skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: CRF-PEPICO: Double velocity map imaging photoelectron photoion coincidence spectroscopy for reaction kinetics studies

Authors:
 [1];  [1];  [1];  [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [2];  [3]
  1. Department of Chemistry, University of the Pacific, Stockton, California 95211, USA
  2. Laboratory for Femtochemistry and Synchrotron Radiation, Paul Scherrer Institute (PSI), CH-5232 Villigen, Switzerland
  3. Combustion Research Facility, Sandia National Laboratories, Livermore, California 94551, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1361918
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Name: Journal of Chemical Physics Journal Volume: 147 Journal Issue: 1; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics
Country of Publication:
United States
Language:
English

Citation Formats

Sztáray, Bálint, Voronova, Krisztina, Torma, Krisztián G., Covert, Kyle J., Bodi, Andras, Hemberger, Patrick, Gerber, Thomas, and Osborn, David L. CRF-PEPICO: Double velocity map imaging photoelectron photoion coincidence spectroscopy for reaction kinetics studies. United States: N. p., 2017. Web. doi:10.1063/1.4984304.
Sztáray, Bálint, Voronova, Krisztina, Torma, Krisztián G., Covert, Kyle J., Bodi, Andras, Hemberger, Patrick, Gerber, Thomas, & Osborn, David L. CRF-PEPICO: Double velocity map imaging photoelectron photoion coincidence spectroscopy for reaction kinetics studies. United States. doi:10.1063/1.4984304.
Sztáray, Bálint, Voronova, Krisztina, Torma, Krisztián G., Covert, Kyle J., Bodi, Andras, Hemberger, Patrick, Gerber, Thomas, and Osborn, David L. Fri . "CRF-PEPICO: Double velocity map imaging photoelectron photoion coincidence spectroscopy for reaction kinetics studies". United States. doi:10.1063/1.4984304.
@article{osti_1361918,
title = {CRF-PEPICO: Double velocity map imaging photoelectron photoion coincidence spectroscopy for reaction kinetics studies},
author = {Sztáray, Bálint and Voronova, Krisztina and Torma, Krisztián G. and Covert, Kyle J. and Bodi, Andras and Hemberger, Patrick and Gerber, Thomas and Osborn, David L.},
abstractNote = {},
doi = {10.1063/1.4984304},
journal = {Journal of Chemical Physics},
number = 1,
volume = 147,
place = {United States},
year = {2017},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1063/1.4984304

Citation Metrics:
Cited by: 13 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

The Recombination of Propargyl Radicals:  Solving the Master Equation
journal, August 2001

  • Miller, James A.; Klippenstein, Stephen J.
  • The Journal of Physical Chemistry A, Vol. 105, Issue 30
  • DOI: 10.1021/jp0102973

Detailed mechanism of the CH 2 I + O 2 reaction: Yield and self-reaction of the simplest Criegee intermediate CH 2 OO
journal, September 2014

  • Ting, Wei-Lun; Chang, Chun-Hung; Lee, Yu-Fang
  • The Journal of Chemical Physics, Vol. 141, Issue 10
  • DOI: 10.1063/1.4894405

Advances in threshold photoelectron spectroscopy (TPES) and threshold photoelectron photoion coincidence (TPEPICO)
journal, January 2017

  • Baer, Tomas; Tuckett, Richard P.
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 15
  • DOI: 10.1039/C7CP00144D

Vacuum ultraviolet photoionization mass spectrometric study of C 6 0
journal, January 1992

  • Yoo, R. K.; Ruscic, B.; Berkowitz, J.
  • The Journal of Chemical Physics, Vol. 96, Issue 2
  • DOI: 10.1063/1.462112

Rate constants for reactions of substituted methyl radicals (CH2OCH3, CH2NH2, CH2I, and CH2CN) with O2
journal, August 1995

