DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Preparation of titania nanoparticles with tunable anisotropy and branched structures from core–shell molecular bottlebrushes

; ; ; ; ; ;
Publication Date:
Sponsoring Org.:
OSTI Identifier:
Grant/Contract Number:  
DEC-2011/03/B/ST5/01084; DEC- 2012/04/M/ST5/00805; DEC-2014/14/A/ST5/00204; DMR 1436219; DMR 1501324; DMR 1122483; DMR 1436201; DMR-1410845; DMR 1407645; EE0006702
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Additional Journal Information:
Journal Name: Polymer Journal Volume: 98 Journal Issue: C; Journal ID: ISSN 0032-3861
Country of Publication:
United Kingdom

Citation Formats

Xie, Guojun, Ding, Hangjun, Daniel, William F. M., Wang, Zongyu, Pietrasik, Joanna, Sheiko, Sergei S., and Matyjaszewski, Krzysztof. Preparation of titania nanoparticles with tunable anisotropy and branched structures from core–shell molecular bottlebrushes. United Kingdom: N. p., 2016. Web. doi:10.1016/j.polymer.2016.03.032.
Xie, Guojun, Ding, Hangjun, Daniel, William F. M., Wang, Zongyu, Pietrasik, Joanna, Sheiko, Sergei S., & Matyjaszewski, Krzysztof. Preparation of titania nanoparticles with tunable anisotropy and branched structures from core–shell molecular bottlebrushes. United Kingdom.
Xie, Guojun, Ding, Hangjun, Daniel, William F. M., Wang, Zongyu, Pietrasik, Joanna, Sheiko, Sergei S., and Matyjaszewski, Krzysztof. Mon . "Preparation of titania nanoparticles with tunable anisotropy and branched structures from core–shell molecular bottlebrushes". United Kingdom.
title = {Preparation of titania nanoparticles with tunable anisotropy and branched structures from core–shell molecular bottlebrushes},
author = {Xie, Guojun and Ding, Hangjun and Daniel, William F. M. and Wang, Zongyu and Pietrasik, Joanna and Sheiko, Sergei S. and Matyjaszewski, Krzysztof},
abstractNote = {},
doi = {10.1016/j.polymer.2016.03.032},
journal = {Polymer},
number = C,
volume = 98,
place = {United Kingdom},
year = {2016},
month = {8}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 27 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Tandem Synthesis of Core−Shell Brush Copolymers and Their Transformation to Peripherally Cross-Linked and Hollowed Nanostructures
journal, May 2006

  • Cheng, Chong; Qi, Kai; Khoshdel, Ezat
  • Journal of the American Chemical Society, Vol. 128, Issue 21
  • DOI: 10.1021/ja061892r

Template-Directed Synthesis of Hybrid Titania Nanowires within Core−Shell Bishydrophilic Cylindrical Polymer Brushes
journal, September 2009

  • Yuan, Jiayin; Lu, Yan; Schacher, Felix
  • Chemistry of Materials, Vol. 21, Issue 18
  • DOI: 10.1021/cm900032m

Cylindrical molecular brushes: Synthesis, characterization, and properties
journal, July 2008

Block copolymer/ferroelectric nanoparticle nanocomposites
journal, January 2013

  • Pang, Xinchang; He, Yanjie; Jiang, Beibei
  • Nanoscale, Vol. 5, Issue 18
  • DOI: 10.1039/c3nr03036a

Superparamagnetic Hybrid Nanocylinders
journal, September 2004

  • Zhang, M.; Estournès, C.; Bietsch, W.
  • Advanced Functional Materials, Vol. 14, Issue 9
  • DOI: 10.1002/adfm.200400064

Recent advances in large-scale assembly of semiconducting inorganic nanowires and nanofibers for electronics, sensors and photovoltaics
journal, January 2012

