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Title: Poly(naphthalene diimide) vinylene: solid state red emission and semiconducting properties for transistors

Here in this work, a conjugated polymer PNV is developed, linking naphthalene diimide with a vinyl linkage. Owing to the C-H ∙∙∙O hydrogen bond between the carbonyl and the vinyl, PNV exhibits a high red emission with a quantum yield of 33.4% in the solid state while it shows n-type properties with an electron mobility up to 1.5 x 10 -3 cm 2 V -1 s -1 in organic field effect transistors, simultaneously.
Authors:
 [1] ; ORCiD logo [2] ; ORCiD logo [3] ;  [3] ;  [3] ;  [4] ;  [2] ;  [2] ;  [5] ; ORCiD logo [6]
  1. Chongqing Univ. (China). School of Chemistry and Chemical Engineering; Yunnan Minzu Univ., Kunming (China). YMU-HKBU Joint Lab. of Traditional Natural Medicine
  2. Chongqing Univ. (China). School of Chemistry and Chemical Engineering
  3. Chinese Academy of Sciences (CAS), Beijing (China). Inst. of Chemistry. Beijing National Lab. for Molecular Sciences
  4. Yunnan Minzu Univ., Kunming (China). YMU-HKBU Joint Lab. of Traditional Natural Medicine
  5. Chinese Academy of Sciences (CAS), Chongqing (China). Chongqing Inst. of Green and Intelligent Technology
  6. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Univ. of Chicago, IL (United States). Inst. for Molecular Engineering
Publication Date:
Grant/Contract Number:
AC02-06CH11357
Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 53; Journal Issue: 36; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Research Org:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Natural Science Foundation of China (NNSFC); Chinese Academy of Sciences (CAS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1364439