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Title: Irradiation-induced damage evolution in concentrated Ni-based alloys

Abstract

Understanding the effects of chemical complexity from the number, type and concentration of alloying elements in single-phase concentred solid-solution alloys (SP-CSAs) on defect dynamics and microstructure evolution is pivotal for developing next-generation radiation-tolerant structural alloys. A specially chosen set of SP-CSAs with different chemical complexity (Ni80Fe20, Ni80Cr20 and Ni40Fe40Cr20) are investigated using 1.5 MeV Mn ions over a wide fluence range, from 2 × 1013 to 1 × 1016 ions cm–2 at room temperature. Based on an integrated study of Rutherford backscattering spectroscopy in channeling geometry and molecular dynamics simulations, the results demonstrate that Ni40Fe40Cr20 is more radiation tolerant than Ni80Fe20, Ni80Cr20 and elemental Ni in the low fluence regime. While chemical complexity of this set of SP-CSAs is clearly demonstrated to affect defect evolution through suppressed defect production and enhanced recombination at early stages, the effect of the mixed ferro- and anti-ferromagnetic interactions is not the only controlling factor responsible for the improved radiation performance. As a result, the observed strong alloying effect on defect evolution is attributed to the altered defect migration mobilities of defect clusters in these alloys, an intrinsic characteristic of the complex energy landscapes in CSAs.

Authors:
 [1];  [1];  [2];  [1];  [2];  [1];  [3];  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Univ. of Tennessee, Knoxville, TN (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Energy Dissipation to Defect Evolution (EDDE)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1366404
Alternate Identifier(s):
OSTI ID: 1550135
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Acta Materialia
Additional Journal Information:
Journal Volume: 135; Journal Issue: C; Journal ID: ISSN 1359-6454
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; concentrated solid-solution alloys; ferro/antiferromagnetic coupling; ion irradiation; damage evolution; molecular dynamics simulations

Citation Formats

Velisa, Gihan, Ullah, Mohammad Wali, Xue, Haizhou, Jin, Ke, Crespillo, Miguel L., Bei, Hongbin, Weber, William J., and Zhang, Yanwen. Irradiation-induced damage evolution in concentrated Ni-based alloys. United States: N. p., 2017. Web. https://doi.org/10.1016/j.actamat.2017.06.002.
Velisa, Gihan, Ullah, Mohammad Wali, Xue, Haizhou, Jin, Ke, Crespillo, Miguel L., Bei, Hongbin, Weber, William J., & Zhang, Yanwen. Irradiation-induced damage evolution in concentrated Ni-based alloys. United States. https://doi.org/10.1016/j.actamat.2017.06.002
Velisa, Gihan, Ullah, Mohammad Wali, Xue, Haizhou, Jin, Ke, Crespillo, Miguel L., Bei, Hongbin, Weber, William J., and Zhang, Yanwen. Tue . "Irradiation-induced damage evolution in concentrated Ni-based alloys". United States. https://doi.org/10.1016/j.actamat.2017.06.002. https://www.osti.gov/servlets/purl/1366404.
@article{osti_1366404,
title = {Irradiation-induced damage evolution in concentrated Ni-based alloys},
author = {Velisa, Gihan and Ullah, Mohammad Wali and Xue, Haizhou and Jin, Ke and Crespillo, Miguel L. and Bei, Hongbin and Weber, William J. and Zhang, Yanwen},
abstractNote = {Understanding the effects of chemical complexity from the number, type and concentration of alloying elements in single-phase concentred solid-solution alloys (SP-CSAs) on defect dynamics and microstructure evolution is pivotal for developing next-generation radiation-tolerant structural alloys. A specially chosen set of SP-CSAs with different chemical complexity (Ni80Fe20, Ni80Cr20 and Ni40Fe40Cr20) are investigated using 1.5 MeV Mn ions over a wide fluence range, from 2 × 1013 to 1 × 1016 ions cm–2 at room temperature. Based on an integrated study of Rutherford backscattering spectroscopy in channeling geometry and molecular dynamics simulations, the results demonstrate that Ni40Fe40Cr20 is more radiation tolerant than Ni80Fe20, Ni80Cr20 and elemental Ni in the low fluence regime. While chemical complexity of this set of SP-CSAs is clearly demonstrated to affect defect evolution through suppressed defect production and enhanced recombination at early stages, the effect of the mixed ferro- and anti-ferromagnetic interactions is not the only controlling factor responsible for the improved radiation performance. As a result, the observed strong alloying effect on defect evolution is attributed to the altered defect migration mobilities of defect clusters in these alloys, an intrinsic characteristic of the complex energy landscapes in CSAs.},
doi = {10.1016/j.actamat.2017.06.002},
journal = {Acta Materialia},
number = C,
volume = 135,
place = {United States},
year = {2017},
month = {6}
}