  • Long, Yun-Ze; Yu, Miao; Sun, Bin
  • Chemical Society Reviews, Vol. 41, Issue 12
  • DOI: 10.1039/c2cs15335a

Hybrids of Magnetic Nanoparticles with Double-Hydrophilic Core/Shell Cylindrical Polymer Brushes and Their Alignment in a Magnetic Field
journal, September 2010

  • Xu, Youyong; Yuan, Jiayin; Fang, Bing
  • Advanced Functional Materials, Vol. 20, Issue 23
  • DOI: 10.1002/adfm.201000769

Cylindrical Core−Shell Brushes Prepared by a Combination of ROP and ATRP
journal, July 2006

  • Lee, Hyung-il; Jakubowski, Wojciech; Matyjaszewski, Krzysztof
  • Macromolecules, Vol. 39, Issue 15
  • DOI: 10.1021/ma0604688

Template-Directed Mild Synthesis of Anatase Hybrid Nanotubes within Cylindrical Core–Shell–Corona Polymer Brushes
journal, August 2012

  • Müllner, Markus; Lunkenbein, Thomas; Schieder, Martin
  • Macromolecules, Vol. 45, Issue 17
  • DOI: 10.1021/ma301232m

Synthesis of Isocyanate-Based Brush Block Copolymers and Their Rapid Self-Assembly to Infrared-Reflecting Photonic Crystals
journal, August 2012

  • Miyake, Garret M.; Weitekamp, Raymond A.; Piunova, Victoria A.
  • Journal of the American Chemical Society, Vol. 134, Issue 34
  • DOI: 10.1021/ja306430k

Solvent-free, supersoft and superelastic bottlebrush melts and networks
journal, November 2015

  • Daniel, William F. M.; Burdyńska, Joanna; Vatankhah-Varnoosfaderani, Mohammad
  • Nature Materials, Vol. 15, Issue 2
  • DOI: 10.1038/nmat4508

Molecular Brushes with Spontaneous Gradient by Atom Transfer Radical Polymerization
journal, October 2005

  • Lee, Hyung-il; Matyjaszewski, Krzysztof; Yu, Sherryl
  • Macromolecules, Vol. 38, Issue 20
  • DOI: 10.1021/ma051231z

Large Pore Size Nanoporous Materials from the Self-Assembly of Asymmetric Bottlebrush Block Copolymers
journal, March 2011

  • Bolton, Justin; Bailey, Travis S.; Rzayev, Javid
  • Nano Letters, Vol. 11, Issue 3
  • DOI: 10.1021/nl103747m

The Synthesis of Densely Grafted Copolymers by Atom Transfer Radical Polymerization
journal, December 1998

  • Beers, Kathryn L.; Gaynor, Scott G.; Matyjaszewski, Krzysztof
  • Macromolecules, Vol. 31, Issue 26
  • DOI: 10.1021/ma981402i

Effect of Initiation Conditions on the Uniformity of Three-Arm Star Molecular Brushes
journal, March 2003

  • Matyjaszewski, Krzysztof; Qin, Shuhui; Boyce, Jamie R.
  • Macromolecules, Vol. 36, Issue 6
  • DOI: 10.1021/ma021633w

Template-Directed Synthesis of Silica Nanowires and Nanotubes from Cylindrical Core–Shell Polymer Brushes
journal, May 2012

  • Müllner, Markus; Lunkenbein, Thomas; Breu, Josef
  • Chemistry of Materials, Vol. 24, Issue 10
  • DOI: 10.1021/cm300312g

Surface-Initiated Polymerization as an Enabling Tool for Multifunctional (Nano-)Engineered Hybrid Materials
journal, August 2013

  • Hui, Chin Ming; Pietrasik, Joanna; Schmitt, Michael
  • Chemistry of Materials, Vol. 26, Issue 1
  • DOI: 10.1021/cm4023634

An Unconventional Route to Monodisperse and Intimately Contacted Semiconducting Organic-Inorganic Nanocomposites
journal, February 2015

