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Title: Tetra- and Heptametallic Ru(II),Rh(III) Supramolecular Hydrogen Production Photocatalysts

ORCiD logo [1]; ORCiD logo [1];  [2]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division
  2. Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division; Virginia Polytechnic Inst. Blacksburg, VA (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
Alternate Identifier(s):
OSTI ID: 1376171
Report Number(s):
BNL-114001-2017-JA; BNL-114146-2017-JA
Journal ID: ISSN 0002-7863; R&D Project: CO026; KC0304030; TRN: US1702325
Grant/Contract Number:  
SC0012704; FG02-05ER15751
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 139; Journal Issue: 23; Journal ID: ISSN 0002-7863
American Chemical Society (ACS)
Country of Publication:
United States

Citation Formats

Manbeck, Gerald F., Fujita, Etsuko, and Brewer, Karen J. Tetra- and Heptametallic Ru(II),Rh(III) Supramolecular Hydrogen Production Photocatalysts. United States: N. p., 2017. Web.
Manbeck, Gerald F., Fujita, Etsuko, & Brewer, Karen J. Tetra- and Heptametallic Ru(II),Rh(III) Supramolecular Hydrogen Production Photocatalysts. United States.
Manbeck, Gerald F., Fujita, Etsuko, and Brewer, Karen J. Thu . "Tetra- and Heptametallic Ru(II),Rh(III) Supramolecular Hydrogen Production Photocatalysts". United States.
title = {Tetra- and Heptametallic Ru(II),Rh(III) Supramolecular Hydrogen Production Photocatalysts},
author = {Manbeck, Gerald F. and Fujita, Etsuko and Brewer, Karen J.},
abstractNote = {},
doi = {10.1021/jacs.7b02142},
journal = {Journal of the American Chemical Society},
number = 23,
volume = 139,
place = {United States},
year = {2017},
month = {6}

Journal Article:
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Works referenced in this record:

Photochemical Conversion of Solar Energy
journal, February 2008

  • Balzani, Vincenzo; Credi, Alberto; Venturi, Margherita
  • ChemSusChem, Vol. 1, Issue 1-2
  • DOI: 10.1002/cssc.200700087

Solar Fuels via Artificial Photosynthesis
journal, December 2009

  • Gust, Devens; Moore, Thomas A.; Moore, Ana L.
  • Accounts of Chemical Research, Vol. 42, Issue 12
  • DOI: 10.1021/ar900209b

Recent progress on photocatalytic and photoelectrochemical water splitting under visible light irradiation
journal, December 2010

Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds
journal, November 2010

  • Cook, Timothy R.; Dogutan, Dilek K.; Reece, Steven Y.
  • Chemical Reviews, Vol. 110, Issue 11
  • DOI: 10.1021/cr100246c

Artificial Photosynthesis: From Molecular Catalysts for Light-driven Water Splitting to Photoelectrochemical Cells
journal, August 2011

Solar Hydrogen Evolution with Hydrogenases: From Natural to Hybrid Systems
journal, December 2010

Making solar fuels by artificial photosynthesis
journal, March 2011

  • Song, Wenjing; Chen, Zuofeng; Brennaman, M. Kyle
  • Pure and Applied Chemistry, Vol. 83, Issue 4
  • DOI: 10.1351/PAC-CON-10-11-09

Photocatalytic hydrogen production
journal, January 2011

  • Teets, Thomas S.; Nocera, Daniel G.
  • Chemical Communications, Vol. 47, Issue 33
  • DOI: 10.1039/c1cc12390d

Nature-Driven Photochemistry for Catalytic Solar Hydrogen Production: A Photosystem I–Transition Metal Catalyst Hybrid
journal, October 2011

  • Utschig, Lisa M.; Silver, Sunshine C.; Mulfort, Karen L.
  • Journal of the American Chemical Society, Vol. 133, Issue 41
  • DOI: 10.1021/ja206012r

Molecular systems for light driven hydrogen production
journal, January 2012

  • Eckenhoff, William T.; Eisenberg, Richard
  • Dalton Transactions, Vol. 41, Issue 42
  • DOI: 10.1039/c2dt30823a

Molecular Chemistry for Solar Fuels: From Natural to Artificial Photosynthesis
journal, January 2012

  • Magnuson, Ann; Styring, Stenbjörn
  • Australian Journal of Chemistry, Vol. 65, Issue 6
  • DOI: 10.1071/CH12114