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Cited by: 9 works
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Works referenced in this record:

Materials challenges for nuclear systems
journal, December 2010


Materials challenges in nuclear energy
journal, February 2013


Designing Radiation Resistance in Materials for Fusion Energy
journal, July 2014


Characterization of microstructure and property evolution in advanced cladding and duct: Materials exposed to high dose and elevated temperature
journal, May 2015

  • Allen, Todd R.; Kaoumi, Djamel; Wharry, Janelle P.
  • Journal of Materials Research, Vol. 30, Issue 9
  • DOI: 10.1557/jmr.2015.99

Structural materials for next generation nuclear systems: Challenges and the path forward
journal, December 2015


Radiation-induced solute segregation in metallic alloys
journal, June 2016


A fracture-resistant high-entropy alloy for cryogenic applications
journal, September 2014


Influence of chemical disorder on energy dissipation and defect evolution in concentrated solid solution alloys
journal, October 2015

  • Zhang, Yanwen; Stocks, G. Malcolm; Jin, Ke
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9736

Deviation from high-entropy configurations in the atomic distributions of a multi-principal-element alloy
journal, January 2015

  • Santodonato, Louis J.; Zhang, Yang; Feygenson, Mikhail
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms6964

Accelerated exploration of multi-principal element alloys with solid solution phases
journal, March 2015

  • Senkov, O. N.; Miller, J. D.; Miracle, D. B.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7529

Tailoring the physical properties of Ni-based single-phase equiatomic alloys by modifying the chemical complexity
journal, February 2016

  • Jin, K.; Sales, B. C.; Stocks, G. M.
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep20159

Direct Observation of Defect Range and Evolution in Ion-Irradiated Single Crystalline Ni and Ni Binary Alloys
journal, February 2016

  • Lu, Chenyang; Jin, Ke; Béland, Laurent K.
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep19994

High-entropy Alloys with High Saturation Magnetization, Electrical Resistivity and Malleability
journal, March 2013

  • Zhang, Yong; Zuo, TingTing; Cheng, YongQiang
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep01455

Refractory high-entropy alloys
journal, September 2010


Mechanical properties of Nb25Mo25Ta25W25 and V20Nb20Mo20Ta20W20 refractory high entropy alloys
journal, May 2011


Synthesis and Characterization of High-Entropy Alloy FeCoNiCuCr by Laser Cladding
journal, January 2011

  • Ye, Xiaoyang; Ma, Mingxing; Liu, Wenjin
  • Advances in Materials Science and Engineering, Vol. 2011
  • DOI: 10.1155/2011/485942

Solid Solution or Intermetallics in a High-Entropy Alloy
journal, August 2009

  • Wang, Yan Ping; Li, Bang Sheng; Fu, Heng Zhi
  • Advanced Engineering Materials, Vol. 11, Issue 8
  • DOI: 10.1002/adem.200900057

High-Entropy Alloys: A Critical Review
journal, April 2014


Physical Properties of High Entropy Alloys
journal, December 2013


Irradiation Resistance of Multicomponent Alloys
journal, September 2013

  • Egami, T.; Guo, W.; Rack, P. D.
  • Metallurgical and Materials Transactions A, Vol. 45, Issue 1
  • DOI: 10.1007/s11661-013-1994-2

Influence of chemical disorder on energy dissipation and defect evolution in advanced alloys
journal, August 2016

  • Zhang, Yanwen; Jin, Ke; Xue, Haizhou
  • Journal of Materials Research, Vol. 31, Issue 16
  • DOI: 10.1557/jmr.2016.269

