Ionization Study of Isomeric Molecules in Strong-field Laser Pulses
Abstract
Through the use of the technique of time-of-flight mass spectroscopy, we obtain strong-field ionization yields for randomly oriented 1,2-dichloroethylene (1,2-DCE) (C2H2Cl2) and 2-butene (C4H8). Here, we are interested in studying the effect of conformal structure in strong-field ionization and, in particular, the role of molecular polarity. That is, we can perform strong-field ionization studies in polar vs non-polar molecules that have the same chemical composition. Here, we report our findings through the ionization yields and the ratio (trans/cis) of each stereoisomer pair as a function of intensity.
- Authors:
-
- Kansas State Univ., Manhattan, KS (United States). Dept. of Physics
- Publication Date:
- Research Org.:
- Kansas State Univ., Manhattan, KS (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1366468
- Grant/Contract Number:
- FG02-86ER13491
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 7; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS; atomic and molecular interactions with photons; chemical physics; electronic structure of atoms and molecules
Citation Formats
Zigo, Stefan, Le, Anh-Thu, Timilsina, Pratap, and Trallero-Herrero, Carlos A. Ionization Study of Isomeric Molecules in Strong-field Laser Pulses. United States: N. p., 2017.
Web. doi:10.1038/srep42149.
Zigo, Stefan, Le, Anh-Thu, Timilsina, Pratap, & Trallero-Herrero, Carlos A. Ionization Study of Isomeric Molecules in Strong-field Laser Pulses. United States. https://doi.org/10.1038/srep42149
Zigo, Stefan, Le, Anh-Thu, Timilsina, Pratap, and Trallero-Herrero, Carlos A. Fri .
"Ionization Study of Isomeric Molecules in Strong-field Laser Pulses". United States. https://doi.org/10.1038/srep42149. https://www.osti.gov/servlets/purl/1366468.
@article{osti_1366468,
title = {Ionization Study of Isomeric Molecules in Strong-field Laser Pulses},
author = {Zigo, Stefan and Le, Anh-Thu and Timilsina, Pratap and Trallero-Herrero, Carlos A.},
abstractNote = {Through the use of the technique of time-of-flight mass spectroscopy, we obtain strong-field ionization yields for randomly oriented 1,2-dichloroethylene (1,2-DCE) (C2H2Cl2) and 2-butene (C4H8). Here, we are interested in studying the effect of conformal structure in strong-field ionization and, in particular, the role of molecular polarity. That is, we can perform strong-field ionization studies in polar vs non-polar molecules that have the same chemical composition. Here, we report our findings through the ionization yields and the ratio (trans/cis) of each stereoisomer pair as a function of intensity.},
doi = {10.1038/srep42149},
journal = {Scientific Reports},
number = ,
volume = 7,
place = {United States},
year = {2017},
month = {2}
}
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Figures / Tables:
Figure 1: Ionization yields of the first ion of (a) 2-butene and (b) 1, 2-DCE (35–35 isotope) as a function of intensity (log-log).
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Works referencing / citing this record:
Quantum-chemistry-aided identification, synthesis and experimental validation of model systems for conformationally controlled reaction studies: separation of the conformers of 2,3-dibromobuta-1,3-diene in the gas phase
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Heteronuclear Limit of Strong-Field Ionization: Fragmentation of by Intense Ultrashort Laser Pulses
journal, August 2018
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other, January 2018
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- Kilaj, Ardita; Gao, Hong; Tahchieva, Diana Nikolaeva
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Heteronuclear Limit of Strong-Field Ionization: Fragmentation of HeH$^+$ by Intense Ultrashort Laser Pulses
text, January 2018
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