  • Xu, Hui; Pang, Xinchang; He, Yanjie
  • Angewandte Chemie International Edition, Vol. 54, Issue 15
  • DOI: 10.1002/anie.201500763

Strategy for Good Dispersion of Well-Defined Tetrapods in Semiconducting Polymer Matrices
journal, September 2014

  • Lim, Jaehoon; Borg, Lisa zur; Dolezel, Stefan
  • Macromolecular Rapid Communications, Vol. 35, Issue 19
  • DOI: 10.1002/marc.201400314

Precisely Size-Tunable Magnetic/Plasmonic Core/Shell Nanoparticles with Controlled Optical Properties
journal, August 2015

Molecular Pressure Sensors
journal, October 2007

  • Xu, H.; Sun, F. C.; Shirvanyants, D. G.
  • Advanced Materials, Vol. 19, Issue 19
  • DOI: 10.1002/adma.200602376

Highly efficient synthesis of polymer brushes with PEO and PCL as side chains via click chemistry
journal, April 2012

Synthesis of Molecular Bottlebrushes by Atom Transfer Radical Polymerization with ppm Amounts of Cu Catalyst
journal, July 2012

  • Nese, Alper; Li, Yuanchao; Sheiko, Sergei S.
  • ACS Macro Letters, Vol. 1, Issue 8
  • DOI: 10.1021/mz3002484

Stimuli-responsive molecular brushes
journal, January 2010

Water-soluble organo-silica hybrid nanowires
journal, July 2008

  • Yuan, Jiayin; Xu, Youyong; Walther, Andreas
  • Nature Materials, Vol. 7, Issue 9
  • DOI: 10.1038/nmat2232

Multiplex Templating Process in One-Dimensional Nanoscale: Controllable Synthesis, Macroscopic Assemblies, and Applications
journal, February 2013

  • Liang, Hai-Wei; Liu, Jian-Wei; Qian, Hai-Sheng
  • Accounts of Chemical Research, Vol. 46, Issue 7
  • DOI: 10.1021/ar300272m

Synthesis of Molecular Brushes with Gradient in Grafting Density by Atom Transfer Polymerization
journal, April 2002

  • Börner, Hans G.; Duran, David; Matyjaszewski, Krzysztof
  • Macromolecules, Vol. 35, Issue 9
  • DOI: 10.1021/ma012100a

Synthesis and Visualization of Densely Grafted Molecular Brushes with Crystallizable Poly(octadecyl methacrylate) Block Segments
journal, February 2003

  • Qin, Shuhui; Matyjaszewski, Krzysztof; Xu, Hui
  • Macromolecules, Vol. 36, Issue 3
  • DOI: 10.1021/ma021472w

Hetero-Grafted Block Brushes with PCL and PBA Side Chains
journal, August 2008

  • Lee, Hyung-il; Matyjaszewski, Krzysztof; Yu-Su, Sherryl
  • Macromolecules, Vol. 41, Issue 16
  • DOI: 10.1021/ma800412s

Water-Soluble Organo−Silica Hybrid Nanotubes Templated by Cylindrical Polymer Brushes
journal, November 2010

  • Müllner, Markus; Yuan, Jiayin; Weiss, Stephan
  • Journal of the American Chemical Society, Vol. 132, Issue 46
  • DOI: 10.1021/ja107132j

Rapid self-assembly of brush block copolymers to photonic crystals
journal, August 2012

  • Sveinbjornsson, B. R.; Weitekamp, R. A.; Miyake, G. M.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 36, p. 14332-14336
  • DOI: 10.1073/pnas.1213055109

De Novo Synthesis and Cellular Uptake of Organic Nanocapsules with Tunable Surface Chemistry
journal, June 2011

  • Huang, Kun; Jacobs, Amy; Rzayev, Javid
  • Biomacromolecules, Vol. 12, Issue 6
  • DOI: 10.1021/bm200394t

