Enhanced charging capability of lithium metal batteries based on lithium bis(trifluoromethanesulfonyl)imide-lithium bis(oxalato)borate dual-salt electrolytes

Xiang, Hongfa; Shi, Pengcheng; Bhattacharya, Priyanka; Chen, Xilin; Mei, Donghai; Bowden, Mark E.; Zheng, Jianming; Zhang, Ji-Guang; Xu, Wu

doi:10.1016/j.jpowsour.2016.04.017

Title: Enhanced charging capability of lithium metal batteries based on lithium bis(trifluoromethanesulfonyl)imide-lithium bis(oxalato)borate dual-salt electrolytes

Full Record
Other Related Research

Authors:: Xiang, Hongfa; Shi, Pengcheng; Bhattacharya, Priyanka; Chen, Xilin; Mei, Donghai; Bowden, Mark E.; Zheng, Jianming; Zhang, Ji-Guang; Xu, Wu

Publication Date:: 2016-06-01

Sponsoring Org.:: USDOE

OSTI Identifier:: 1359469

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Power Sources

Additional Journal Information:: Journal Name: Journal of Power Sources Journal Volume: 318 Journal Issue: C; Journal ID: ISSN 0378-7753

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Xiang, Hongfa, Shi, Pengcheng, Bhattacharya, Priyanka, Chen, Xilin, Mei, Donghai, Bowden, Mark E., Zheng, Jianming, Zhang, Ji-Guang, and Xu, Wu. Enhanced charging capability of lithium metal batteries based on lithium bis(trifluoromethanesulfonyl)imide-lithium bis(oxalato)borate dual-salt electrolytes.  Netherlands: N. p., 2016. 
Web.  doi:10.1016/j.jpowsour.2016.04.017.

Copy to clipboard


                    Xiang, Hongfa, Shi, Pengcheng, Bhattacharya, Priyanka, Chen, Xilin, Mei, Donghai, Bowden, Mark E., Zheng, Jianming, Zhang, Ji-Guang, & Xu, Wu. Enhanced charging capability of lithium metal batteries based on lithium bis(trifluoromethanesulfonyl)imide-lithium bis(oxalato)borate dual-salt electrolytes.  Netherlands.  https://doi.org/10.1016/j.jpowsour.2016.04.017

Copy to clipboard


                    Xiang, Hongfa, Shi, Pengcheng, Bhattacharya, Priyanka, Chen, Xilin, Mei, Donghai, Bowden, Mark E., Zheng, Jianming, Zhang, Ji-Guang, and Xu, Wu. Wed .  
"Enhanced charging capability of lithium metal batteries based on lithium bis(trifluoromethanesulfonyl)imide-lithium bis(oxalato)borate dual-salt electrolytes".  Netherlands.  https://doi.org/10.1016/j.jpowsour.2016.04.017.

Copy to clipboard


                    
@article{osti_1359469,

  title        = {Enhanced charging capability of lithium metal batteries based on lithium bis(trifluoromethanesulfonyl)imide-lithium bis(oxalato)borate dual-salt electrolytes},

  author       = {Xiang, Hongfa and Shi, Pengcheng and Bhattacharya, Priyanka and Chen, Xilin and Mei, Donghai and Bowden, Mark E. and Zheng, Jianming and Zhang, Ji-Guang and Xu, Wu},

  abstractNote = {},

  doi          = {10.1016/j.jpowsour.2016.04.017},

  journal      = {Journal of Power Sources},

  number       = C,

  volume       = 318,

  place        = {Netherlands},

  year         = {2016},

  month        = {6}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.jpowsour.2016.04.017

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 157 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Enhanced charging capability of lithium metal batteries based on lithium bis(trifluoromethanesulfonyl)imide-lithium bis(oxalato)borate dual-salt electrolytes

Journal Article Xiang, Hongfa ; Shi, Pengcheng ; Bhattacharya, Priyanka ; ... - Journal of Power Sources

Rechargeable lithium (Li) metal batteries with conventional LiPF6-carbonate electrolytes have been reported to fail quickly at charging current densities of about 1.0 mA cm-2 and above. In this work, we demonstrate the rapid charging capability of the Li||LiNi0.8Co0.15Al0.05O2 (NCA) cells enabled by a dual-salt electrolyte of LiTFSI-LiBOB in a carbonate solvent mixture. It is found that the thickness of solid electrolyte interphase (SEI) layer on Li metal anode largely increases with increasing charging current density. However, the cells using the LiTFSI-LiBOB dual-salt electrolyte significantly outperforms those using the LiPF6 electrolyte at high charging current densities. At the charging current densitymore »« less
https://doi.org/10.1016/j.jpowsour.2016.04.017
Effects of Imide–Orthoborate Dual-Salt Mixtures in Organic Carbonate Electrolytes on the Stability of Lithium Metal Batteries

