Quantitative Determination on Ionic-Liquid-Gating Control of Interfacial Magnetism
Abstract
Ionic-liquid gating on a functional thin film with a low voltage has drawn a lot of attention due to rich chemical, electronic, and magnetic phenomena at the interface. A key challenge in quantitative determination of voltage-controlled magnetic anisotropy (VCMA) in Au/[DEME]+[TFSI]-/Co field-effect transistor heterostructures is addressed. The magnetic anisotropy change as response to the gating voltage is precisely detected by in situ electron spin resonance measurements. Furthermore, a reversible change of magnetic anisotropy up to 219 Oe is achieved with a low gating voltage of 1.5 V at room temperature, corresponding to a record high VCMA coefficient of ≈146 Oe V-1. Two gating effects, the electrostatic doping and electrochemical reaction, are distinguished at various gating voltage regions, as confirmed by X-ray photoelectron spectroscopy and atomic force microscopy experiments. Our work shows a unique ionic-liquid-gating system for strong interfacial magnetoelectric coupling with many practical advantages, paving the way toward ion-liquid-gating spintronic/electronic devices.
- Authors:
-
- Xi'an Jiaotong Univ. (China). Electronic Materials Research Lab. and Key Laboratory of the Ministry of Education & International Center for Dielectric Research
- Xi'an Jiaotong Univ. (China). Electronic Materials Research Lab. and Key Laboratory of the Ministry of Education & International Center for Dielectric Research; Simon Fraser Univ., Burnaby, BC (Canada). Dept. of Chemistry and 4D Labs
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1360067
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Volume: 29; Journal Issue: 17; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Zhao, Shishun, Zhou, Ziyao, Peng, Bin, Zhu, Mingmin, Feng, Mengmeng, Yang, Qu, Yan, Yuan, Ren, Wei, Ye, Zuo-Guang, Liu, Yaohua, and Liu, Ming. Quantitative Determination on Ionic-Liquid-Gating Control of Interfacial Magnetism. United States: N. p., 2017.
Web. doi:10.1002/adma.201606478.
Zhao, Shishun, Zhou, Ziyao, Peng, Bin, Zhu, Mingmin, Feng, Mengmeng, Yang, Qu, Yan, Yuan, Ren, Wei, Ye, Zuo-Guang, Liu, Yaohua, & Liu, Ming. Quantitative Determination on Ionic-Liquid-Gating Control of Interfacial Magnetism. United States. https://doi.org/10.1002/adma.201606478
Zhao, Shishun, Zhou, Ziyao, Peng, Bin, Zhu, Mingmin, Feng, Mengmeng, Yang, Qu, Yan, Yuan, Ren, Wei, Ye, Zuo-Guang, Liu, Yaohua, and Liu, Ming. Fri .
"Quantitative Determination on Ionic-Liquid-Gating Control of Interfacial Magnetism". United States. https://doi.org/10.1002/adma.201606478. https://www.osti.gov/servlets/purl/1360067.
@article{osti_1360067,
title = {Quantitative Determination on Ionic-Liquid-Gating Control of Interfacial Magnetism},
author = {Zhao, Shishun and Zhou, Ziyao and Peng, Bin and Zhu, Mingmin and Feng, Mengmeng and Yang, Qu and Yan, Yuan and Ren, Wei and Ye, Zuo-Guang and Liu, Yaohua and Liu, Ming},
abstractNote = {Ionic-liquid gating on a functional thin film with a low voltage has drawn a lot of attention due to rich chemical, electronic, and magnetic phenomena at the interface. A key challenge in quantitative determination of voltage-controlled magnetic anisotropy (VCMA) in Au/[DEME]+[TFSI]-/Co field-effect transistor heterostructures is addressed. The magnetic anisotropy change as response to the gating voltage is precisely detected by in situ electron spin resonance measurements. Furthermore, a reversible change of magnetic anisotropy up to 219 Oe is achieved with a low gating voltage of 1.5 V at room temperature, corresponding to a record high VCMA coefficient of ≈146 Oe V-1. Two gating effects, the electrostatic doping and electrochemical reaction, are distinguished at various gating voltage regions, as confirmed by X-ray photoelectron spectroscopy and atomic force microscopy experiments. Our work shows a unique ionic-liquid-gating system for strong interfacial magnetoelectric coupling with many practical advantages, paving the way toward ion-liquid-gating spintronic/electronic devices.},
doi = {10.1002/adma.201606478},
journal = {Advanced Materials},
number = 17,
volume = 29,
place = {United States},
year = {Fri Mar 03 00:00:00 EST 2017},
month = {Fri Mar 03 00:00:00 EST 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 52 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Electrically induced enormous magnetic anisotropy in Terfenol-D/lead zinc niobate-lead titanate multiferroic heterostructures
journal, September 2012
- Liu, Ming; Li, Shandong; Zhou, Ziyao
- Journal of Applied Physics, Vol. 112, Issue 6
Probing electric field control of magnetism using ferromagnetic resonance
journal, January 2015
- Zhou, Ziyao; Trassin, Morgan; Gao, Ya
- Nature Communications, Vol. 6, Issue 1
Quantifying thickness-dependent charge mediated magnetoelectric coupling in magnetic/dielectric thin film heterostructures
journal, December 2013
- Zhou, Z.; Nan, T. X.; Gao, Y.