  • Masaki, Akira; Tsunashima, Shigeru; Washida, Nobuaki
  • The Journal of Physical Chemistry, Vol. 99, Issue 35
  • DOI: 10.1021/j100035a014

Absolute Ultraviolet Absorption Spectrum of a Criegee Intermediate CH 2 OO
journal, November 2013

  • Sheps, Leonid
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 24
  • DOI: 10.1021/jz402191w

Isomer-specific product detection of CN radical reactions with ethene and propene by tunable VUV photoionization mass spectrometry
journal, February 2009

  • Trevitt, Adam J.; Goulay, Fabien; Meloni, Giovanni
  • International Journal of Mass Spectrometry, Vol. 280, Issue 1-3
  • DOI: 10.1016/j.ijms.2008.07.033

Reaction Mechanisms of IO Radical Formation from the Reaction of CH 3 I with Cl Atom in the Presence of O 2
journal, October 2008

  • Enami, Shinichi; Sakamoto, Yosuke; Yamanaka, Takashi
  • Bulletin of the Chemical Society of Japan, Vol. 81, Issue 10
  • DOI: 10.1246/bcsj.81.1250

Photoelectron and photofragment velocity map imaging of state-selected molecular oxygen dissociation/ionization dynamics
journal, August 1997

  • Parker, D. H.; Eppink, A. T. J. B.
  • The Journal of Chemical Physics, Vol. 107, Issue 7
  • DOI: 10.1063/1.474624

On the adiabatic ionization energy of the propargyl radical
journal, August 2013

  • Jacovella, U.; Gans, B.; Merkt, F.
  • The Journal of Chemical Physics, Vol. 139, Issue 8
  • DOI: 10.1063/1.4818982

Directly measuring reaction kinetics of ˙QOOH – a crucial but elusive intermediate in hydrocarbon autoignition
journal, January 2013

  • Zádor, Judit; Huang, Haifeng; Welz, Oliver
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 26
  • DOI: 10.1039/c3cp51185e

Photoionization and dissociative photoionization of the allyl radical, C3H5
journal, March 2007

  • Fischer, Ingo; Schüßler, Thomas; Deyerl, Hans-Jürgen
  • International Journal of Mass Spectrometry, Vol. 261, Issue 2-3
  • DOI: 10.1016/j.ijms.2006.09.023

New particle formation from photooxidation of diiodomethane (CH 2 I 2 )
journal, January 2003


The first bands in the photoelectron spectra of the bromomethyl, bromomethyl-d2, dibromomethyl, and iodomethyl free radicals
journal, May 1984

  • Andrews, Lester; Dyke, John M.; Jonathan, Neville
  • The Journal of Physical Chemistry, Vol. 88, Issue 10
  • DOI: 10.1021/j150654a007

A spectrokinetic study of CH2I and CH2IO2 radicals
journal, February 1994

  • Sehested, Jens; Ellermann, Thomas; Nielsen, Ole John
  • International Journal of Chemical Kinetics, Vol. 26, Issue 2
  • DOI: 10.1002/kin.550260204

Photodissociation dynamics of the propargyl radical
journal, August 1999

  • Deyerl, Hans-Jürgen; Fischer, Ingo; Chen, Peter
  • The Journal of Chemical Physics, Vol. 111, Issue 8
  • DOI: 10.1063/1.479629

A versatile electron-ion coincidence spectrometer for photoelectron momentum imaging and threshold spectroscopy on mass selected ions using synchrotron radiation
journal, February 2009

  • Garcia, Gustavo A.; Soldi-Lose, Héloïse; Nahon, Laurent
  • Review of Scientific Instruments, Vol. 80, Issue 2
  • DOI: 10.1063/1.3079331

Time‐of‐Flight Mass Spectrometer with Improved Resolution
journal, December 1955

  • Wiley, W. C.; McLaren, I. H.
  • Review of Scientific Instruments, Vol. 26, Issue 12
  • DOI: 10.1063/1.1715212

