Characterizing rapid capacity fade and impedance evolution in high rate pulsed discharged lithium iron phosphate cells for complex, high power loads

Wong, Derek N.; Wetz, David A.; Heinzel, John M.; Mansour, Azzam N.

doi:10.1016/j.jpowsour.2016.08.013

Title: Characterizing rapid capacity fade and impedance evolution in high rate pulsed discharged lithium iron phosphate cells for complex, high power loads

Full Record
Other Related Research

Authors:: Wong, Derek N.; Wetz, David A.; Heinzel, John M.; Mansour, Azzam N.

Publication Date:: Sat Oct 01 00:00:00 EDT 2016

Sponsoring Org.:: USDOE

OSTI Identifier:: 1359480

Grant/Contract Number:: AC02-98CH10886

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Power Sources

Additional Journal Information:: Journal Name: Journal of Power Sources Journal Volume: 328 Journal Issue: C; Journal ID: ISSN 0378-7753

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Wong, Derek N., Wetz, David A., Heinzel, John M., and Mansour, Azzam N. Characterizing rapid capacity fade and impedance evolution in high rate pulsed discharged lithium iron phosphate cells for complex, high power loads.  Netherlands: N. p., 2016. 
Web.  doi:10.1016/j.jpowsour.2016.08.013.

Copy to clipboard


                    Wong, Derek N., Wetz, David A., Heinzel, John M., & Mansour, Azzam N. Characterizing rapid capacity fade and impedance evolution in high rate pulsed discharged lithium iron phosphate cells for complex, high power loads.  Netherlands.  https://doi.org/10.1016/j.jpowsour.2016.08.013

Copy to clipboard


                    Wong, Derek N., Wetz, David A., Heinzel, John M., and Mansour, Azzam N. Sat .  
"Characterizing rapid capacity fade and impedance evolution in high rate pulsed discharged lithium iron phosphate cells for complex, high power loads".  Netherlands.  https://doi.org/10.1016/j.jpowsour.2016.08.013.

Copy to clipboard


                    
@article{osti_1359480,

  title        = {Characterizing rapid capacity fade and impedance evolution in high rate pulsed discharged lithium iron phosphate cells for complex, high power loads},

  author       = {Wong, Derek N. and Wetz, David A. and Heinzel, John M. and Mansour, Azzam N.},

  abstractNote = {},

  doi          = {10.1016/j.jpowsour.2016.08.013},

  journal      = {Journal of Power Sources},

  number       = C,

  volume       = 328,

  place        = {Netherlands},

  year         = {Sat Oct 01 00:00:00 EDT 2016},

  month        = {Sat Oct 01 00:00:00 EDT 2016}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.jpowsour.2016.08.013

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 18 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Effect of cathode composition on capacity fade, impedance rise and power fade in high-power, lithium-ion cells.

Journal Article Bloom, I ; Jones, S A ; Battaglia, V S ; ... - J. Power Sources

We tested the effect of Al concentration on the performance of lithium-ion cells. One set of cells contained a LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} cathode and the other, LiNi{sub 0.8}Co{sub 0.10}Al{sub 0.10}O{sub 2}. The cells were calendar- and cycle-life tested at several temperatures, with periodic interruptions for reference performance tests that were used to gauge capacity and power fade as a function of time. The C{sub 1}/25 capacity fade in the cells displayed t{sup 1/2} dependence. The capacity fade of the 10% Al-doped cells tested at 45 {sup o}C was similar to that of the 5% Al-doped cells at 25more »« less
https://doi.org/10.1016/S0378-7753(03)00806-1
A High Potential, Low Capacity Fade Rate Iron Complex Posolyte for Aqueous Organic Flow Batteries

Journal Article Gao, Jinxu ; Amini, Kiana ; George, Thomas Y. ; ... - Advanced Energy Materials

Abstract An iron complex, tris(4,4′‐bis(hydroxymethyl)‐2,2′‐bipyridine) iron dichloride is reported, which operates at near‐neutral pH with a redox potential of 0.985 V versus SHE. This high potential compound is employed in the posolyte of an aqueous flow battery, paired with bis(3‐trimethylammonio)propyl viologen tetrachloride in the negolyte, exhibiting an open‐circuit voltage of 1.3 V at near‐neutral pH. It demonstrates excellent cycling performance with a low temporal capacity fade rate of 0.07% per day over 35 days of cycling. The extended cycling lifetime is the result of low permeability and improved structural stability of the newly developed iron complex compared to that of the ironmore »« less
https://doi.org/10.1002/aenm.202202444
Tracking inhomogeneity in high-capacity lithium iron phosphate batteries

Journal Article Paxton, William A. ; Zhong, Zhong ; Tsakalakos, Thomas - Journal of Power Sources
Cited by 34
https://doi.org/10.1016/j.jpowsour.2014.11.035
Power and capacity fade mechanism of LiNi0.8Co0.15Al0.0502composite cathodes in high-power lithium-ion batteries

Conference Kostecki, Robert ; McLarnon, Frank

High-power Li-ion cells that were tested at elevatedtemperatures showed a significant impedance rise, which was associatedprimarily with the LiNi0.8Co0.15Al0.05O2 cathode. By systematicallycollecting thousands of Raman spectra from 50 x 80 mm areas at 0.9 mmspatial resolution, and integrating the respective bands of the cathodecomponents for each spectrum, we were able to produce color-coded,semi-quantitative composition maps of cathode surfaces. Raman microscopyimages of cathodes from tested cells revealed that cell cycling orstorage at elevated temperatures led to significant changes in theLiNi0.8Co0.15Al0.05O2/elemental-carbon surface concentration ratio. Theloss of conductive carbon correlated with the power and capacity fade ofthe tested cathodes. The cathode surface statemore »« less
Full Text Available
Capacity and power fade cycle-life model for plug-in hybrid electric vehicle lithium-ion battery cells containing blended spinel and layered-oxide positive electrodes

Journal Article Cordoba-Arenas, Andrea ; Onori, Simona ; Guezennec, Yann ; ... - Journal of Power Sources
Cited by 141
https://doi.org/10.1016/j.jpowsour.2014.12.047

Similar Records