PDMS−PEO Densely Grafted Copolymers
journal, October 2005

  • Neugebauer, Dorota; Zhang, Ying; Pakula, Tadeusz
  • Macromolecules, Vol. 38, Issue 21
  • DOI: 10.1021/ma0514828

Molecular brushes as super-soft elastomers
journal, September 2006

Effects of Core Microstructure on Structure and Dynamics of Star Polymer Melts: From Polymeric to Colloidal Response
journal, July 2014

  • Snijkers, Frank; Cho, Hong Y.; Nese, Alper
  • Macromolecules, Vol. 47, Issue 15
  • DOI: 10.1021/ma5008336

Precisely Tunable Photonic Crystals From Rapidly Self-Assembling Brush Block Copolymer Blends
journal, September 2012

  • Miyake, Garret M.; Piunova, Victoria A.; Weitekamp, Raymond A.
  • Angewandte Chemie International Edition, Vol. 51, Issue 45, p. 11246-11248
  • DOI: 10.1002/anie.201205743

Soft Elastomers via Introduction of Poly(butyl acrylate) “Diluent” to Poly(hydroxyethyl acrylate)-Based Gel Networks
journal, December 2012

  • Mpoukouvalas, Anastasia; Li, Wenwen; Graf, Robert
  • ACS Macro Letters, Vol. 2, Issue 1
  • DOI: 10.1021/mz300614m

Cylindrical polymer brushes
journal, January 2005

  • Zhang, Mingfu; Müller, Axel H. E.
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 16, p. 3461-3481
  • DOI: 10.1002/pola.20900

Synthesis of Amphiphilic Poly( N -vinylpyrrolidone)- b -poly(vinyl acetate) Molecular Bottlebrushes
journal, December 2011

  • Nese, Alper; Li, Yuanchao; Averick, Saadyah
  • ACS Macro Letters, Vol. 1, Issue 1
  • DOI: 10.1021/mz200134n

Template-Controlled Synthesis of Wire-Like Cadmium Sulfide Nanoparticle Assemblies within Core−Shell Cylindrical Polymer Brushes
journal, February 2004

  • Zhang, Mingfu; Drechsler, Markus; Müller, Axel H. E.
  • Chemistry of Materials, Vol. 16, Issue 3
  • DOI: 10.1021/cm034760v

A general and robust strategy for the synthesis of nearly monodisperse colloidal nanocrystals
journal, June 2013

Precursor Polymers for the Carbon Coating of Au@ZnO Multipods for Application as Active Material in Lithium-Ion Batteries
journal, January 2015

  • Oschmann, Bernd; Tahir, Muhammad Nawaz; Mueller, Franziska
  • Macromolecular Rapid Communications, Vol. 36, Issue 11
  • DOI: 10.1002/marc.201400647

Tadpole Conformation of Gradient Polymer Brushes
journal, June 2004

  • Lord, Samuel J.; Sheiko, Sergei S.; LaRue, Isaac
  • Macromolecules, Vol. 37, Issue 11
  • DOI: 10.1021/ma035989z

How Far Can We Push Polymer Architectures?
journal, March 2013

  • Stals, Patrick J. M.; Li, Yuanchao; Burdyńska, Joanna
  • Journal of the American Chemical Society, Vol. 135, Issue 31
  • DOI: 10.1021/ja400890v

Multiarm Molecular Brushes:  Effect of the Number of Arms on the Molecular Weight Polydispersity and Surface Ordering
journal, July 2004

  • Boyce, Jamie R.; Shirvanyants, David; Sheiko, Sergei S.
  • Langmuir, Vol. 20, Issue 14
  • DOI: 10.1021/la049852t

Synthesis of Platinum Multipods:  An Induced Anisotropic Growth
journal, May 2005

Are block copolymer worms more effective Pickering emulsifiers than block copolymer spheres?
journal, January 2014