The Artificial Leaf
journal, January 2012

  • Nocera, Daniel G.
  • Accounts of Chemical Research, Vol. 45, Issue 5
  • DOI: 10.1021/ar2003013

Recent advances in hybrid photocatalysts for solar fuel production
journal, January 2012

  • Tran, Phong D.; Wong, Lydia H.; Barber, James
  • Energy & Environmental Science, Vol. 5, Issue 3
  • DOI: 10.1039/c2ee02849b

Homogeneous Catalytic System for Photoinduced Hydrogen Production Utilizing Iridium and Rhodium Complexes
journal, November 2008

  • Cline, Eric D.; Adamson, Samantha E.; Bernhard, Stefan
  • Inorganic Chemistry, Vol. 47, Issue 22
  • DOI: 10.1021/ic800988b

Light-Driven Hydrogen Generation: Efficient Iron-Based Water Reduction Catalysts
journal, December 2009

  • Gärtner, Felix; Sundararaju, Basker; Surkus, Annette-Enrica
  • Angewandte Chemie International Edition, Vol. 48, Issue 52
  • DOI: 10.1002/anie.200905115

Reductive Side of Water Splitting in Artificial Photosynthesis: New Homogeneous Photosystems of Great Activity and Mechanistic Insight
journal, November 2010

  • McCormick, Theresa M.; Calitree, Brandon D.; Orchard, Alexandra
  • Journal of the American Chemical Society, Vol. 132, Issue 44
  • DOI: 10.1021/ja1057357

Catalytic mechanisms of hydrogen evolution with homogeneous and heterogeneous catalysts
journal, January 2011

  • Fukuzumi, Shunichi; Yamada, Yusuke; Suenobu, Tomoyoshi
  • Energy & Environmental Science, Vol. 4, Issue 8
  • DOI: 10.1039/c1ee01551f

Theoretical studies of the mechanism of catalytic hydrogen production by a cobaloxime
journal, January 2011

  • Muckerman, James T.; Fujita, Etsuko
  • Chemical Communications, Vol. 47, Issue 46
  • DOI: 10.1039/c1cc15330g

Photocatalytic H 2 Production from Water with Rhenium and Cobalt Complexes
journal, April 2011

  • Probst, Benjamin; Guttentag, Miguel; Rodenberg, Alexander
  • Inorganic Chemistry, Vol. 50, Issue 8
  • DOI: 10.1021/ic102317u

Homogeneous Photocatalytic Hydrogen Production Using π-Conjugated Platinum(II) Arylacetylide Sensitizers
journal, February 2011

  • Wang, Xianghuai; Goeb, Sébastien; Ji, Zhiqiang
  • Inorganic Chemistry, Vol. 50, Issue 3
  • DOI: 10.1021/ic101731j

Synthesis and Characterization of New Iridium Photosensitizers for Catalytic Hydrogen Generation from Water
journal, February 2012

  • Gärtner, Felix; Denurra, Stefania; Losse, Sebastian
  • Chemistry - A European Journal, Vol. 18, Issue 11
  • DOI: 10.1002/chem.201103670

Photocatalytic H2 Production with a Rhenium/Cobalt System in Water under Acidic Conditions
journal, November 2011

  • Guttentag, Miguel; Rodenberg, Alexander; Kopelent, René
  • European Journal of Inorganic Chemistry, Vol. 2012, Issue 1
  • DOI: 10.1002/ejic.201100883

A Nickel Thiolate Catalyst for the Long-Lived Photocatalytic Production of Hydrogen in a Noble-Metal-Free System
journal, January 2012

  • Han, Zhiji; McNamara, William R.; Eum, Min-Sik
  • Angewandte Chemie International Edition, Vol. 51, Issue 7
  • DOI: 10.1002/anie.201107329

Cobalt-dithiolene complexes for the photocatalytic and electrocatalytic reduction of protons in aqueous solutions
journal, June 2012

  • McNamara, W. R.; Han, Z.; Yin, C. -J.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
  • DOI: 10.1073/pnas.1120757109

Photocatalytic Hydrogen Evolution with a Hydrogenase in a Mediator-Free System under High Levels of Oxygen
journal, September 2013

