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Title: π conjugation in the epitaxial Si(111)- 3 × 3 surface: Unconventional “bamboo hat” bonding geometry for Si

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Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
Grant/Contract Number:  
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Name: Physical Review B Journal Volume: 95 Journal Issue: 24; Journal ID: ISSN 2469-9950
American Physical Society
Country of Publication:
United States

Citation Formats

Jiang, Wei, Liu, Zheng, Zhou, Miao, Ni, Xiaojuan, and Liu, Feng. π conjugation in the epitaxial Si(111)- 3 × 3 surface: Unconventional “bamboo hat” bonding geometry for Si. United States: N. p., 2017. Web. doi:10.1103/PhysRevB.95.241405.
Jiang, Wei, Liu, Zheng, Zhou, Miao, Ni, Xiaojuan, & Liu, Feng. π conjugation in the epitaxial Si(111)- 3 × 3 surface: Unconventional “bamboo hat” bonding geometry for Si. United States. doi:10.1103/PhysRevB.95.241405.
Jiang, Wei, Liu, Zheng, Zhou, Miao, Ni, Xiaojuan, and Liu, Feng. Mon . "π conjugation in the epitaxial Si(111)- 3 × 3 surface: Unconventional “bamboo hat” bonding geometry for Si". United States. doi:10.1103/PhysRevB.95.241405.
title = {π conjugation in the epitaxial Si(111)- 3 × 3 surface: Unconventional “bamboo hat” bonding geometry for Si},
author = {Jiang, Wei and Liu, Zheng and Zhou, Miao and Ni, Xiaojuan and Liu, Feng},
abstractNote = {},
doi = {10.1103/PhysRevB.95.241405},
journal = {Physical Review B},
number = 24,
volume = 95,
place = {United States},
year = {2017},
month = {6}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1103/PhysRevB.95.241405

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Works referenced in this record:

Delocalized Surface State in Epitaxial Si(111) Film with Spontaneous √3 × √3 Superstructure
journal, August 2015

  • Chen, Jian; Du, Yi; Li, Zhi
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep13590

Surface states on Si(111)-(2×1)
journal, August 1981

Self-Organized Nanoscale Pattern Formation on Vicinal Si(111) Surfaces via a Two-Stage Faceting Transition
journal, February 2002

It Began with a Daydream: The 150th Anniversary of the Kekulé Benzene Structure
journal, September 2014

Modern Surface Science and Surface Technologies:  An Introduction
journal, January 1996

Multilayer silicene: clear evidence
journal, September 2016

Silicene-derived phases on Ag(111) substrate versus coverage: Ab initio studies
journal, January 2014

Buckled Silicene Formation on Ir(111)
journal, January 2013

  • Meng, Lei; Wang, Yeliang; Zhang, Lizhi
  • Nano Letters, Vol. 13, Issue 2, p. 685-690
  • DOI: 10.1021/nl304347w

Self-Assembled Si(111) Surface States: 2D Dirac Material for THz Plasmonics
journal, July 2015

The Structure of Graphite
journal, December 1924

  • Bernal, J. D.
  • Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 106, Issue 740
  • DOI: 10.1098/rspa.1924.0101

Surface Structures and Properties of Diamond-Structure Semiconductors
journal, February 1961

Surface Chemistry of Silicon
journal, July 1995

  • Neergaard Waltenburg, Hanne.; Yates, John T.
  • Chemical Reviews, Vol. 95, Issue 5
  • DOI: 10.1021/cr00037a600

Interface orbital engineering of large-gap topological states: Decorating gold on a Si(111) surface
journal, March 2016

Silicite: The layered allotrope of silicon
journal, August 2014

Spontaneous Symmetry Breaking and Dynamic Phase Transition in Monolayer Silicene
journal, February 2013

7 × 7 Reconstruction on Si(111) Resolved in Real Space
journal, January 1983

Two- and One-Dimensional Honeycomb Structures of Silicon and Germanium
journal, June 2009

Evidence for Dirac Fermions in a Honeycomb Lattice Based on Silicon
journal, August 2012

Epitaxial growth of large-gap quantum spin Hall insulator on semiconductor surface
journal, September 2014

  • Zhou, Miao; Ming, Wenmei; Liu, Zheng
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 40
  • DOI: 10.1073/pnas.1409701111

Semiconductor Surface Reconstruction:  The Structural Chemistry of Two-Dimensional Surface Compounds
journal, January 1996

Why sp 2 -like nanosilicons should not form: Insight from quantum chemistry
journal, March 2012

  • Sheka, E. F.
  • International Journal of Quantum Chemistry, Vol. 113, Issue 4
  • DOI: 10.1002/qua.24081

Relative stability of Si surfaces: A first-principles study
journal, August 2005

Silicene field-effect transistors operating at room temperature
journal, February 2015

  • Tao, Li; Cinquanta, Eugenio; Chiappe, Daniele
  • Nature Nanotechnology, Vol. 10, Issue 3
  • DOI: 10.1038/nnano.2014.325

Atomic and Electronic Structures of Reconstructed Si(100) Surfaces
journal, July 1979

Multilayered silicene: the bottom-up approach for a weakly relaxed Si(111) with Dirac surface states
journal, January 2015

Feier der Deutschen Chemischen Gesellschaft zu Ehren August Kekulé's
journal, January 1890

Overview of Silicon-Based Materials *
journal, October 1998

  • Matsumoto, Nobuo
  • Japanese Journal of Applied Physics, Vol. 37, Issue Part 1, No. 10
  • DOI: 10.1143/JJAP.37.5425

New Phases of Germanene
journal, July 2014

  • Özçelik, V. Ongun; Durgun, E.; Ciraci, Salim
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 15
  • DOI: 10.1021/jz500977v

Crossover between silicene and ultra-thin Si atomic layers on Ag(111) surfaces
journal, April 2015

Formation of quantum spin Hall state on Si surface and energy gap scaling with strength of spin orbit coupling
journal, November 2014

  • Zhou, Miao; Ming, Wenmei; Liu, Zheng
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep07102

Evidence of Dirac fermions in multilayer silicene
journal, April 2013

  • De Padova, Paola; Vogt, Patrick; Resta, Andrea
  • Applied Physics Letters, Vol. 102, Issue 16
  • DOI: 10.1063/1.4802782

The quasiparticle band dispersion in epitaxial multilayer silicene
journal, August 2013

New π -Bonded Chain Model for Si(111)-(2×1) Surface
journal, December 1981

Silicene: Compelling Experimental Evidence for Graphenelike Two-Dimensional Silicon
journal, April 2012

Silicon quantum electronics
journal, July 2013

  • Zwanenburg, Floris A.; Dzurak, Andrew S.; Morello, Andrea
  • Reviews of Modern Physics, Vol. 85, Issue 3
  • DOI: 10.1103/RevModPhys.85.961

Local Reconstructions of Silicene Induced by Adatoms
journal, December 2013

  • Özçelik, V. Ongun; Ciraci, S.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 49
  • DOI: 10.1021/jp408647t

Real-space observation of π -bonded chains and surface disorder on Si(111)2×1
journal, February 1986

Effect of Strain on Structure and Morphology of Ultrathin Ge Films on Si(001)
journal, June 1997

  • Liu, Feng; Wu, Fang; Lagally, M. G.
  • Chemical Reviews, Vol. 97, Issue 4
  • DOI: 10.1021/cr9600722

Surface Energy of Germanium and Silicon
journal, January 1963

  • Jaccodine, R. J.
  • Journal of The Electrochemical Society, Vol. 110, Issue 6
  • DOI: 10.1149/1.2425806