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Title: High-energy x-ray scattering studies of battery materials

Abstract

High-energy x-ray (HEX) scattering is a sensitive and powerful tool to nondestructively probe the atomic and mesoscale structures of battery materials under synthesis and operational conditions. The penetration power of HEXs enables the use of large, practical samples and realistic environments, allowing researchers to explore the inner workings of batteries in both laboratory and commercial formats. This article highlights the capability and versatility of HEX techniques, particularly from synchrotron sources, to elucidate materials synthesis processes and thermal instability mechanisms in situ, to understand (dis)charging mechanisms in operando under a variety of cycling conditions, and to spatially resolve electrode/electrolyte responses to highlight connections between inhomogeneity and performance. Such studies have increased our understanding of the fundamental mechanisms underlying battery performance. Here, by deepening our understanding of the linkages between microstructure and overall performance, HEXs represent a powerful tool for validating existing batteries and shortening battery-development timelines.

Authors:
 [1];  [2];  [2];  [2]
  1. Northwestern Univ., Evanston, IL (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1362123
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
MRS Bulletin
Additional Journal Information:
Journal Volume: 41; Journal Issue: 06; Journal ID: ISSN 0883-7694
Publisher:
Materials Research Society
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 36 MATERIALS SCIENCE

Citation Formats

Glazer, Matthew P. B., Okasinski, John S., Almer, Jonathan D., and Ren, Yang. High-energy x-ray scattering studies of battery materials. United States: N. p., 2016. Web. doi:10.1557/mrs.2016.96.
Glazer, Matthew P. B., Okasinski, John S., Almer, Jonathan D., & Ren, Yang. High-energy x-ray scattering studies of battery materials. United States. doi:10.1557/mrs.2016.96.
Glazer, Matthew P. B., Okasinski, John S., Almer, Jonathan D., and Ren, Yang. Wed . "High-energy x-ray scattering studies of battery materials". United States. doi:10.1557/mrs.2016.96. https://www.osti.gov/servlets/purl/1362123.
@article{osti_1362123,
title = {High-energy x-ray scattering studies of battery materials},
author = {Glazer, Matthew P. B. and Okasinski, John S. and Almer, Jonathan D. and Ren, Yang},
abstractNote = {High-energy x-ray (HEX) scattering is a sensitive and powerful tool to nondestructively probe the atomic and mesoscale structures of battery materials under synthesis and operational conditions. The penetration power of HEXs enables the use of large, practical samples and realistic environments, allowing researchers to explore the inner workings of batteries in both laboratory and commercial formats. This article highlights the capability and versatility of HEX techniques, particularly from synchrotron sources, to elucidate materials synthesis processes and thermal instability mechanisms in situ, to understand (dis)charging mechanisms in operando under a variety of cycling conditions, and to spatially resolve electrode/electrolyte responses to highlight connections between inhomogeneity and performance. Such studies have increased our understanding of the fundamental mechanisms underlying battery performance. Here, by deepening our understanding of the linkages between microstructure and overall performance, HEXs represent a powerful tool for validating existing batteries and shortening battery-development timelines.},
doi = {10.1557/mrs.2016.96},
journal = {MRS Bulletin},
number = 06,
volume = 41,
place = {United States},
year = {2016},
month = {6}
}

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Works referenced in this record:

Nanostructured high-energy cathode materials for advanced lithium batteries
journal, October 2012

  • Sun, Yang-Kook; Chen, Zonghai; Noh, Hyung-Joo
  • Nature Materials, Vol. 11, Issue 11
  • DOI: 10.1038/nmat3435

Progress Toward an Ultimate Storage Ring Light Source
journal, March 2013


Tracking inhomogeneity in high-capacity lithium iron phosphate batteries
journal, February 2015


Three-dimensional distribution of polymorphs and magnesium in a calcified underwater attachment system by diffraction tomography
journal, September 2013