Improved sliced velocity map imaging apparatus optimized for H photofragments
journal, April 2013

  • Ryazanov, Mikhail; Reisler, Hanna
  • The Journal of Chemical Physics, Vol. 138, Issue 14
  • DOI: 10.1063/1.4798929

Isomer-Specific Product Detection of Gas-Phase Xylyl Radical Rearrangement and Decomposition Using VUV Synchrotron Photoionization
journal, April 2014

  • Hemberger, Patrick; Trevitt, Adam J.; Gerber, Thomas
  • The Journal of Physical Chemistry A, Vol. 118, Issue 20
  • DOI: 10.1021/jp501117n

Kinetic and thermodynamic issues in the formation of aromatic compounds in flames of aliphatic fuels
journal, October 1992


Kinetics of the reactions of CH2Br and CH2I radicals with molecular oxygen at atmospheric temperatures
journal, January 2006

  • Eskola, Arkke J.; Wojcik-Pastuszka, Dorota; Ratajczak, Emil
  • Physical Chemistry Chemical Physics, Vol. 8, Issue 12
  • DOI: 10.1039/b516291b

Direct Observation of the Gas-Phase Criegee Intermediate (CH 2 OO)
journal, September 2008

  • Taatjes, Craig A.; Meloni, Giovanni; Selby, Talitha M.
  • Journal of the American Chemical Society, Vol. 130, Issue 36
  • DOI: 10.1021/ja804165q

Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I with O2
journal, January 2012


Photoionization of Propargyl and Bromopropargyl Radicals: A Threshold Photoelectron Spectroscopic Study
journal, March 2011

  • Hemberger, Patrick; Lang, Melanie; Noller, Bastian
  • The Journal of Physical Chemistry A, Vol. 115, Issue 11
  • DOI: 10.1021/jp112110j

A new double imaging velocity focusing coincidence experiment: i 2 PEPICO
journal, August 2012

  • Bodi, Andras; Hemberger, Patrick; Gerber, Thomas
  • Review of Scientific Instruments, Vol. 83, Issue 8
  • DOI: 10.1063/1.4742769

Absolute photoionization cross-section of the propargyl radical
journal, April 2012

  • Savee, John D.; Soorkia, Satchin; Welz, Oliver
  • The Journal of Chemical Physics, Vol. 136, Issue 13
  • DOI: 10.1063/1.3698282

Photoionization Cross Section of the Propargyl Radical and Some General Ideas for Estimating Radical Cross Sections
journal, December 2012

  • Xu, Hong; Pratt, S. T.
  • The Journal of Physical Chemistry A, Vol. 117, Issue 39
  • DOI: 10.1021/jp309874q

Vacuum Ultraviolet Photoionization of Complex Chemical Systems
journal, May 2016


Imaging photoelectron photoion coincidence spectroscopy with velocity focusing electron optics
journal, March 2009

  • Bodi, Andras; Johnson, Melanie; Gerber, Thomas
  • Review of Scientific Instruments, Vol. 80, Issue 3
  • DOI: 10.1063/1.3082016

CH2OO Criegee biradical yields following photolysis of CH2I2 in O2
journal, January 2013

  • Stone, Daniel; Blitz, Mark; Daubney, Laura
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 44
  • DOI: 10.1039/c3cp52466c

A photoion–photoelectron coincidence (PIPECO) study of fragmentation rates and kinetic energy release in energy selected metastable ions
journal, November 1975

  • Tsai, Bilin P.; Werner, Arthur S.; Baer, Tomas
  • The Journal of Chemical Physics, Vol. 63, Issue 10
  • DOI: 10.1063/1.431155

The multiplexed chemical kinetic photoionization mass spectrometer: A new approach to isomer-resolved chemical kinetics
journal, October 2008

  • Osborn, David L.; Zou, Peng; Johnsen, Howard
  • Review of Scientific Instruments, Vol. 79, Issue 10
  • DOI: 10.1063/1.3000004