  • Sakai, Tsubasa; Mersch, Dirk; Reisner, Erwin
  • Angewandte Chemie International Edition, Vol. 52, Issue 47
  • DOI: 10.1002/anie.201306214

Photo-induced redox catalysis for proton reduction to hydrogen with homogeneous molecular systems using rhodium-based catalysts
journal, December 2015

  • Stoll, Thibaut; Castillo, Carmen E.; Kayanuma, Megumi
  • Coordination Chemistry Reviews, Vol. 304-305
  • DOI: 10.1016/j.ccr.2015.02.002

Oxygen-Dependent Photocatalytic Water Reduction with a Ruthenium(imidazolium) Chromophore and a Cobaloxime Catalyst
journal, May 2016

  • Petermann, Lydia; Staehle, Robert; Pfeifer, Maxim
  • Chemistry - A European Journal, Vol. 22, Issue 24
  • DOI: 10.1002/chem.201505113

A Photo-Hydrogen-Evolving Molecular Device Driving Visible-Light-Induced EDTA-Reduction of Water into Molecular Hydrogen
journal, April 2006

  • Ozawa, Hironobu; Haga, Masa-aki; Sakai, Ken
  • Journal of the American Chemical Society, Vol. 128, Issue 15
  • DOI: 10.1021/ja058087h

Cobaloxime-Based Photocatalytic Devices for Hydrogen Production
journal, January 2008

  • Fihri, Aziz; Artero, Vincent; Razavet, Mathieu
  • Angewandte Chemie International Edition, Vol. 47, Issue 3
  • DOI: 10.1002/anie.200702953

Photophysics of an Intramolecular Hydrogen-Evolving Ru-Pd Photocatalyst
journal, August 2009

  • Tschierlei, Stefanie; Presselt, Martin; Kuhnt, Christian
  • Chemistry - A European Journal, Vol. 15, Issue 31
  • DOI: 10.1002/chem.200900457

Photochemical Fate: The First Step Determines Efficiency of H2 Formation with a Supramolecular Photocatalyst
journal, April 2010

  • Tschierlei, Stefanie; Karnahl, Michael; Presselt, Martin
  • Angewandte Chemie International Edition, Vol. 49, Issue 23
  • DOI: 10.1002/anie.200906595

Powering the future of molecular artificial photosynthesis with light-harvesting metallosupramolecular dye assemblies
journal, January 2013

  • Frischmann, Peter D.; Mahata, Kingsuk; Würthner, Frank
  • Chem. Soc. Rev., Vol. 42, Issue 4
  • DOI: 10.1039/C2CS35223K

Recent progress in the development of bimetallic photocatalysts for hydrogen generation
journal, January 2013

  • Halpin, Yvonne; Pryce, Mary T.; Rau, Sven
  • Dalton Transactions, Vol. 42, Issue 46
  • DOI: 10.1039/c3dt52319e

Subtle Changes to Peripheral Ligands Enable High Turnover Numbers for Photocatalytic Hydrogen Generation with Supramolecular Photocatalysts
journal, February 2016

Peripheral ligands as electron storage reservoirs and their role in enhancement of photocatalytic hydrogen generation
journal, January 2016

  • Pan, Qing; Freitag, Leon; Kowacs, Tanja
  • Chemical Communications, Vol. 52, Issue 60
  • DOI: 10.1039/C6CC05222C

Molecular devices featuring sequential photoinduced charge separations for the storage of multiple redox equivalents
journal, November 2011

The role of the bridging ligand in photocatalytic supramolecular assemblies for the reduction of protons and carbon dioxide
journal, August 2012

  • Schulz, Martin; Karnahl, Michael; Schwalbe, Matthias
  • Coordination Chemistry Reviews, Vol. 256, Issue 15-16
  • DOI: 10.1016/j.ccr.2012.02.016

Energy transfer and trapping in photosynthesis
journal, August 1994

  • van Grondelle, Rienk; Dekker, Jan P.; Gillbro, Tomas
  • Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1187, Issue 1
  • DOI: 10.1016/0005-2728(94)90166-X

Understanding the Energy Transfer Function of LHCII, the Major Light-Harvesting Complex of Green Plants
journal, January 2001

  • van Amerongen, Herbert; van Grondelle, Rienk
  • The Journal of Physical Chemistry B, Vol. 105, Issue 3
  • DOI: 10.1021/jp0028406

Crystal structure of spinach major light-harvesting complex at 2.72 Å resolution
journal, March 2004

