},
abstractNote = {Laser ablation of silver nanoparticles (NPs) was studied with laser post-ionization (LPI) time-of-flight mass spectrometry (TOF MS). Silver NPs containing ~15 000 Ag atoms (4 nm radius) were deposited by soft landing (energy 3 eV/atom) onto indium tin oxide (ITO)/glass substrates. Laser ablation was performed using frequency-doubled Ti:sapphire nanosecond pulsed laser irradiation at three different wavelengths (371, 401, and 421 nm), whereas for post-ionization, pulses from an F2 laser were used. Laser fluences and time delay dependencies of Ag and In signals were obtained. Using these data, the temperature of the desorption source as well as its time duration were calculated. It was found that the peak temperature of NPs was above their melting point and they cooled down slowly, with temperature decay time of several hundreds of nanoseconds. This anomalous behavior was explained based on a model where the semiconducting ITO substrate is initially transparent to the desorption laser radiation but starts to adsorb it due to the temperature increase arising from heat exchange with NPs. Poor heat conduction in the ITO film creates conditions for long-lived hot spots on the surface and initiates further optical damage of the substrate. No difference in the ablation process due to plasmon resonance was detected, likely due to thermal expansion and melting of NPs during laser irradiation, which then broadens the plasmon absorption band enough to cover all wavelengths used. Here, these results clearly demonstrate that the process of NP interaction with laser radiation is governed not only by initial optical and thermophysical parameters of NPs and the surrounding media, but also by their alteration due to temperature increases during the irradiation process.},
doi = {10.1021/acs.jpcc.7b01061},
journal = {Journal of Physical Chemistry. C},
number = 17,
volume = 121,
place = {United States},
year = {2017},
month = {4}
}