Journal Article Li, Xing ; Zheng, Jianming ; Engelhard, Mark H. ; ... - ACS Applied Materials & Interfaces

The effects of lithium imide and lithium orthoborate dual-salt electrolytes of different salt chemistries in carbonate solvents on the cycling stability of Li metal batteries were systematically and comparatively investigated. Two imide salts (LiTFSI and LiFSI) and two orthoborate salts (LiBOB and LiDFOB) were chosen for this study and compared with the conventional LiPF6 salt. The cycling stability of the Li metal cells with the electrolytes follows the order from good to poor as LiTFSI-LiBOB > LiTFSI-LiDFOB > LiPF6 > LiFSI-LiBOB > LiFSI-LiDFOB, indicating that LiTFSI behaves better than LiFSI and LiBOB over LiDFOB in these four dual-salt mixtures. Themore »« less
https://doi.org/10.1021/acsami.7b15117
Effects of Imide-Orthoborate Dual-Salt Mixtures in Organic Carbonate Electrolytes on the Stability of Lithium Metal Batteries

Journal Article Li, Xing ; Zheng, Jianming ; Engelhard, Mark H. ; ... - ACS Applied Materials and Interfaces

In this study, the effects of lithium imide and lithium orthoborate dual-salt electrolytes of different salt chemistries in carbonate solvents on the cycling stability of lithium (Li) metal batteries are systematically and comparatively investigated. Two imide salts (LiTFSI and LiFSI) and two orthoborate salts (LiBOB and LiDFOB) are chosen for this study and compared with the conventional LiPF6 salt. Density functional theory calculations indicate that the chemical and electrochemical stabilities follow the order of LiTFSI-LiBOB > LiTFSI-LiDFOB > LiFSI-LiDFOB > LiFSI-LiBOB. The experimental cycling stability of the Li metal batteries with the electrolytes follows the order as LiTFSI-LiBOB > LiTFSI-LiDFOBmore »« less
Cited by 87
https://doi.org/10.1021/acsami.7b15117

Full Text Available
Effects of Imide–Orthoborate Dual-Salt Mixtures in Organic Carbonate Electrolytes on the Stability of Lithium Metal Batteries

Journal Article Li, Xing ; Zheng, Jianming ; Engelhard, Mark H. ; ... - ACS Applied Materials and Interfaces

The effects of lithium imide and lithium orthoborate dual-salt electrolytes of different salt chemistries in carbonate solvents on the cycling stability of Li metal batteries were systematically and comparatively investigated. Two imide salts (LiTFSI and LiFSI) and two orthoborate salts (LiBOB and LiDFOB) were chosen for this study and compared with the conventional LiPF6 salt. The cycling stability of the Li metal cells with the electrolytes follows the order from good to poor as LiTFSI-LiBOB > LiTFSI-LiDFOB > LiPF6 > LiFSI-LiBOB > LiFSI-LiDFOB, indicating that LiTFSI behaves better than LiFSI and LiBOB over LiDFOB in these four dual-salt mixtures. Themore »« less
https://doi.org/10.1021/acsami.7b15117
A new class of electrochemically and thermally stable lithium salts for lithium battery electrolytes. 5. Synthesis and properties of lithium bis[2,3-pyridinediolato(2-)-O,O{prime}]borate

Journal Article Barthel, J ; Schmid, A ; Gores, H J - Journal of the Electrochemical Society

Synthesis, analysis, and purification of lithium bis[2,3-pyridinediolato(2-)-O,O{prime}]borate (LBPB), is described, LBPB is the first lithium spiroborate known with a heterocycle, where the nitrogen works as an electron withdrawing atom. The anodic oxidation limit of this salt as determined from cyclic voltammetric measurements is 3.95 V vs. Li/Li{sup +} and it is increased by about 0.35 V when compared with lithium bis[1,2-benzenediolato(2-)-O,O{prime}]borate. The gas phase energy of the highest occupied molecular orbital of the anion as obtained by the use of a semiempirical quantum mechanical method is {minus}5.1 eV. No corrosion of aluminum is observed with this salt, which shows goodmore »« less
https://doi.org/10.1149/1.1393138

Similar Records