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Title: Molecular and morphological characterization of midblock-sulfonated styrenic triblock copolymers

Midblock-sulfonated triblock copolymers afford a desirable opportunity to generate network-forming amphiphilic materials that are suitable for use in a wide range of emerging technologies as fuel-cell, water-desalination, ion-exchange, photovoltaic, or electroactive membranes. Employing a previously reported synthetic strategy wherein poly( p- tert-butylstyrene) remains unreactive, we have selectively sulfonated the styrenic midblock of a poly( p- tert-butylstyrene- b-styrene- b- p- tert- butylstyrene) (TST) triblock copolymer to different extents. Comparison of the resulting sulfonated copolymers with results from our prior study provides favorable quantitative agreement and suggests that a shortened reaction time is advantageous. An ongoing challenge regarding the morphological development of charged block copolymers is the competition between microphase separation of the incompatible blocks and physical cross-linking of ionic clusters, with the latter often hindering the former. Here, we expose the sulfonated TST copolymers to solvent-vapor annealing to promote nanostructural refinement. Furthermore, the effect of such annealing on morphological characteristics, as well as on molecular free volume, is explored.
Authors:
 [1] ;  [1] ;  [2] ;  [3] ;  [1]
  1. North Carolina State Univ., Raleigh, NC (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. The Procter & Gamble Co., Cincinnati, OH (United States)
Publication Date:
Grant/Contract Number:
AC02-06CH11357
Type:
Accepted Manuscript
Journal Name:
Journal of Polymer Science. Part B, Polymer Physics
Additional Journal Information:
Journal Volume: 55; Journal Issue: 6; Journal ID: ISSN 0887-6266
Publisher:
Wiley
Research Org:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org:
North Carolina State University; National Science Foundation (NSF); USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; block copolymers; ionomers; morphology; TEM; SAXS; self-assembly
OSTI Identifier:
1366515

Mineart, Kenneth P., Ryan, Justin J., Lee, Byeongdu, Smith, Steven D., and Spontak, Richard J.. Molecular and morphological characterization of midblock-sulfonated styrenic triblock copolymers. United States: N. p., Web. doi:10.1002/polb.24294.
Mineart, Kenneth P., Ryan, Justin J., Lee, Byeongdu, Smith, Steven D., & Spontak, Richard J.. Molecular and morphological characterization of midblock-sulfonated styrenic triblock copolymers. United States. doi:10.1002/polb.24294.
Mineart, Kenneth P., Ryan, Justin J., Lee, Byeongdu, Smith, Steven D., and Spontak, Richard J.. 2017. "Molecular and morphological characterization of midblock-sulfonated styrenic triblock copolymers". United States. doi:10.1002/polb.24294. https://www.osti.gov/servlets/purl/1366515.
@article{osti_1366515,
title = {Molecular and morphological characterization of midblock-sulfonated styrenic triblock copolymers},
author = {Mineart, Kenneth P. and Ryan, Justin J. and Lee, Byeongdu and Smith, Steven D. and Spontak, Richard J.},
abstractNote = {Midblock-sulfonated triblock copolymers afford a desirable opportunity to generate network-forming amphiphilic materials that are suitable for use in a wide range of emerging technologies as fuel-cell, water-desalination, ion-exchange, photovoltaic, or electroactive membranes. Employing a previously reported synthetic strategy wherein poly(p-tert-butylstyrene) remains unreactive, we have selectively sulfonated the styrenic midblock of a poly(p-tert-butylstyrene-b-styrene-b-p-tert- butylstyrene) (TST) triblock copolymer to different extents. Comparison of the resulting sulfonated copolymers with results from our prior study provides favorable quantitative agreement and suggests that a shortened reaction time is advantageous. An ongoing challenge regarding the morphological development of charged block copolymers is the competition between microphase separation of the incompatible blocks and physical cross-linking of ionic clusters, with the latter often hindering the former. Here, we expose the sulfonated TST copolymers to solvent-vapor annealing to promote nanostructural refinement. Furthermore, the effect of such annealing on morphological characteristics, as well as on molecular free volume, is explored.},
doi = {10.1002/polb.24294},
journal = {Journal of Polymer Science. Part B, Polymer Physics},
number = 6,
volume = 55,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Ultrahigh-Density Nanowire Arrays Grown in Self-Assembled Diblock Copolymer Templates
journal, December 2000

Ordered Mesoporous Materials from Metal Nanoparticle-Block Copolymer Self-Assembly
journal, June 2008
  • Warren, S. C.; Messina, L. C.; Slaughter, L. S.
  • Science, Vol. 320, Issue 5884, p. 1748-1752
  • DOI: 10.1126/science.1159950

A silica sol–gel design strategy for nanostructured metallic materials
journal, March 2012
  • Warren, Scott C.; Perkins, Matthew R.; Adams, Ashley M.
  • Nature Materials, Vol. 11, Issue 5, p. 460-467
  • DOI: 10.1038/nmat3274