  • Thompson, K. L.; Mable, C. J.; Cockram, A.
  • Soft Matter, Vol. 10, Issue 43
  • DOI: 10.1039/C4SM01724B

Densely-Grafted and Double-Grafted PEO Brushes via ATRP. A Route to Soft Elastomers
journal, September 2003

  • Neugebauer, Dorota; Zhang, Ying; Pakula, Tadeusz
  • Macromolecules, Vol. 36, Issue 18
  • DOI: 10.1021/ma0345347

Atom Transfer Radical Polymerization
journal, September 2001

  • Matyjaszewski, Krzysztof; Xia, Jianhui
  • Chemical Reviews, Vol. 101, Issue 9
  • DOI: 10.1021/cr940534g

Nanoparticle assembly for 1D and 2D ordered structures
journal, January 2009

  • Srivastava, Sudhanshu; Kotov, Nicholas A.
  • Soft Matter, Vol. 5, Issue 6
  • DOI: 10.1039/b812115j

ATRP Synthesis of Thermally Responsive Molecular Brushes from Oligo(ethylene oxide) Methacrylates
journal, December 2007

  • Yamamoto, Shin-ichi; Pietrasik, Joanna; Matyjaszewski, Krzysztof
  • Macromolecules, Vol. 40, Issue 26
  • DOI: 10.1021/ma701970t

Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement
journal, December 2009

  • Xia, Yan; Olsen, Bradley D.; Kornfield, Julia A.
  • Journal of the American Chemical Society, Vol. 131, Issue 51, p. 18525-18532
  • DOI: 10.1021/ja908379q

Synthesis of Molecular Brushes by “Grafting onto” Method:  Combination of ATRP and Click Reactions
journal, May 2007

  • Gao, Haifeng; Matyjaszewski, Krzysztof
  • Journal of the American Chemical Society, Vol. 129, Issue 20
  • DOI: 10.1021/ja0711617

Preparation of Polymeric Nanoscale Networks from Cylindrical Molecular Bottlebrushes
journal, June 2012

  • Wu, Dingcai; Nese, Alper; Pietrasik, Joanna
  • ACS Nano, Vol. 6, Issue 7
  • DOI: 10.1021/nn302096d

Organic–Inorganic Nanocomposites via Placing Monodisperse Ferroelectric Nanocrystals in Direct and Permanent Contact with Ferroelectric Polymers
journal, September 2015

  • Jiang, Beibei; Pang, Xinchang; Li, Bo
  • Journal of the American Chemical Society, Vol. 137, Issue 36
  • DOI: 10.1021/jacs.5b06736

Synthesis and Morphology of Molecular Brushes with Polyacrylonitrile Block Copolymer Side Chains and Their Conversion into Nanostructured Carbons
journal, August 2007

  • Tang, Chuanbing; Dufour, Bruno; Kowalewski, Tomasz
  • Macromolecules, Vol. 40, Issue 17
  • DOI: 10.1021/ma070892o

One-Pot Orthogonal Copper-Catalyzed Synthesis and Self-Assembly of l -Lysine-Decorated Polymeric Dendrimers
journal, March 2015

Synthesis of poly(vinyl alcohol) combs via MADIX/RAFT polymerization
journal, February 2006

Amphiphilic Cylindrical Core−Shell Brushes via a “Grafting From” Process Using ATRP
journal, September 2001

  • Cheng, Guanglou; Böker, Alexander; Zhang, Mingfu
  • Macromolecules, Vol. 34, Issue 20
  • DOI: 10.1021/ma0013962

Densely Heterografted Brush Macromolecules with Crystallizable Grafts. Synthesis and Bulk Properties
journal, December 2005

  • Neugebauer, Dorota; Theis, Matthieu; Pakula, Tadeusz
  • Macromolecules, Vol. 39, Issue 2
  • DOI: 10.1021/ma051702h