  • Liu, Zhenfeng; Yan, Hanchi; Wang, Kebin
  • Nature, Vol. 428, Issue 6980
  • DOI: 10.1038/nature02373

Energy transfer in photosynthesis: experimental insights and quantitative models
journal, January 2006

  • van Grondelle, Rienk; Novoderezhkin, Vladimir I.
  • Phys. Chem. Chem. Phys., Vol. 8, Issue 7
  • DOI: 10.1039/B514032C

Lessons from nature about solar light harvesting
journal, September 2011

  • Scholes, Gregory D.; Fleming, Graham R.; Olaya-Castro, Alexandra
  • Nature Chemistry, Vol. 3, Issue 10
  • DOI: 10.1038/nchem.1145

An Efficient Ru II -Rh III -Ru II Polypyridyl Photocatalyst for Visible-Light-Driven Hydrogen Production in Aqueous Solution
journal, January 2014

  • Stoll, Thibaut; Gennari, Marcello; Fortage, Jérôme
  • Angewandte Chemie International Edition, Vol. 53, Issue 6
  • DOI: 10.1002/anie.201308132

Photocatalytic Hydrogen Production from Water Employing A Ru, Rh, Ru Molecular Device for Photoinitiated Electron Collection
journal, September 2007

  • Elvington, Mark; Brown, Jared; Arachchige, Shamindri M.
  • Journal of the American Chemical Society, Vol. 129, Issue 35
  • DOI: 10.1021/ja073123t

Efficient Photocatalytic Hydrogen Production in a Single-Component System Using Ru,Rh,Ru Supramolecules Containing 4,7-Diphenyl-1,10-Phenanthroline
journal, October 2011

  • White, Travis A.; Higgins, Samantha L. H.; Arachchige, Shamindri M.
  • Angewandte Chemie International Edition, Vol. 50, Issue 51
  • DOI: 10.1002/anie.201105170

Electrochemistry of rhodium-dipyridyl complexes
journal, March 1974

  • Kew, Gregory; DeArmond, Keith; Hanck, Kenneth
  • The Journal of Physical Chemistry, Vol. 78, Issue 7
  • DOI: 10.1021/j100600a017

Designing Dendrimers Based on Transition-Metal Complexes. Light-Harvesting Properties and Predetermined Redox Patterns
journal, January 1998

  • Balzani, Vincenzo; Campagna, Sebastiano; Denti, Gianfranco
  • Accounts of Chemical Research, Vol. 31, Issue 1
  • DOI: 10.1021/ar950202d

Emission Spectroscopy as a Probe into Photoinduced Intramolecular Electron Transfer in Polyazine Bridged Ru(II),Rh(III) Supramolecular Complexes
journal, August 2010

  • White, Travis; Arachchige, Shamindri; Sedai, Baburam
  • Materials, Vol. 3, Issue 8
  • DOI: 10.3390/ma3084328

Photophysics and photoredox reactions of ligand-bridged binuclear polypyridyl complexes of ruthenium(II) and of their monomeric analogs
journal, May 1990

  • Kalyanasundaram, K.; Nazeeruddin, M. K.
  • Inorganic Chemistry, Vol. 29, Issue 10
  • DOI: 10.1021/ic00335a026

Photodriven heterogeneous charge transfer with transition-metal compounds anchored to TiO 2 semiconductor surfaces
journal, January 2009

  • Ardo, Shane; Meyer, Gerald J.
  • Chem. Soc. Rev., Vol. 38, Issue 1
  • DOI: 10.1039/B804321N

Low Quantum Yields of Relaxed Electron Transfer Products of Moderately Coupled Ruthenium(II)−Cobalt(III) Compounds on the Subpicosecond Laser Excitation
journal, June 2004

  • Torieda, Hiroaki; Nozaki, Koichi; Yoshimura, Akio
  • The Journal of Physical Chemistry A, Vol. 108, Issue 22
  • DOI: 10.1021/jp037259z

Visualizing the non-equilibrium dynamics of photoinduced intramolecular electron transfer with femtosecond X-ray pulses
journal, March 2015

  • Canton, Sophie E.; Kjær, Kasper S.; Vankó, György
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7359

Femtosecond Dynamics of Excited-State Evolution in [Ru(bpy)3]2+
journal, January 1997