- Applied Physics Letters, Vol. 103, Issue 23
Self-Biased 215MHz Magnetoelectric NEMS Resonator for Ultra-Sensitive DC Magnetic Field Detection
journal, June 2013
- Nan, Tianxiang; Hui, Yu; Rinaldi, Matteo
- Scientific Reports, Vol. 3, Issue 1
Quantification of strain and charge co-mediated magnetoelectric coupling on ultra-thin Permalloy/PMN-PT interface
journal, January 2014
- Nan, Tianxiang; Zhou, Ziyao; Liu, Ming
- Scientific Reports, Vol. 4, Issue 1
Multiferroic Heterostructures Integrating Ferroelectric and Magnetic Materials
journal, November 2015
- Hu, Jia-Mian; Chen, Long-Qing; Nan, Ce-Wen
- Advanced Materials, Vol. 28, Issue 1
Electrostatic versus Electrochemical Doping and Control of Ferromagnetism in Ion-Gel-Gated Ultrathin La 0.5 Sr 0.5 CoO 3−δ
journal, July 2016
- Walter, Jeff; Wang, Helin; Luo, Bing
- ACS Nano, Vol. 10, Issue 8
E-Field Control of Exchange Bias and Deterministic Magnetization Switching in AFM/FM/FE Multiferroic Heterostructures
journal, May 2011
- Liu, Ming; Lou, Jing; Li, Shandong
- Advanced Functional Materials, Vol. 21, Issue 13
Large voltage-induced magnetic anisotropy change in a few atomic layers of iron
journal, January 2009
- Maruyama, T.; Shiota, Y.; Nozaki, T.
- Nature Nanotechnology, Vol. 4, Issue 3
Reversible Control of Co Magnetism by Voltage-Induced Oxidation
journal, December 2014
- Bi, Chong; Liu, Yaohua; Newhouse-Illige, T.
- Physical Review Letters, Vol. 113, Issue 26
Electric-Field-Induced Magnetization Reversal in a Ferromagnet-Multiferroic Heterostructure
journal, November 2011
- Heron, J. T.; Trassin, M.; Ashraf, K.
- Physical Review Letters, Vol. 107, Issue 21
Formation of a Stable p – n Junction in a Liquid-Gated MoS 2 Ambipolar Transistor
journal, June 2013
- Zhang, Y. J.; Ye, J. T.; Yomogida, Y.
- Nano Letters, Vol. 13, Issue 7
Collective bulk carrier delocalization driven by electrostatic surface charge accumulation
journal, July 2012
- Nakano, M.; Shibuya, K.; Okuyama, D.
- Nature, Vol. 487, Issue 7408
Voltage Tuning of Ferromagnetic Resonance with Bistable Magnetization Switching in Energy-Efficient Magnetoelectric Composites
journal, January 2013
- Liu, Ming; Zhou, Ziyao; Nan, Tianxiang
- Advanced Materials, Vol. 25, Issue 10
Electrical Manipulation of Orbital Occupancy and Magnetic Anisotropy in Manganites
journal, December 2014
- Cui, Bin; Song, Cheng; Gehring, Gillian A.
- Advanced Functional Materials, Vol. 25, Issue 6
Electric Field-Induced Modification of Magnetism in Thin-Film Ferromagnets
journal, January 2007
- Weisheit, M.; Fahler, S.; Marty, A.
- Science, Vol. 315, Issue 5810
Electric-field control of ferromagnetism
journal, December 2000
- Ohno, H.; Chiba, D.; Matsukura, F.
- Nature, Vol. 408, Issue 6815
Superconducting Dome in a Gate-Tuned Band Insulator
journal, November 2012
- Ye, J. T.; Zhang, Y. J.; Akashi, R.