Electrical resistivity of nickel-rich nickel-chromium alloys between 4 and 300 K
journal, November 1975

  • Yao, Y. D.; Arajs, Sigurds; Anderson, E. E.
  • Journal of Low Temperature Physics, Vol. 21, Issue 3-4
  • DOI: 10.1007/BF01141333

Electrical Resistivity of Ten Selected Binary Alloy Systems
journal, April 1983

  • Ho, C. Y.; Ackerman, M. W.; Wu, K. Y.
  • Journal of Physical and Chemical Reference Data, Vol. 12, Issue 2
  • DOI: 10.1063/1.555684

Electrical resistivities of γ-phase Fe x Ni 80 x Cr 20 alloys
journal, September 1994


New ion beam materials laboratory for materials modification and irradiation effects research
journal, November 2014

  • Zhang, Y.; Crespillo, M. L.; Xue, H.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 338
  • DOI: 10.1016/j.nimb.2014.07.028

Defect production in collision cascades in elemental semiconductors and fcc metals
journal, April 1998


Molecular dynamics investigations of surface damage produced by kiloelectronvolt self-bombardment of solids
journal, April 1999


Interatomic potential for studying ageing under irradiation in stainless steels: the FeNiCr model alloy
journal, October 2013

  • Bonny, G.; Castin, N.; Terentyev, D.
  • Modelling and Simulation in Materials Science and Engineering, Vol. 21, Issue 8
  • DOI: 10.1088/0965-0393/21/8/085004

Damage accumulation in ion-irradiated Ni-based concentrated solid-solution alloys
journal, May 2016


Ion irradiation induced defect evolution in Ni and Ni-based FCC equiatomic binary alloys
journal, April 2016


Simulation of Rutherford backscattering spectrometry from arbitrary atom structures
journal, October 2016


Response of strontium titanate to ion and electron irradiation
journal, May 2009


Versatile computer programs for analysis of random and channeling backscattering spectra
journal, February 1987

  • Kido, Yoshiaki; Kawamoto, Junichi
  • Journal of Applied Physics, Vol. 61, Issue 3
  • DOI: 10.1063/1.338148

Low current MeV Au2+ ion-induced amorphization in silicon: Rutherford backscattering spectrometry and transmission electron microscopy study
journal, July 2003

  • Kamila, J.; Satpati, B.; Goswami, D. K.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 207, Issue 3
  • DOI: 10.1016/S0168-583X(03)00459-2

Methods for the accurate analysis of channeling Rutherford backscattering spectrometry
journal, August 2005

  • Shao, Lin; Nastasi, Michael
  • Applied Physics Letters, Vol. 87, Issue 6
  • DOI: 10.1063/1.2007861

Mechanism of Radiation Damage Reduction in Equiatomic Multicomponent Single Phase Alloys
journal, April 2016


Atomic-level heterogeneity and defect dynamics in concentrated solid-solution alloys
journal, October 2017

  • Zhang, Yanwen; Zhao, Shijun; Weber, William J.
  • Current Opinion in Solid State and Materials Science, Vol. 21, Issue 5
  • DOI: 10.1016/j.cossms.2017.02.002

Local Structure and Short-Range Order in a NiCoCr Solid Solution Alloy
journal, May 2017


Defect energetics of concentrated solid-solution alloys from ab initio calculations: Ni 0.5 Co 0.5 , Ni 0.5 Fe 0.5 , Ni 0.8 Fe 0.2 and Ni 0.8 Cr 0.2
journal, January 2016

  • Zhao, Shijun; Stocks, G. Malcolm; Zhang, Yanwen
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 34
  • DOI: 10.1039/C6CP05161H

    Works referencing / citing this record:

    Irradiation responses and defect behavior of single-phase concentrated solid solution alloys
    journal, September 2018

    • Yang, Tengfei; Li, Congyi; Zinkle, Steven J.
    • Journal of Materials Research, Vol. 33, Issue 19
    • DOI: 10.1557/jmr.2018.285

    Radiation stability of nanocrystalline single-phase multicomponent alloys
    journal, February 2019

    • Levo, Emil; Granberg, Fredric; Utt, Daniel
    • Journal of Materials Research, Vol. 34, Issue 5
    • DOI: 10.1557/jmr.2019.19