Bioinspired Bottle-Brush Polymer Exhibits Low Friction and Amontons-like Behavior
journal, April 2014

  • Banquy, Xavier; Burdyńska, Joanna; Lee, Dong Woog
  • Journal of the American Chemical Society, Vol. 136, Issue 17
  • DOI: 10.1021/ja501770y

Synthesis and Arm Dissociation in Molecular Stars with a Spoked Wheel Core and Bottlebrush Arms
journal, September 2014

  • Burdyńska, Joanna; Li, Yuanchao; Aggarwal, Anant Vikas
  • Journal of the American Chemical Society, Vol. 136, Issue 36
  • DOI: 10.1021/ja506780y

Exploring Quality in Gradient Copolymers
journal, October 2013

  • Elsen, Andrea M.; Li, Yuanchao; Li, Qiaoxi
  • Macromolecular Rapid Communications, Vol. 35, Issue 2
  • DOI: 10.1002/marc.201300654

Phototransport in networks of tetrapod-shaped colloidal semiconductor nanocrystals
journal, January 2010

  • Franchini, Isabella R.; Cola, Adriano; Rizzo, Aurora
  • Nanoscale, Vol. 2, Issue 10
  • DOI: 10.1039/c0nr00308e

Super soft elastomers as ionic conductors
journal, August 2004

Synthesis of Molecular Brushes with Block Copolymer Side Chains Using Atom Transfer Radical Polymerization
journal, June 2001

  • Börner, Hans G.; Beers, Kathryn; Matyjaszewski, Krzysztof
  • Macromolecules, Vol. 34, Issue 13
  • DOI: 10.1021/ma010001r

One-dimensional organic–inorganic hybrid nanomaterials
journal, August 2010

Stimuli-Responsive Organosilica Hybrid Nanowires Decorated with Metal Nanoparticles
journal, March 2010

  • Yuan, Jiayin; Schacher, Felix; Drechsler, Markus
  • Chemistry of Materials, Vol. 22, Issue 8
  • DOI: 10.1021/cm9038076

Macromolecular Engineering by Atom Transfer Radical Polymerization
journal, April 2014

  • Matyjaszewski, Krzysztof; Tsarevsky, Nicolay V.
  • Journal of the American Chemical Society, Vol. 136, Issue 18
  • DOI: 10.1021/ja408069v

Amphipolar Core−Shell Cylindrical Brushes as Templates for the Formation of Gold Clusters and Nanowires
journal, April 2002

  • Djalali, Ramin; Li, Shu-You; Schmidt, Manfred
  • Macromolecules, Vol. 35, Issue 11
  • DOI: 10.1021/ma0113733

Temperature- and pH-Responsive Dense Copolymer Brushes Prepared by ATRP
journal, October 2008

  • Yamamoto, Shin-ichi; Pietrasik, Joanna; Matyjaszewski, Krzysztof
  • Macromolecules, Vol. 41, Issue 19
  • DOI: 10.1021/ma8011366

pH-Responsive Fluorescent Molecular Bottlebrushes Prepared by Atom Transfer Radical Polymerization
journal, August 2011

  • Nese, Alper; Lebedeva, Natalia V.; Sherwood, Gizelle
  • Macromolecules, Vol. 44, Issue 15
  • DOI: 10.1021/ma201045c

A versatile strategy for uniform hybrid nanoparticles and nanocapsules
journal, January 2015

  • Feng, Chaowei; Pang, Xinchang; He, Yanjie
  • Polymer Chemistry, Vol. 6, Issue 29
  • DOI: 10.1039/C5PY00765H

Well-Defined Organic Nanotubes from Multicomponent Bottlebrush Copolymers
journal, May 2009

  • Huang, Kun; Rzayev, Javid
  • Journal of the American Chemical Society, Vol. 131, Issue 19
  • DOI: 10.1021/ja901936g