Femtosecond Absorption Spectroscopy of Transition Metal Charge-Transfer Complexes
journal, December 2003

  • McCusker, James K.
  • Accounts of Chemical Research, Vol. 36, Issue 12
  • DOI: 10.1021/ar030111d

Broadband Femtosecond Fluorescence Spectroscopy of [Ru(bpy)3]2+
journal, May 2006

  • Cannizzo, Andrea; van Mourik, Frank; Gawelda, Wojciech
  • Angewandte Chemie International Edition, Vol. 45, Issue 19
  • DOI: 10.1002/anie.200600125

The Early Picosecond Photophysics of Ru(II) Polypyridyl Complexes: A Tale of Two Timescales
journal, April 2008

  • Henry, William; Coates, Colin G.; Brady, Clare
  • The Journal of Physical Chemistry A, Vol. 112, Issue 20
  • DOI: 10.1021/jp711873s

Ultrafast Energy Transfer in Binuclear Ruthenium−Osmium Complexes as Models for Light-harvesting Antennas
journal, May 2002

  • Baudin, Helena Berglund; Davidsson, Jan; Serroni, Scolastica
  • The Journal of Physical Chemistry A, Vol. 106, Issue 17
  • DOI: 10.1021/jp012770i

Ultrafast singlet energy transfer competes with intersystem crossing in a multi-center transition metal polypyridine complex
journal, March 2004

Ultrafast Processes in Bimetallic Dyads with Extended Aromatic Bridges. Energy and Electron Transfer Pathways in Tetrapyridophenazine-Bridged Complexes
journal, January 2003

  • Chiorboli, Claudio; Rodgers, Michael A. J.; Scandola, Franco
  • Journal of the American Chemical Society, Vol. 125, Issue 2
  • DOI: 10.1021/ja0284916

Photoinduced Electron Transfer across Oligo- p -phenylene Bridges. Distance and Conformational Effects in Ru(II)−Rh(III) Dyads
journal, July 2007

  • Indelli, Maria Teresa; Chiorboli, Claudio; Flamigni, Lucia
  • Inorganic Chemistry, Vol. 46, Issue 14
  • DOI: 10.1021/ic700430u

Electron transfers in chemistry and biology
journal, August 1985

  • Marcus, R. A.; Sutin, Norman
  • Biochimica et Biophysica Acta (BBA) - Reviews on Bioenergetics, Vol. 811, Issue 3
  • DOI: 10.1016/0304-4173(85)90014-X

Excited-state interactions in ligand-bridged chromophore-quencher complexes containing rhodium(III) and ruthenium(II) polypyridyl units
journal, July 1992

  • Kalyanasundaram, K.; Graetzel, M.; Nazeeruddin, M. K.
  • The Journal of Physical Chemistry, Vol. 96, Issue 14
  • DOI: 10.1021/j100193a041

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    journal, January 2020

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    • Chemical Society Reviews, Vol. 49, Issue 3
    • DOI: 10.1039/c8cs00660a

    Water‐Soluble Conjugated Molecule for Solar‐Driven Hydrogen Evolution from Salt Water
    journal, February 2019

    • Yang, Xiye; Hu, Zhicheng; Yin, Qingwu
    • Advanced Functional Materials, Vol. 29, Issue 13
    • DOI: 10.1002/adfm.201808156

    Tethered sensitizer–catalyst noble-metal-free molecular devices for solar-driven hydrogen generation
    journal, January 2018

    • Luo, Geng-Geng; Pan, Zhong-Hua; Lin, Jin-Qing
    • Dalton Transactions, Vol. 47, Issue 44
    • DOI: 10.1039/c8dt02831a

    Photocatalytic H 2 Evolution Using a Ru Chromophore Tethered to Six Viologen Acceptors
    journal, October 2018

    • Yamamoto, Keiya; Call, Arnau; Sakai, Ken
    • Chemistry - A European Journal, Vol. 24, Issue 62
    • DOI: 10.1002/chem.201803662

    BIAN-Fluorene Copolymer Bearing Ruthenium Pendant as Sensitizer of Titanium Nanotubes for Photocatalytic Hydrogen Evolution
    journal, January 2018

    • Patnaik, S. G.; Gagan, R. K.; Vedarajan, R.
    • Journal of The Electrochemical Society, Vol. 165, Issue 15
    • DOI: 10.1149/2.0231815jes