Modeling unimolecular reactions in photoelectron photoion coincidence experiments
journal, September 2010

  • Sztáray, Bálint; Bodi, Andras; Baer, Tomas
  • Journal of Mass Spectrometry, Vol. 45, Issue 11
  • DOI: 10.1002/jms.1813

Data acquisition schemes for continuous two-particle time-of-flight coincidence experiments
journal, August 2007

  • Bodi, Andras; Sztáray, Bálint; Baer, Tomas
  • Review of Scientific Instruments, Vol. 78, Issue 8
  • DOI: 10.1063/1.2776012

THE C( 3 P) + NH 3 REACTION IN INTERSTELLAR CHEMISTRY. I. INVESTIGATION OF THE PRODUCT FORMATION CHANNELS
journal, October 2015

  • Bourgalais, Jérémy; Capron, Michael; Kailasanathan, Ranjith Kumar Abhinavam
  • The Astrophysical Journal, Vol. 812, Issue 2
  • DOI: 10.1088/0004-637x/812/2/106

Factors affecting lifetimes and resolution of Rydberg states observed in zero‐electron‐kinetic‐energy spectroscopy
journal, March 1993

  • Chupka, William A.
  • The Journal of Chemical Physics, Vol. 98, Issue 6
  • DOI: 10.1063/1.465011

Breaking through the false coincidence barrier in electron–ion coincidence experiments
journal, October 2016

  • Osborn, David L.; Hayden, Carl C.; Hemberger, Patrick
  • The Journal of Chemical Physics, Vol. 145, Issue 16
  • DOI: 10.1063/1.4965428

Direct observation and kinetics of a hydroperoxyalkyl radical (QOOH)
journal, February 2015


Photoionization and Pyrolysis of a 1,4-Azaborinine: Retro-Hydroboration in the Cation and Identification of Novel Organoboron Ring Systems
journal, June 2014

  • Holzmeier, Fabian; Lang, Melanie; Hemberger, Patrick
  • Chemistry - A European Journal, Vol. 20, Issue 31
  • DOI: 10.1002/chem.201402884

Isomeric identification of polycyclic aromatic hydrocarbons formed in combustion with tunable vacuum ultraviolet photoionization
journal, August 2006

  • Qi, Fei; Yang, Rui; Yang, Bin
  • Review of Scientific Instruments, Vol. 77, Issue 8
  • DOI: 10.1063/1.2234855

Reactions of Atomic Carbon with Butene Isomers: Implications for Molecular Growth in Carbon-Rich Environments
journal, November 2016

  • Bourgalais, J.; Spencer, Michael; Osborn, David L.
  • The Journal of Physical Chemistry A, Vol. 120, Issue 46
  • DOI: 10.1021/acs.jpca.6b09785

A threshold photoelectron-photoion coincidence spectrometer with double velocity imaging using synchrotron radiation
journal, November 2009

  • Tang, Xiaofeng; Zhou, Xiaoguo; Niu, Mingli
  • Review of Scientific Instruments, Vol. 80, Issue 11
  • DOI: 10.1063/1.3250872

Infrared Laser Absorption Measurements of the Kinetics of Propargyl Radical Self-Reaction and the 193 nm Photolysis of Propyne
journal, June 2003

  • DeSain, John D.; Taatjes, Craig A.
  • The Journal of Physical Chemistry A, Vol. 107, Issue 24
  • DOI: 10.1021/jp034047t

Universal crossed molecular beams apparatus with synchrotron photoionization mass spectrometric product detection
journal, September 1997

  • Yang, X.; Lin, J.; Lee, Y. T.
  • Review of Scientific Instruments, Vol. 68, Issue 9
  • DOI: 10.1063/1.1148291

The Recombination of Propargyl Radicals and Other Reactions on a C 6 H 6 Potential
journal, October 2003

