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Title: CO 2 capture in the sustainable wheat-derived activated microporous carbon compartments

Here, microporous carbon compartments (MCCs) were developed via controlled carbonization of wheat flour producing large cavities that allow CO 2 gas molecules to access micropores and adsorb effectively. KOH activation of MCCs was conducted at 700 °C with varying mass ratios of KOH/C ranging from 1 to 5, and the effects of activation conditions on the prepared carbon materials in terms of the characteristics and behavior of CO 2 adsorption were investigated. Textural properties, such as specific surface area and total pore volume, linearly increased with the KOH/C ratio, attributed to the development of pores and enlargement of pores within carbon. The highest CO 2 adsorption capacities of 5.70 mol kg -1 at 0 °C and 3.48 mol kg -1 at 25 °C were obtained for MCC activated with a KOH/C ratio of 3 (MCC-K3). In addition, CO 2 adsorption uptake was significantly dependent on the volume of narrow micropores with a pore size of less than 0.8 nm rather than the volume of larger pores or surface area. MCC-K3 also exhibited excellent cyclic stability, facile regeneration, and rapid adsorption kinetics. As compared to the pseudofirst-order model, the pseudo-second-order kinetic model described the experimental adsorption data methodically.
Authors:
 [1] ;  [1] ;  [2] ;  [2] ;  [1]
  1. Korea Univ., Seoul (Republic of Korea)
  2. Purdue Univ., West Lafayette, IN (United States)
Publication Date:
Grant/Contract Number:
EE0006832
Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Research Org:
Purdue Univ., West Lafayette, IN (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; climate-change mitigation; pollution remediation
OSTI Identifier:
1363896