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Title: Bicarbonate Elution of Uranium from Amidoxime-Based Polymer Adsorbents for Sequestering Uranium from Seawater

Uranium adsorbed on amidoxime-based polyethylene fibers in simulated seawater can be quantitatively eluted using 3 M KHCO 3 at 40°C. Thermodynamic calculations are in agreement with the experimental observation that at high bicarbonate concentrations (3 M) uranyl ions bound to amidoxime molecules are converted to uranyl tris-carbonato complex in the aqueous solution. The elution process is basically the reverse reaction of the uranium adsorption process which occurs at a very low bicarbonate concentration (~10 -3 M) in seawater. The bicarbonate elution is followed by a NaOH treatment to remove natural organic matter adsorbed on the polymer adsorbent, in real seawater experiments. Furthermore, by using the sequential bicarbonate and NaOH elution, the adsorbent is reusable after rinsing with deionized water and the recycled adsorbent shows no loss of uranium loading capacity based on real seawater experiments.
Authors:
 [1] ;  [1] ;  [2] ;  [2] ;  [3] ;  [3] ;  [4] ;  [4] ;  [4]
  1. Univ. of Idaho, Moscow, ID (United States). Dept. of Chemistry
  2. Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Marine Sciences Lab.
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Publication Date:
Grant/Contract Number:
AC05-00OR22725; 00042246
Type:
Accepted Manuscript
Journal Name:
Chemistry Select
Additional Journal Information:
Journal Volume: 2; Journal Issue: 13; Journal ID: ISSN 2365-6549
Publisher:
Wiley
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE Office of Nuclear Energy (NE)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; uranium; polyethyethylene; amidoxime; bicarbonate; seawater
OSTI Identifier:
1362216
Alternate Identifier(s):
OSTI ID: 1400853

Pan, Horng-Bin, Wai, Chien M., Kuo, Li-Jung, Gill, Gary, Tian, Guoxin, Rao, Linfeng, Das, Sadananda, Mayes, Richard T., and Janke, Christopher J.. Bicarbonate Elution of Uranium from Amidoxime-Based Polymer Adsorbents for Sequestering Uranium from Seawater. United States: N. p., Web. doi:10.1002/slct.201700177.
Pan, Horng-Bin, Wai, Chien M., Kuo, Li-Jung, Gill, Gary, Tian, Guoxin, Rao, Linfeng, Das, Sadananda, Mayes, Richard T., & Janke, Christopher J.. Bicarbonate Elution of Uranium from Amidoxime-Based Polymer Adsorbents for Sequestering Uranium from Seawater. United States. doi:10.1002/slct.201700177.
Pan, Horng-Bin, Wai, Chien M., Kuo, Li-Jung, Gill, Gary, Tian, Guoxin, Rao, Linfeng, Das, Sadananda, Mayes, Richard T., and Janke, Christopher J.. 2017. "Bicarbonate Elution of Uranium from Amidoxime-Based Polymer Adsorbents for Sequestering Uranium from Seawater". United States. doi:10.1002/slct.201700177. https://www.osti.gov/servlets/purl/1362216.
@article{osti_1362216,
title = {Bicarbonate Elution of Uranium from Amidoxime-Based Polymer Adsorbents for Sequestering Uranium from Seawater},
author = {Pan, Horng-Bin and Wai, Chien M. and Kuo, Li-Jung and Gill, Gary and Tian, Guoxin and Rao, Linfeng and Das, Sadananda and Mayes, Richard T. and Janke, Christopher J.},
abstractNote = {Uranium adsorbed on amidoxime-based polyethylene fibers in simulated seawater can be quantitatively eluted using 3 M KHCO3 at 40°C. Thermodynamic calculations are in agreement with the experimental observation that at high bicarbonate concentrations (3 M) uranyl ions bound to amidoxime molecules are converted to uranyl tris-carbonato complex in the aqueous solution. The elution process is basically the reverse reaction of the uranium adsorption process which occurs at a very low bicarbonate concentration (~10-3 M) in seawater. The bicarbonate elution is followed by a NaOH treatment to remove natural organic matter adsorbed on the polymer adsorbent, in real seawater experiments. Furthermore, by using the sequential bicarbonate and NaOH elution, the adsorbent is reusable after rinsing with deionized water and the recycled adsorbent shows no loss of uranium loading capacity based on real seawater experiments.},
doi = {10.1002/slct.201700177},
journal = {Chemistry Select},
number = 13,
volume = 2,
place = {United States},
year = {2017},
month = {5}
}