- Science, Vol. 338, Issue 6111
Magneto-ionic control of interfacial magnetism
journal, November 2014
- Bauer, Uwe; Yao, Lide; Tan, Aik Jun
- Nature Materials, Vol. 14, Issue 2
Electrically Induced Ferromagnetism at Room Temperature in Cobalt-Doped Titanium Dioxide
journal, May 2011
- Yamada, Y.; Ueno, K.; Fukumura, T.
- Science, Vol. 332, Issue 6033
Electrical control of Curie temperature in cobalt using an ionic liquid film
journal, March 2012
- Shimamura, K.; Chiba, D.; Ono, S.
- Applied Physics Letters, Vol. 100, Issue 12
Metal-Insulator Transition Induced by Oxygen Vacancies from Electrochemical Reaction in Ionic Liquid-Gated Manganite Films
journal, September 2015
- Ge, Chen; Jin, Kui-Juan; Gu, Lin
- Advanced Materials Interfaces, Vol. 2, Issue 17
Magnetoelectric Effects in Complex Oxides with Competing Ground States
journal, September 2009
- Molegraaf, Hajo J. A.; Hoffman, Jason; Vaz, Carlos A. F.
- Advanced Materials, Vol. 21, Issue 34
Reversible Ferromagnetic Phase Transition in Electrode-Gated Manganites
journal, September 2014
- Cui, Bin; Song, Cheng; Wang, Guangyue
- Advanced Functional Materials, Vol. 24, Issue 46
Tuning the metal-insulator crossover and magnetism in SrRuO3 by ionic gating
journal, October 2014
- Yi, Hee Taek; Gao, Bin; Xie, Wei
- Scientific Reports, Vol. 4, Issue 1
Transport Properties of Polymer Semiconductor Controlled by Ionic Liquid as a Gate Dielectric and a Pressure Medium
journal, November 2013
- Shi, Wu; Ye, Jianting; Checkelsky, Joseph G.
- Advanced Functional Materials, Vol. 24, Issue 14
Electrochemical properties of novel ionic liquids for electric double layer capacitor applications
journal, September 2004
- Sato, Takaya; Masuda, Gen; Takagi, Kentaro
- Electrochimica Acta, Vol. 49, Issue 21
Predicted Magnetoelectric Effect in Multilayers: Ferroelectric Control of Magnetism
journal, July 2006
- Duan, Chun-Gang; Jaswal, S. S.; Tsymbal, E. Y.
- Physical Review Letters, Vol. 97, Issue 4
Giant Electric Field Tuning of Magnetic Properties in Multiferroic Ferrite/Ferroelectric Heterostructures
journal, June 2009
- Liu, Ming; Obi, Ogheneyunume; Lou, Jing
- Advanced Functional Materials, Vol. 19, Issue 11
Electric-double-layer field-effect transistors with ionic liquids
journal, January 2013
- Fujimoto, Takuya; Awaga, Kunio
- Physical Chemistry Chemical Physics, Vol. 15, Issue 23
Electric double-layer transistors: a review of recent progress
journal, June 2015
- Du, Haiwei; Lin, Xi; Xu, Zhemi
- Journal of Materials Science, Vol. 50, Issue 17
Hydrogenation-Induced Surface Polarity Recognition and Proton Memory Behavior at Protic-Ionic-Liquid/Oxide Electric-Double-Layer Interfaces
journal, May 2010
- Yuan, Hongtao; Shimotani, Hidekazu; Tsukazaki, Atsushi
- Journal of the American Chemical Society, Vol. 132, Issue 19
Hybridization-controlled charge transfer and induced magnetism at correlated oxide interfaces
journal, January 2016
- Grisolia, M. N.; Varignon, J.; Sanchez-Santolino, G.
- Nature Physics, Vol. 12, Issue 5
Magnetoelectric Charge Trap Memory
journal, February 2012
- Bauer, Uwe; Przybylski, Marek; Kirschner, Jürgen
- Nano Letters, Vol. 12, Issue 3
Electrical control of the ferromagnetic phase transition in cobalt at room temperature
journal, October 2011
- Chiba, D.; Fukami, S.; Shimamura, K.
- Nature Materials, Vol. 10, Issue 11
Electric-field control of local ferromagnetism using a magnetoelectric multiferroic
journal, April 2008
- Chu, Ying-Hao; Martin, Lane W.; Holcomb, Mikel B.
- Nature Materials, Vol. 7, Issue 6, p. 478-482
Electrostatic charge accumulation versus electrochemical doping in SrTiO3 electric double layer transistors
journal, June 2010
- Ueno, K.; Shimotani, H.; Iwasa, Y.