  • Leemreize, Hanna; Almer, Jonathan D.; Stock, Stuart R.
  • Journal of The Royal Society Interface, Vol. 10, Issue 86
  • DOI: 10.1098/rsif.2013.0319

In situ visualization of Li/Ag2VP2O8 batteries revealing rate-dependent discharge mechanism
journal, January 2015


Ultimate upgrade for US synchrotron
journal, September 2013


High-energy X-ray optics with silicon saw-tooth refractive lenses
journal, February 2007


Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes
journal, June 2014


Rate-Dependent, Li-Ion Insertion/Deinsertion Behavior of LiFePO 4 Cathodes in Commercial 18650 LiFePO 4 Cells
journal, February 2014

  • Liu, Qi; He, Hao; Li, Zhe-Fei
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 5
  • DOI: 10.1021/am405150c

Synthesis of full concentration gradient cathode studied by high energy X-ray diffraction
journal, January 2016


The migration mechanism of transition metal ions in LiNi 0.5 Mn 1.5 O 4
journal, January 2015

  • Xu, Gui-Liang; Qin, Yan; Ren, Yang
  • Journal of Materials Chemistry A, Vol. 3, Issue 24
  • DOI: 10.1039/C5TA02522B

New class of nonaqueous electrolytes for long-life and safe lithium-ion batteries
journal, February 2013

  • Chen, Zonghai; Ren, Yang; Jansen, Andrew N.
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2518

High-Energy X-Rays: A tool for Advanced Bulk Investigations in Materials Science and Physics
journal, January 2003


Three-dimensional maps of grain boundaries and the stress state of individual grains in polycrystals and powders
journal, November 2001

  • Poulsen, H. F.; Nielsen, S. F.; Lauridsen, E. M.
  • Journal of Applied Crystallography, Vol. 34, Issue 6
  • DOI: 10.1107/S0021889801014273

In situ X-ray diffraction of prototype sodium metal halide cells: Time and space electrochemical profiling
journal, February 2011


Graphene-modified nanostructured vanadium pentoxide hybrids with extraordinary electrochemical performance for Li-ion batteries
journal, January 2015

  • Liu, Qi; Li, Zhe-Fei; Liu, Yadong
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7127

Solid state synthesis of LiFePO4 studied by in situ high energy X-ray diffraction
journal, January 2011

  • Chen, Zonghai; Ren, Yang; Qin, Yan
  • Journal of Materials Chemistry, Vol. 21, Issue 15
  • DOI: 10.1039/c0jm04049e

Study of Thermal Decomposition of Li 1-x (Ni 1/3 Mn 1/3 Co 1/3 ) 0.9 O 2 Using In-Situ High-Energy X-Ray Diffraction
journal, March 2013

  • Chen, Zonghai; Ren, Yang; Lee, Eungje
  • Advanced Energy Materials, Vol. 3, Issue 6
  • DOI: 10.1002/aenm.201201059

Holotomography: Quantitative phase tomography with micrometer resolution using hard synchrotron radiation x rays
journal, November 1999

  • Cloetens, P.; Ludwig, W.; Baruchel, J.
  • Applied Physics Letters, Vol. 75, Issue 19
  • DOI: 10.1063/1.125225

Single-crystal diffraction at megabar conditions by synchrotron radiation
journal, August 2013


In Operando Strain Measurement of Bicontinuous Silicon-Coated Nickel Inverse Opal Anodes for Li-Ion Batteries
journal, May 2015

  • Glazer, Matthew P. B.; Cho, Jiung; Almer, Jonathan
  • Advanced Energy Materials, Vol. 5, Issue 14
  • DOI: 10.1002/aenm.201500466

Nanoscale strain mapping in battery nanostructures
journal, February 2014

  • Ulvestad, A.; Cho, H. M.; Harder, R.
  • Applied Physics Letters, Vol. 104, Issue 7
  • DOI: 10.1063/1.4866030