  • Miller, James A.; Klippenstein, Stephen J.
  • The Journal of Physical Chemistry A, Vol. 107, Issue 39
  • DOI: 10.1021/jp030375h

DELICIOUS III: A multipurpose double imaging particle coincidence spectrometer for gas phase vacuum ultraviolet photodynamics studies
journal, May 2013

  • Garcia, G. A.; Cunha de Miranda, B. K.; Tia, M.
  • Review of Scientific Instruments, Vol. 84, Issue 5
  • DOI: 10.1063/1.4807751

Atmospheric Chemistry of Iodine
journal, October 2011

  • Saiz-Lopez, Alfonso; Plane, John M. C.; Baker, Alex R.
  • Chemical Reviews, Vol. 112, Issue 3
  • DOI: 10.1021/cr200029u

Flow tube studies of the C( 3 P) reactions with ethylene and propylene
journal, January 2015

  • Capron, Michael; Bourgalais, Jérémy; Abhinavam Kailasanathan, Ranjith Kumar
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 37
  • DOI: 10.1039/c5cp03918e

On the formation of cyclopentadiene in the C 3 H 5 ˙ + C 2 H 2 reaction
journal, January 2015

  • Bouwman, Jordy; Bodi, Andras; Oomens, Jos
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 32
  • DOI: 10.1039/c5cp02243f

Vacuum upgrade and enhanced performances of the double imaging electron/ion coincidence end-station at the vacuum ultraviolet beamline DESIRS
journal, December 2015

  • Tang, Xiaofeng; Garcia, Gustavo A.; Gil, Jean-François
  • Review of Scientific Instruments, Vol. 86, Issue 12
  • DOI: 10.1063/1.4937624

New mechanistic insights to the O(3P) + propene reaction from multiplexed photoionization mass spectrometry
journal, January 2012

  • Savee, John D.; Welz, Oliver; Taatjes, Craig A.
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 30
  • DOI: 10.1039/c2cp41200d

Suppression of hot electrons in threshold photoelectron photoion coincidence spectroscopy using velocity focusing optics
journal, August 2003

  • Sztáray, Bálint; Baer, Tomas
  • Review of Scientific Instruments, Vol. 74, Issue 8
  • DOI: 10.1063/1.1593788

Kinetics of free radicals produced by infrared multiphoton-induced decompositions. 1. Reactions of allyl radicals with nitrogen dioxide and bromine
journal, January 1981

  • Slagle, Irene R.; Yamada, Fumiaki; Gutman, David
  • Journal of the American Chemical Society, Vol. 103, Issue 1
  • DOI: 10.1021/ja00391a027

Pressure and Temperature Effects on Product Channels of the Propargyl (HC⋮CCH 2 ) Combination Reaction and the Formation of the “First Ring”
journal, November 2003

  • Howe, Pui-Teng; Fahr, Askar
  • The Journal of Physical Chemistry A, Vol. 107, Issue 45
  • DOI: 10.1021/jp0307497

Mass-Resolved Isomer-Selective Chemical Analysis with Imaging Photoelectron Photoion Coincidence Spectroscopy
journal, August 2013

  • Bodi, Andras; Hemberger, Patrick; Osborn, David L.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 17
  • DOI: 10.1021/jz401500c

Neutral and cationic heats of formation for ketene, methylketene, and dimethylketene
journal, January 2000


Pressure-Dependent I-Atom Yield in the Reaction of CH 2 I with O 2 Shows a Remarkable Apparent Third-Body Efficiency for O 2
journal, October 2012

  • Huang, Haifeng; Eskola, Arkke J.; Taatjes, Craig A.
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 22
  • DOI: 10.1021/jz301585c

The thermal decomposition of the benzyl radical in a heated micro-reactor. I. Experimental findings
journal, January 2015

  • Buckingham, Grant T.; Ormond, Thomas K.; Porterfield, Jessica P.
  • The Journal of Chemical Physics, Vol. 142, Issue 4
  • DOI: 10.1063/1.4906156