- Applied Physics Letters, Vol. 96, Issue 25
Ambipolar Insulator-to-Metal Transition in Black Phosphorus by Ionic-Liquid Gating
journal, February 2015
- Saito, Yu; Iwasa, Yoshihiro
- ACS Nano, Vol. 9, Issue 3
Works referencing / citing this record:
Voltage-Controlled On/Off Switching of Ferromagnetism in Manganite Supercapacitors
journal, November 2017
- Molinari, Alan; Hahn, Horst; Kruk, Robert
- Advanced Materials, Vol. 30, Issue 1
Ionic Gel Modulation of RKKY Interactions in Synthetic Anti-Ferromagnetic Nanostructures for Low Power Wearable Spintronic Devices
journal, April 2018
- Yang, Qu; Zhou, Ziyao; Wang, Liqian
- Advanced Materials, Vol. 30, Issue 22
Voltage‐Control of Magnetism in All‐Solid‐State and Solid/Liquid Magnetoelectric Composites
journal, February 2019
- Molinari, Alan; Hahn, Horst; Kruk, Robert
- Advanced Materials, Vol. 31, Issue 26
Sunlight Control of Interfacial Magnetism for Solar Driven Spintronic Applications
journal, October 2019
- Zhao, Yifan; Zhao, Shishun; Wang, Lei
- Advanced Science, Vol. 6, Issue 24
Voltage Control of Perpendicular Exchange Bias in Multiferroic Heterostructures
journal, May 2019
- Yang, Qu; Hu, Zhongqiang; Zhang, Yao
- Advanced Electronic Materials, Vol. 5, Issue 7
Room‐Temperature Reversible and Nonvolatile Tunability of Electrical Properties of Cr‐Doped In 2 O 3 Semiconductor Thin Films Gated by Ferroelectric Single Crystal and Ionic Liquid
journal, May 2019
- Xu, Meng; Yan, Jian‐Min; Chen, Ting‐Wei
- Advanced Electronic Materials, Vol. 5, Issue 7
Ionic Liquid Gating Control of Spin Wave Resonance in La 0.7 Sr 0.3 MnO 3 Thin Film
journal, November 2019
- Zhao, Shishun; Hou, Weixiao; Zhou, Ziyao
- Advanced Electronic Materials, Vol. 6, Issue 1
Ionic liquid gating control of RKKY interaction in FeCoB/Ru/FeCoB and (Pt/Co)2/Ru/(Co/Pt)2 multilayers
journal, March 2018
- Yang, Qu; Wang, Lei; Zhou, Ziyao
- Nature Communications, Vol. 9, Issue 1
Low voltage induced reversible magnetoelectric coupling in Fe 3 O 4 thin films for voltage tunable spintronic devices
journal, January 2018
- Zhang, Le; Hou, Weixiao; Dong, Guohua
- Materials Horizons, Vol. 5, Issue 5
Recent progress on flexible inorganic single-crystalline functional oxide films for advanced electronics
journal, January 2019
- Zhang, Yong; Ma, Chunrui; Lu, Xiaoli
- Materials Horizons, Vol. 6, Issue 5
Phase-transition-induced large magnetic anisotropy change in VO 2 /(Co/Pt) 2 heterostructure
journal, January 2019
- Wei, Guodong; Lin, Xiaoyang; Si, Zhizhong
- Applied Physics Letters, Vol. 114, Issue 1
Electrolyte-gated magnetoelectric actuation: Phenomenology, materials, mechanisms, and prospective applications
journal, March 2019
- Navarro-Senent, Cristina; Quintana, Alberto; Menéndez, Enric
- APL Materials, Vol. 7, Issue 3
Voltage-controlled ON switching and manipulation of magnetization via the redox transformation of β -FeOOH nanoplatelets
journal, December 2019
- Nichterwitz, Martin; Neitsch, Sabine; Röher, Stefan
- Journal of Physics D: Applied Physics, Vol. 53, Issue 8
Voltage control of ferromagnetic resonance and spin waves
journal, September 2018
- Zhao, Xinger; Hu, Zhongqiang; Yang, Qu
- Chinese Physics B, Vol. 27, Issue 9
Voltage-Control of Magnetism in All-Solid-State and Solid/Liquid Magnetoelectric Composites
text, January 2019
- Molinari, A.; Hahn, H.; Kruk, R.
- Karlsruhe
Ionic liquid gating control of RKKY interaction in FeCoB/Ru/FeCoB and (Pt/Co)2/Ru/(Co/Pt)2 multilayers
journal, March 2018
- Yang, Qu; Wang, Lei; Zhou, Ziyao
- Nature Communications, Vol. 9, Issue 1